多级机站通风新模式和矿井通风技术的新进展

文中详细论述了我国“九五”期间金属矿山在多级机站通风系统改造中涌现出的先进技术 ,反映了我国矿山通风技术的发展现状。同时 ,探讨了矿井通风技术的发展方向 ,对矿井通风系统的改造研究具有一定意义     

Potential use of phenolic antioxidants on peanut to control growth and aflatoxin B1 accumulation by Aspergillus flavus and Aspergillus parasiticus

Food‐grade antioxidants: butylated hydroxyanisole (BHA), propyl paraben (PP) and butylated hydroxytoluene (BHT) (10 and 20 mmol g^?1) and all the mixtures of these chemicals were tested for inhibitory activity on the growth of and aflatoxin B₁ (AFB₁) accumulation by Aspergillus parasiticus and A. flavus on irradiated (7 kGy) peanut grains. Also, the influence of these treatments was evaluated in different water conditions (0.982, 0.955, 0.937a_w) at 11 and 35 days of incubation at 28 °C. Water activity (a_w) affected the fungal growth, no fungal development was observed at the highest stress water condition (0.937a_w). Butylated hydroxyanisole at 10 mmol g^?1 level and all the mixtures with PP and/or BHT were significantly effective (P = 0.05) in increasing lag phase and reducing growth rate and colony forming units per gram of peanut of both Aspergillus section Flavi strains and AFB₁ accumulation. The application of BHA at concentrations of 20 mmol g^?1 alone or with PP and/or BHT totally inhibited fungal growth at 11 and 35 days of incubation. The results suggest that the addition of these chemical mixtures on peanut grains at low levels has potential to impact synergically on the control of Aspergillus section Flavi. Copyright © 2007 Society of Chemical Industry     

Alpha induced reactions on Sn: An experimental study of excitation functions and possible production pathways

In the frame of a systematic study of light ion induced threshold reactions on natural tin (Sn) excitation functions for alpha particles induced reactions are presented in a 12–38 MeV energy domain. Using a stacked foil activation method the following radioisotopes were identified: ¹¹⁶Te, ¹¹⁷Te, ¹¹⁸Te, ¹¹⁹Te, ¹²¹Te, ¹²³Te, ¹¹⁷Sb, ¹¹⁸Sb, ¹²⁰Sb, ¹²²Sb, ¹²⁴Sb, ¹²⁶Sb, ¹¹⁷Sn, ¹¹¹In. The experimental cross sections for these isotopes are presented for the first time in this energy range and a direct comparison with values calculated with the ALICE-IPPE code is discussed. Possible use of these data for production of some isotopes relevant in nuclear medicine is suggested.     

Study of hot air generator with quasi-uniform temperature using concentrated solar radiation: Influence of the shape parameters

The non-uniformity of the air temperatures and the slow flow rate at the plane collector exit constitute the main cause of the limitations of the solar drying systems. In order to obtain an uniform and a variable flow rate for different uses, a hot air generator using concentrated solar radiation is proposed. To improve the thermal efficiency of the generator, a study of the influence of different shape parameters is realized. The generator is simulated in the laboratory while investigating the flow induced by a circular disc heated uniformly by Joule effect at constant temperature. This disc is placed at the entrance of an open ended vertical cylinder of a larger diameter. Thermal radiation emitted by the hot disc heats the cylinder wall. The heating of the fluid at the cylinder-inlet generates a thermosiphon flow around the one created by the hot disc. The comparison of the velocity and the temperature profiles of the resulting flow permits to determine the influence of the cylinder height, the vertical source-cylinder spacing and the radius ratio, on the resulting flow at the system exit. Thus, a judicious choice of the shape parameters entails an improvement of the flow rate as well as the thermal flux absorbed by the air and a good homogenization of the air temperature at the generator exit.     

Passive cooling in a low-energy office building

In office buildings, the use of passive cooling techniques combined with a reduced cooling load may result in a good thermal summer comfort and therefore save cooling energy consumption. This is shown in the low-energy office building ‘SD Worx’ in Kortrijk (Belgium), in which natural night ventilation and an earth-to-air heat exchanger are applied. In winter, the supply air is successively heated by the earth-to-air heat exchanger and the regenerative heat exchanger, which recovers the heat from the exhaust air. In summer, the earth-to-air heat exchanger cools the ventilation air by day. In addition, natural night ventilation cools down the exposed structure which has accumulated the heat of the previous day. In this article the overall thermal comfort in the office building is evaluated by means of measuring and simulation results. Measurements of summer 2002 are discussed and compared to simulations with a coupled thermal and ventilation simulation model TRNSYS-COMIS. The simulations are used to estimate the relative importance of the different techniques. The evaluation shows that passive cooling has an important impact on the thermal summer comfort in the building. Furthermore, natural night ventilation appears to be much more effective than an earth-to-air heat exchanger to improve comfort.     

Nanocrystalline TiO2 photosensitized with natural polymers with enhanced efficiency from 400 to 600 nm

TiO₂ sensitization for solar applications requires not only efficient but also stable and inexpensive sensitizers. Different condensed tannins extracted from bark wastes of tropical wood trees were studied as possible sensitizers of TiO₂. These natural polymers adhere strongly to the TiO₂ even from aqueous solutions. Absorption spectra are presented for 1 mM aqueous sensitizing solutions prepared with lyophilized condensed tannins which absorb light in the visible range. Spectral photocurrent measurements and I–V characterization show that no bias is required for electron injection to the TiO₂ from all studied condensed tannins. Incident photon to current efficiency (IPCE) analysis indicates that surface complexation originates absorption bands with different electron injection efficiencies. These play a dominant role in determining IPCE spectral shape. We propose that surface modification by the sensitizer changes the surface trap density, thereby decreasing recombination losses.     

Photochemical reduction of molecular weight and number of double bonds in natural rubber film

Natural rubber (NR) can be degraded depending on various factors such as heat, mechanical force, chemical reaction, and light. Light is a very interesting factor because it can cause the NR to degrade under low temperature and pressure. The photo-degradation of NR films was carried out to investigate the effects of the light and the temperature on the reduction of the weight-average molecular weight (Mw) and the double bonds in the NR films. The NR films, with and without catalysts, titanium dioxide (TiO₂), and potassium persulfate (K₂S₂O₈), were exposed to light from a mercury light bulb at 7,000 and 36,000 lux, and at the temperature of 25 °C and 80 °C for 192 hrs. After exposure, the Mw of the NR films was analyzed by gel permeation chromatography (GPC). Changes in the Mw were used to construct a kinetic model for the process, (1/Mw)=(1/Mw₀)+(kt/2M₀) where k is the rate constant, and M₀ is the Mw of the monomer unit. The linear relationship between 1/Mw and time suggested pseudo first-order processes with random scission. The Mw distribution information from the GPC was used to calculate the number of double bonds in the NR films. The trend of the double bonds reduction curves was quite similar to the result obtained from the calculation from the FTIR spectra. This indicated that this calculation method might possibly be another alternative way to obtain the number of double bonds in the NR.     

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以天然气为能源，用燃气机代替电动机驱动压缩机并充分利用发动机废热、工业余热以及低品位环境热量的采暖、空调装置——燃气压缩式热泵近年来发展迅速。美国燃气设备的总装机容量已达到1．2GW，日本燃气机热泵占全部燃气制冷设备的29％，总装机容量大约1GW，燃气机热泵在英国、法国、德国、瑞士等都得到了较快的发展与应用。中研究了以天然气为驱动能源的压缩式热泵的特点及能量利用率，分析并测试了该系统的运行特性及交工况特性，进行了各种工况及转速下的实验研究。结果表明，该系统具有较好的部分负荷特性、一次能源利用率及交工况特性，为一种绿色高效的供热空调系统。     

输气管道天然气连续取样器的研制及应用

文章针对国内管输天然气气质分析工作中取样环节所存在的问题，结合国外技术发展趋势，全面地介绍了输气管道天然气连续取样器的研制过程。实践证明，该装置较好地解决了天然气密度值偏差问题，满足管输天然气全分析的要求，同时，该装置的推广应用将会提高天然气的计量准确度。     

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当前我国管道天然气计量系以体积表示，就其计量器具而言，差压式流量计、容积式流量计和速变式流量计都有，但大流量计量大多仍采用标准孔板差压式流量计，其流量计量标准招待我国SY／T6143－1996《天然气流量的标准孔板计量方法》。文章介绍目前常用的三种流量计的优缺点比较；天然气标准孔板差压式流量计算机自动计量系统的检定，其中包括：标准孔板节流装置，静压、差压变送器、温度传感器、数据采集系统等组件的检定；以及计量器具的正确使用和维护。最后，文章指出目前流量计量的发展主要是二次仪表的发展，籍助应用计算机大大提高流量法的测量范围和准确度，但对用户来说，应选择性／价比合适的仪表，并要考虑所选用仪表要便于检定、维护，同时，计量检定部门则应跟上发展，为广大用户提供技术支持。