莱钢2#竖炉自控系统的应 用

针对莱钢2#竖炉存在的问题,对其自控系统进行升级改造,以确保系统稳定运行,提高生产效率。     

燃煤发电机组锅炉节油技术

介绍浙能长兴发电有限公司300MW燃煤机组锅炉在节约燃油方面所采取的措施.     

Reprint of “Suppressing propylene carbonate decomposition by coating graphite electrode foil with silver”

A method has been developed to suppress the decomposition of propylene carbonate (PC) by coating graphite electrode foil with a layer of silver. Results from electrochemical impedance measurements show that the Ag-coated graphite electrode presents lower charge transfer resistance and faster diffusion of lithium ions in comparison with the virginal one. Cyclic voltammograms and discharge-charge measurements suggest that the decomposition of propylene carbonate and co-intercalation of solvated lithium ions are prevented, and lithium ions can reversibly intercalate into and deintercalate from the Ag-coated graphite electrode. These results indicate that Ag-coating is a good way to improve the electrochemical performance of graphitic carbon in PC-based electrolyte solutions.     

Hot-spot combustion of heterogeneous condensed mixtures. Thermal percolation

A model of combustion of heterogeneous condensed mixtures composed of reactive particles separated by an inert heat-conducting substance is considered. Propagation of the reaction in a one-dimensional periodic system of point reaction cells connected by inert thermal bridges is examined. The burning rate is determined as a function of the basic parameters of the system, and stability of the steady combustion mode is studied. It is shown that there exists a range of parameters in which the reaction propagates in an unstable manner. Combustion of the system in the instability domain is examined. It is shown that the reaction propagation loses its stability many times as the adiabatic temperature of the system decreases; in this case, the existing unsteady mode is replaced by another, more complicated mode, and the alteration of the regimes in the examined systems always proceeds as a period-doubling bifurcation. Beginning from a certain value of adiabatic temperature, the reaction-propagation process becomes stochastic. In the systems examined, there exists an ultimate adiabatic temperature, below which self-sustained propagation of the reaction in the system becomes impossible.Translated from Fizika Goreniya i Vzryva, Vol. 41, No. 1, pp. 41–54, January–February, 2005.     

Synthesis of thermosetting poly(phenylene ether) containing allyl groups

New thermosetting poly(2-allyl-6-methylphenol-co-2,6-dimethylphenol)s (3) have been developed by oxidative coupling copolymerization of 2-allyl-6-methylphenol (1) with 2,6-dimethylphenol (2), followed by thermal curing. Copolymerization was conducted in nitrobenzene in the presence of copper(I) chloride and pyridine as the catalyst under a stream of oxygen, producing high molecular weight copolymers (M_n∼50,000) with broad molecular weight distributions (M_w/M_n∼35). The structure of resulting copolymers 3 was characterized by IR, ¹H, and ¹³C NMR spectroscopy. Cross-linking reactions of copolymers were carried out by thermal treatment in the absence or presence of a peroxide (3 wt%, 2,5-dimethyl-2,5-di(tert-butylperoxy)-3-butane). The 10% weight loss and glass transition temperatures of the cured copolymers were 436 °C in nitrogen and 235 °C, respectively after curing at 70 °C for 1 h and 300 °C for 1 h. The average refractive index of the cured copolymer (3b) film was 1.5407, from which the dielectric constant (ε) at 1 MHz was estimated as 2.6. The ε and dissipation factor of copolymer-films at 1 MHz were directly measured from their capacitances as 2.5-2.6 and 0.0015-0.0019, respectively.     

一维炉系统的测试实验

一维炉是一种研究煤的热解燃烧和结渣等方面的实验系统,可用于模拟电厂煤粉的燃烧特性。以元宝山褐煤为燃料,介绍了一维炉的结构和功能,并对系统的可靠性进行了验证,利用烟气分析仪及热重分析仪对燃烧后的尾部烟气及灰渣进行了分析测定。结果表明:尾部烟气含氧量与灰渣可燃部分剩余量均在理论计算值的误差允许范围内,说明一维炉密封良好,系统内各部分正常运行,对维炉的调试和研究具有一定的参考意义。     

燃烧离子色谱法测定α-烯烃齐聚反应体系中催化剂BF3的含量

BF₃作为α-烯烃齐聚反应催化剂,其含量控制对催化反应的调控与产品质量的把控至关重要。通过建立样品前处理方法、优化仪器测试条件与标准溶液配制方法,建立利用燃烧离子色谱测定BF₃·醇催化的α-烯烃齐聚反应体系中F元素含量,进而计算出BF₃含量的方法,并考察了方法的重复性和准确性。结果表明：利用该方法可测定BF₃质量分数范围为2.68～53.50 g/kg的样品,前处理时适量的正丁醇和白油可有效稳定和稀释样品;测定稀释样品中F元素含量的标准曲线分为2段,线性范围分别为300～2000 mg/L和2000～3000 mg/L,线性相关系数R²分别为0.9992和0.9940;测定5次BF₃质量分数结果相对标准偏差均小于5%,方法加标回收率在95.0%～105.0%之间,方法检出限取决于前处理时的取样量,当取样量为5 g时,检出限为1 mg/kg。     

低碳低合金铸钢力学性能的研究

利用Olympus光学显微镜、扫描电镜(SEM)及能谱分析(EDAX)探讨了等温淬火工艺对低碳低合金CrMnSi铸钢力学性能的影响,并通过XRD定量分析了相的组成.结果表明,合适的等温淬火工艺,可获得一定数量的贝氏体和残余奥氏体(约6%)的复合组织,冲击断口形貌由解理刻面变为韧窝状,铸造成形无缺口试样(10 mm×10 mm×55 mm)的冲击韧度由ακ≤30 J/cm2增加至ακ≥170 J/cm2,硬度HRC≥40,具有较高硬度和冲击韧度的配合.     

High temperature corrosion mechanisms and effect of alloying elements for materials used in waste incineration environment

Corrosion products on two typical materials, SA213-T12 steel and alloy 625 exposed to the actual combustion gas, were analyzed in addition to laboratory tests for penetration of corrosive matter. It has been clarified that corrosion products of oxides containing a little chlorides and sulphides show lamellar structures and that at the alloy-scale interface, chlorination, sulphidation, and oxidation occur under a low P_O2-high P_Cl2 condition. The formation of scale structures and the effect of corrosion-resistant alloying elements can be explained according to the stability tendencies of metals, chlorides, and oxides in the M-Cl-O equilibrium diagrams. The severity of corrosion environments at the interface is influenced by the penetration extent of corrosive matters through deposits and scales, and the protective effects of oxide films derived from alloying elements play an important role in preventing the corrosion. On the other hand, it has been shown that thermal fluctuation characterized in this kind of environment makes the lamellar scale structures and sometimes breaks and peels off the scale, and thus accelerates the corrosion. On the basis of the above mentioned knowledge, a new corrosion model is presented.     

海绵城市建设的径流控制指标探析

城市化引起的诸多水生态、水环境及洪灾问题均与天然水文条件的破坏紧密相关;水文控制指标是海绵城市建设中的关键控制指标。在调研国际城市雨洪管理的演变及目前城市水文控制指标发展趋势的基础上,提出海绵城市建设所必需的水文控制指标体系概念。该体系包括维持河湖湿地基流与地下水补给的入渗控制指标,减少雨洪面源污染的水质控制指标,防止河道侵蚀的水土侵蚀控制指标,以及避免小量级洪涝和减轻极端洪涝灾害的洪水控制指标。在此基础上,分析了我国在海绵城市建设中缺乏完整水文控制指标体系的现状,并提出了我国目前在建立城市雨洪管理水文控制指标工作中亟待开展的工作,为海绵城市建设中合理确定适合各地具体条件的水文控制指标体系提供研究思路与参考。