HL型碎玻璃风选机的设计及改进

本文详细介绍了HL型碎玻璃风选机的设计原理、结构特点、技术方案与主要应用范围。介绍了HL型风选机的主体结构及运行特征。针对HL型碎玻璃风选机在风选碎玻璃时出现的各种问题,提出了解决方案,并优化结构设计。     

影响干式磁选机在石英除铁过程中的因素研究

本文通过对陕西某地石英矿进行干式磁选试验研究,介绍了给料速度、尾矿抛尾率、矿样含水率及含泥量等几个因素对干式磁选作用的影响,分析了干式磁选各因素在石英除铁过程中的规律,为后续工业应用提供一定的理论基础。     

Strain‐rate‐dependent mechanical properties of polypropylene separator for lithium‐ion batteries

The mechanical integrity of battery separators is critical for battery safety and durability. A comprehensive study of strain‐rate‐dependent tensile and puncture properties of a polypropylene lithium‐ion battery separator is presented here with a new model. Due to anisotropy of the polymeric membrane, tensile testing was conducted for different directions. Results showed that tensile strength and elastic modulus were increased 1000% and 500%, respectively, for different directions. It was also demonstrated that tensile strength changed 10 to 25% with strain rate (1.67 × 10^?4 to 1.67 × 10^?1 s^?1) for different directions. An equation was obtained for the first time for flow stress versus strain rate at varied tensile directions with respect to machine direction. Moreover, puncture testing was performed and it was shown that puncture strength was increased 140% with increasing strain rate from 0.25 to 250 mm min^?1. Two failure modes were also observed in puncture samples. Finally, Eyring's model was used to calculate activation enthalpy of the porous polypropylene separator. © 2020 Society of Chemical Industry     

Imidazolium functionalized poly(vinyl alcohol) membranes for direct methanol alkaline fuel cell applications

In this study, imidazolium functionalized poly(vinyl alcohol) (PVA) was synthesized by acetalization and direct quaternization reaction. Afterwards, composite anion exchange membranes based on imidazolium‐ and quaternary ammonium‐ functionalized PVA were used for direct methanol alkaline fuel cell applications. ¹H NMR and Fourier transform infrared spectroscopy data indicated that imidazole functionalized PVA was successfully synthesized. Inductively coupled plasma mass spectrometry data demonstrated that the imidazolium structure was efficiently obtained by direct quaternization of the imidazole group. Composite anion exchange membranes were fabricated by application of the functionalized PVA solution on the surface of porous polycarbonate (PC) membranes. Fuel cell related properties of all prepared membranes were investigated systematically. The imidazolium functionalized composite membrane (PVA‐Im/PC) exhibited higher ionic conductivity (7.8 mS cm^?1 at 30 °C) despite a lower water uptake and ion exchange capacity value compared to that of quaternary ammonium. In addition, PVA‐Im/PC showed the lowest methanol permeation rate and the highest membrane selectivity as well as high alkaline and oxidative stability. Dynamic mechanical analysis results reveal that both composite membranes were mechanically resistant up to 10⁷ Pa at 140 °C. The superior performance of imidazolium functionalized PVA composite membrane compared to quaternary ammonium functionalized membrane makes it a promising candidate for direct methanol alkaline fuel cell applications. © 2020 Society of Chemical Industry     

Performance evaluation of a bubble generator and a bubble separator designed for the gas removal system of a small thorium molten salt reactor

In the present study, a bubble generator and a bubble separator were designed and evaluated for an independent off-gas removal system of a small thorium molten salt reactor(TMSR) with reference to the design of the Oak Ridge National Laboratory(ONRL). The bubble generator employed a Venturi tube as its main body owing to its simplicity and highly reliable structure. A centrifugal separator was used as the bubble separator, taking advantage of the kinetic energy of fluid to create a centrifugal force to separate gas bubbles from the mixture flow. Both the bubble generator and the separator were demonstrated to have good potential to meet the performance requirements of an off-gas removal system for a small TMSR. With water and air as the working fluids, for the final designs of the two key pieces of equipment, a liquid flow rate exceeding 15 m~3·h~(-1) can essentially make their performance meet the requirements of the off-gas removal system in terms of the average size of the generated bubbles and gas separation efficiency.     

Interpolymer radical coupling: A toolbox complementary to controlled radical polymerization

The current review focuses on the relevance and practical benefit of interpolymer radical coupling methods. The latter are developing rapidly and constitute a perfectly complementary macromolecular engineering toolbox to the controlled radical polymerization techniques (CRP). Indeed, all structures formed by CRP are likely to be prone to radical coupling reactions, which multiply the available synthetic possibilities. Basically, the coupling systems can be divided in two main categories. The first one, including the atom transfer radical coupling (ATRC), silane radical atom abstraction (SRAA) and cobalt-mediated radical coupling (CMRC), relies on the recombination of macroradicals produced from a dormant species. The second one, including atom transfer nitroxide radical coupling (ATNRC), single electron transfer nitroxide radical coupling (SETNRC), enhanced spin capturing polymerization (ESCP) and nitrone/nitroso mediated radical coupling (NMRC), makes use of a radical scavenger in order to promote the conjugation of the polymer chains. More than a compilation of macromolecular engineering achievements, the present review additionally aims to emphasize the particularities, synthetic potential and present limitations of each system.     

FZJ—1G型螺杆分装机盖胶塞机构的技术改造

为提高FJZ－1G型螺杆分装机盖塞机构的自动盖塞合格率,对该机构进行了技术改造,改造后,故障率几乎为零,盖塞合格率接近100％。     

正弦波纹挡板式沉降器内流动特性

采用VOF模型对正弦波纹式入口挡板的重力非均相沉降器内流场进行数值模拟研究。对比了正弦波纹挡板与平挡板的平均流场分布情况,分析了沉降器的轴向流速均一程度(λ₁)随时间演化特性,探究了λ₁和面积加权平均湍流强度(I_a)在沉降器内空间分布特性;引入流场均稳指标USC,研究了冲击间距(L_b/D)对USC的影响。结果表明:正弦波纹挡板作为入口构件可以有效降低返混。在0.84b/D减小,平挡板沉降器内流场的λ₁基本不变,但正弦波纹挡板沉降器内流场的λ₁降低,且对I_a的影响不明显。对比平挡板,正弦波纹挡板可以有效降低轴向速度的梯度,使返混区面积减小,流场稳定性提高。随着L_b/D增加,USC值呈现多峰值趋势,L_b/D=2.17时正弦波纹板沉降器的USC取得极大值为14.68,较平挡板提高了...     

新型上浆工艺的研究

作为新型的上浆工序,利用水溶性PVA长丝,将经纱通过水溶性PVA长丝的卷装中心,在水溶性长丝退绕过程中,PVA长丝包绕在经纱上,利用该合捻纱,通过上浆罗拉上浆的方法.对获得的浆纱,通过耐摩性、浸透度的测试作出评价,表明此方法的可行性,为简化上浆工序,降低成本提供了依据.     

Nonwoven viscose fabric-polyvinyl alcohol based flexible composite

Development of ecofriendly packaging materials is still a challenging area. Researchers are continuously working to improve the mechanical and barrier properties of the different polymers which are used in the packaging industry. Selection of reinforcement and matrix for any composite are based upon end use applications. The novelty of the work is development of fully biodegradable, flexible, lightweight biocomposite by reinforcing needle punched flexible nonwoven viscose fabric to the PVA solution. The effect of PVA concentration and areal density of viscose fabric on the properties of prepared composite is examined. The composite thus prepared is assessed in terms of mechanical, thermal, breathability, and UV blocking properties. The nonwoven viscose-PVA composite shows excellent improvement in tensile strength of 100% to 300% with respect to PVA film of equivalent concentration for two different areal densities of viscose fabric. The composite also exhibits improved thermal stability and UV blocking property with respect to parent components. However, a reduction in flexibility (with respect to PVA film) as well as breathability (with respect to viscose fabric) of the composite is observed. Based upon the improved performance of the viscose-PVA composite in terms of mechanical properties, UV and water vapor permeability, it seems that the composite has a strong potential for application in the packaging sector as a flexible as well as biodegradable composite.