全文获取类型
收费全文 | 75088篇 |
免费 | 8763篇 |
国内免费 | 8337篇 |
专业分类
电工技术 | 5910篇 |
技术理论 | 2篇 |
综合类 | 4877篇 |
化学工业 | 19205篇 |
金属工艺 | 3561篇 |
机械仪表 | 4420篇 |
建筑科学 | 3006篇 |
矿业工程 | 853篇 |
能源动力 | 2357篇 |
轻工业 | 4562篇 |
水利工程 | 880篇 |
石油天然气 | 1844篇 |
武器工业 | 604篇 |
无线电 | 10881篇 |
一般工业技术 | 8618篇 |
冶金工业 | 1878篇 |
原子能技术 | 2131篇 |
自动化技术 | 16599篇 |
出版年
2024年 | 268篇 |
2023年 | 1283篇 |
2022年 | 1896篇 |
2021年 | 2435篇 |
2020年 | 2473篇 |
2019年 | 2238篇 |
2018年 | 1924篇 |
2017年 | 2889篇 |
2016年 | 2971篇 |
2015年 | 3495篇 |
2014年 | 3567篇 |
2013年 | 4772篇 |
2012年 | 5782篇 |
2011年 | 4924篇 |
2010年 | 4359篇 |
2009年 | 4462篇 |
2008年 | 4680篇 |
2007年 | 5655篇 |
2006年 | 5477篇 |
2005年 | 4574篇 |
2004年 | 3865篇 |
2003年 | 3166篇 |
2002年 | 2558篇 |
2001年 | 1989篇 |
2000年 | 1737篇 |
1999年 | 1610篇 |
1998年 | 1280篇 |
1997年 | 1090篇 |
1996年 | 881篇 |
1995年 | 725篇 |
1994年 | 636篇 |
1993年 | 504篇 |
1992年 | 400篇 |
1991年 | 317篇 |
1990年 | 279篇 |
1989年 | 200篇 |
1988年 | 193篇 |
1987年 | 122篇 |
1986年 | 104篇 |
1985年 | 105篇 |
1984年 | 82篇 |
1983年 | 43篇 |
1982年 | 60篇 |
1981年 | 23篇 |
1980年 | 23篇 |
1979年 | 17篇 |
1978年 | 7篇 |
1977年 | 20篇 |
1976年 | 8篇 |
1951年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 171 毫秒
991.
Poly(p-tert-butoxycarbonyloxystyrene): a convenient precursor to p-hydroxystyrene resins 总被引:1,自引:0,他引:1
An efficient synthetic route to pure, high molecular weight poly(p-hydroxystyrene) is reported. The route involves synthesis of a new monomer, p-tert-butoxycarbonyloxystyrene, polymerization by radical initiation or by cationic initiation in liquid SO2, followed by thermolysis or acidolysis of the tert-butoxycarbonyl protecting group. Porous, crosslinked resin beads containing the nucleophilic, phenol pendant group have been prepared in a similar fashion from the precursor terpolymer of p-tert-butoxycarbonyloxystyrene, styrene and divinylbenzene. The utility of this resin for solid-phase synthesis has been demonstrated. 相似文献
992.
用人工神经网络预测混杂复合材料混杂效应 总被引:1,自引:0,他引:1
本研究建立一个二输入单输出的BP人工神经网络模型,并用QBASIC语言编制了相应的软件。利用该神经网络模型对混杂效应与混杂比及分散度系数间关系进行了预测。研究结果表明,网络经过61223次的迭代,预潮值误差为0.12%,具有很高的预测精度,可用于混杂复合材料混杂效应的预测。 相似文献
993.
To synthesize new functional poly(urethane‐imide) crosslinked networks, soluble polyimide from 2,2′‐bis(3,4‐dicarboxyphenyl) hexafluoropropane dianhydride, 4,4′‐oxydianiline, and maleic anhydride and polyurethane prepolymer from polycaprolactone diol, tolylene 2,4‐diisocyanate and hydroxyl ethyl acrylate were prepared. Poly(urethane‐imide) thin films were finally prepared by the reaction between maleimide end‐capped soluble polyimide (PI) and acrylate end‐capped polyurethane (PU). The effect of polyurethane content on dielectric constant, residual stress, morphology, thermal property, and mechanical property was studied by FTIR, prism coupler, Thin Film Stress Analyzer (TFSA), XRD, TGA, DMTA, and Nano‐indentation. Dielectric constant of poly(urethane‐imide) thin films (2.39–2.45) was lower than that of pure polyimide (2.46). Especially, poly(urethane‐imide) thin films with 50% of PU showed lower dielectric constant than other poly(urethane‐imide) thin films did. Lower residual stress and slope in cooling curve were achieved in higher PU content. Compared to typical polyurethane, poly(urethane‐imide) thin films exhibited better thermal stability due to the presence of the imide groups. The glass transition temperature, modulus, and hardness decreased with increase in the flexible PU content even though elongation and thermal expansion coefficient increased. Finally, poly(urethane‐imide) thin films with low residual stress and dielectric constant, which are strongly affected by the morphological structure, chain mobility, and modulus, can be suggested to apply for electronic devices by variation of PU. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 113–123, 2006 相似文献
994.
以2,6-二氯吡啶为原料,制得2,6-二溴吡啶(收率79%)或2,6-二碘吡啶(收率56%),再分别与三氟乙酸钾反应,均可得标题化合物,收率28%~53%。该合成路线的优点是原料易得,反应条件温和,收率较高。 相似文献
995.
996.
This study was undertaken to elucidate the state of a polymer in the amorphous state through a change of motion of the molecular chain caused by heat treatment below the glass transition temperature. From dielectric measurements of amorphous poly(ethylene terephthalate) heat-treated below Tg, it was found that the average relaxation time, the distribution of relaxation time and the dielectric strength increase with increase of heat treatment. From these results, it was concluded that the amorphous state becomes more random by heat treatment. 相似文献
997.
为开发六芳基二咪唑类光致变色材料 ,以联苯甲酰、对甲氧基苯甲醛及乙酸铵为原料 ,经过环合、氧化合成了光致变色化合物 2 ,2′-二对甲氧苯基 - 4,4′,5 ,5′-四苯基 - 1 ,2′-二咪唑。研究了多种因素对反应收率的影响 ,得到最佳工艺条件 :在冰乙酸中 ,联苯甲酰、对甲氧基苯甲醛及醋酸铵物质的量之比为 1∶ 1∶ 8,回流 3 h后生成 2 -对甲氧苯基 - 4,5 -二苯基咪唑 ,收率为 93 .6 % ;以乙二醇 -乙醚为溶剂 ,2 -对甲氧苯基 - 4,5 -二苯基咪唑与氧化剂 K3 [Fe(CN) 6]的物质的量之比为 1∶ 2 ,在 0~1 5°C下反应 5 h,得到产品 2 ,2′-二对甲氧苯基 - 4,4′,5 ,5′-四苯基 - 1 ,2′-二咪唑 ,收率为 87.5 %。 相似文献
998.
活性中间体失水甘油基三甲基氯化铵的性质研究 总被引:5,自引:0,他引:5
以环氧氯丙烷和三甲胺为原料 ,常温下合成活性中间体失水甘油基三甲基氯化铵 (GTA)。通过对GTA的吸水性和水解性的定量分析可知 :温度上升水解加快 ,吸水减慢 ;吸水与水解都随时间延长加强。在较低浓度的GTA水溶液中 ,随时间的延长GTA逐渐水解失效 ,但质量分数为 70 %~ 80 %的GTA稠浆的分解速率常数却很小。 相似文献
999.
Sara Cavaliere-Jaricot Arnaud Etcheberry Michel Herlem Henri Perez 《Electrochimica acta》2007,52(6):2285-2293
Platinum nanoparticles (n-Pt), over-grafted with 2-thiophenecarbonyl chloride are assembled on gold electrodes, by the Langmuir Blodgett (LB) technique using behenic acid (BHA) as promoting agent. These layers are electrochemically active without any preliminary activation. The [Fe(CN)6]3−/4− redox couple was used as electrochemical probe. This paper reports on the influence of the number of deposited LB layers, and the n-Pt density on the electrochemical response. n-Pt density was modified by the change of the “BHA/n-Pt” ratio. Cyclic voltammograms of “[Fe(CN)6]3−/4−” were observed whatever the coating conditions. As soon as the first layer was deposited the electrochemical response was associated to the n-Pt coverage, its response slightly increased up to a steady state for five or seven layers. As expected, the increase of the Pt density favored the increase of the current density. XPS analysis performed before and after electrochemical cycling showed that 4-mercaptoaniline capped platinum nanoparticles, and their over grafting were chemically and electrochemically stable. Analysis of influence of the number or the n-Pt density of the layers showed that the electrochemically active part of LB electrodes was provided by the last layer plus a part of the underlying one. 相似文献
1000.
A self-assembled monolayer (SAM) of a novel cobalt(II)porphyrin disulphide derivative was prepared on flat gold(1 1 1) electrode. Evidence for surface modification was provided by electrochemical reductive desorption of the monolayer and ellipsometry, consistent with a coverage of 2.5 × 10−10 mol cm−2 and a thickness of 13 Å, respectively. Both results support the presence of SAMs where the molecules share an intermediate position between perpendicular and flat orientation. Scanning tunnelling microscopy have also proven the formation of CoPSS SAMs, however high-resolution images could only be obtained when the CoPSS molecules were diluted in an hexanethiol SAM. The electrocatalytic activity of the surface confined Co-porphyrin was evaluated for the oxygen reduction. Voltammetric data indicate that reaction involves two electrons consistent with the formation of hydrogen peroxide. Under similar experimental conditions the data obtained for an iron-porphyrin analogue points for a full reduction of dioxygen to water. 相似文献