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Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is the most successful conducting polymer in terms of the practical application. It can be dispersed in water and some polar organic solvents, and high-quality PEDOT:PSS films can be readily prepared through solution processing. In addition, PEDOT:PSS is highly transparent in the visible range and has excellent thermal stability. Nevertheless, PEDOT:PSS has a problem of low conductivity. The as-prepared PEDOT:PSS films from its aqueous solution have a conductivity of lower than 1 S cm−1, which severely impedes the application of PEDOT:PSS in various aspects. It has been discovered that the conductivity of as-prepared PEDOT:PSS from its aqueous solution can be significantly enhanced by adding organic compounds like high-boiling point polar organic solvents, ionic liquids and surfactants or through a post-treatment of PEDOT:PSS films with organic compounds, including high-boiling point polar solvents, salts, zwitterions, cosolvents, organic and inorganic acids. Conductivity of more than 3000 S cm−1 was recently observed on PEDOT:PSS films after treated with sulfuric acid. This conductivity is comparable to that of indium tin oxide (ITO), the conventional transparent electrode material of optoelectronic devices. In addition, PEDOT:PSS has high mechanical flexibility while ITO is a brittle material. Thus, PEDOT:PSS is very promising to be the next-generation transparent electrode material. This article reviews the methods to enhance the conductivity of PEDOT:PSS, the mechanisms for the conductivity enhancements and the application of the highly conductive PEDOT:PSS films in polymer light-emitting diodes and polymer solar cells. 相似文献
64.
Electroconductive papers were produced by coating commercial base papers with blends of poly(3,4‐ethylenedioxythiophene)/poly(4‐styrenesulfonate) (PEDOT:PSS) and organic solvents. The bulk conductivities of the coated papers were measured using a four‐probe technique. One‐sided and two‐sided coating gave comparable conductivity levels. The presence of sorbitol and isopropanol in the PEDOT:PSS blends did not enhance the bulk conductivity of the coated paper, and with increasing concentrations of these solvents, the conductivity decreased due to dilution of the conducting component. Samples coated with PEDOT:PSS blends containing N‐methylpyrrolidone (NMP) or dimethyl sulfoxide (DMSO) exhibited a higher conductivity than those coated with pure PEDOT:PSS because of their plasticizing effect and conformational changes of PEDOT molecules indicated by the red shift and disappearance of the shoulder peak at about 1442 cm?1 in the Raman spectra of the coated samples. EDS imaging showed that PEDOT:PSS is distributed throughout the thickness direction of the paper. Contact angle measurements were made to monitor the hydrophilicity of the paper surface and total sulfur analysis was used to determine the amount of PEDOT:PSS deposited onto the paper. The tensile strength of all the paper samples increased slightly after treatment. Thus, it is demonstrated that enhanced bulk conductivity in the order of 10?3 S/cm can be achieved by using organic conductive materials and surface treatment techniques. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
65.
为了优化藻酸双酯磺化物的合成工艺,按L1645正交表设计考察了影响以酯化物、氯磺酸、吡啶、甲酰胺为原料合成藻酸双酯钠磺化物的投料比(A)、反应时间(B)、吡啶用量(C)、滴加温度(D)4个主要因素,每个因素各取4个水平。结果表明:合成的最优反应条件为A3B3C3D1,此合成工艺硫酸盐合格率可达到95.0%以上。 相似文献
66.
提出基于特征值对PSS传递函数的灵敏度以及阻尼比对PSS放大倍数的灵敏度分析方法,分别进行PSS的配置以及放大倍数的整定,并通过四机两区域典型系统验证文中所提方法的有效性. 相似文献
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68.
L. Basiricò P. Cosseddu A. ScidàB. Fraboni G.G. MalliarasA. Bonfiglio 《Organic Electronics》2012,13(2):244-248
We report on the fabrication and characterization of inkjet-printed, all-Organic ElectroChemical Transistors (OECTs) entirely realized by a conducting polymer, namely poly(3,4-ethylenedioxythiophene) doped with poly(styrene sulfonic acid) (PEDOT:PSS). The transistors utilized saline as the electrolyte and exhibited output characteristics typical for operation in depletion regime. The transfer characteristics could be tuned on the basis of device geometry, with the ratio between the area of the channel and the area of the gate electrode determining the transconductance. This work paves the road for the low-cost, print-on-demand fabrication of circuits for applications in bio-sensors and disposable electronics. 相似文献
69.
文章叙述了百色水利枢纽工程电站UNITROL 5000型数字式可控硅励磁调节器系统的主要功能及其电力系统稳定器的功能,并介绍了在百色电站的有关试验及参数设定情况。 相似文献
70.
Xing Zhao Meicheng Li Dandan Song Peng Cui Zhirong Zhang Yan Zhao Chao Shen Zhaohuang Zhang 《Nanoscale research letters》2014,9(1):202
A novel hierarchical Pt- and FTO-free counter electrode (CE) for the dye-sensitized solar cell (DSSC) was prepared by spin coating the mixture of TiO2 nanoparticles and poly(3,4-ethylenedioxy-thiophene):poly(styrenesulfonate) (PEDOT:PSS) solution onto the glass substrate. Compared with traditional Pt/FTO CE, the cost of the new CE is dramatically reduced by the application of bilayer TiO2-PEDOT:PSS/PEDOT:PSS film and the glass substrate. The sheet resistance of this composite film is 35 Ω sq−1 and is low enough to be used as an electrode. The surface morphologies of TiO2-PEDOT:PSS layer and modified PEDOT:PSS layer were characterized by scanning electron microscope, which shows that the former had larger surface areas than the latter. Electrochemical impedance spectra and Tafel polarization curves prove that the catalytic activity of TiO2-PEDOT:PSS/PEDOT:PSS/glass CE is higher than that of PEDOT:PSS/FTO CE and is similar to Pt/FTO CE''s. This new fabricated device with TiO2-PEDOT:PSS/PEDOT:PSS/glass CE achieves a high power conversion efficiency (PCE) of 4.67%, reaching 91.39% of DSSC with Pt/FTO CE (5.11%). 相似文献