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101.
The polyesterification and isomerization reaction of 1,6-hexane diol and maleic anydride in a melt without catalyst was studied by 13C and 1H n.m.r. spectroscopy. The structure and concentration of oligoester species during the polyesterification and isomerization were determined depending on the reaction temperature and time. According to the number and configuration of repeating units determined from 1H n.m.r. spectra kinetics of both reactions were also considered. The degree of isomerization is continuously increasing in the investigated reaction range. 相似文献
102.
mPE-g-MAH对HDPE/木粉复合材料的改性 总被引:5,自引:0,他引:5
采用废木粉填充高密度聚乙烯(HDPE)制备木塑复合材料。采用马来酸酐接枝茂金属聚乙烯(mPE—g-MAH)对复合材料进行增容和增韧,并阐述了它的增容和增韧机理。讨论了mPE—g—MAH用量对复合材料的力学性能如拉伸强度、冲击强度、弯曲强度、弯曲模量的影响。结果表明,mPE—g—MAH不仅可明显提高复合材料的强度和韧性,而且也使材料的弯曲模量有了一定的提高。当其质量分数为16%时,复合材料的拉伸强度、冲击强度分别由原来的16.2MPa和4.5kJ/m^2提高到30.5MPa和9.8kJ/m^2。 相似文献
103.
The fabrication of monolayers composed of nordihydroguaiaretic acid (NDGA), and hybrid films composed of NDGA-flavin adenine dinucleotide (FAD) adsorbed films was performed in neutral aqueous solutions to produce electrochemically active thin films exhibiting one and two redox couples, respectively. An electrochemical quartz crystal microbalance and cyclic voltammetry were used to study the in situ growth of the NDGA and hybrid NDGA/FAD film monolayers. The NDGA modified film electrocatalytically oxidized NADH, ascorbic acid, dopamine, and N2H4 in neutral aqueous solutions. Well-separated voltammetric peaks were observed for dopamine and uric acid mixtures, and also for ascorbic acid and uric acid mixtures using the NDGA/GC modified electrode. When transferred to various aqueous buffered solutions, the two redox couples of the NDGA/FAD hybrid film and their formal potentials were observed to be pH-dependent. The electrocatalytic oxidation and reduction of NADH and NAD+ by a NDGA/FAD hybrid film in neutral aqueous solutions was carried out, and the electrocatalytic oxidation of NADH was performed using a NDGA/FAD hybrid film. 相似文献
104.
王加龙 《现代塑料加工应用》2003,15(5):17-19
研究了采用过氧化物DCP、将DCP制成母料、在DCP母料中加入分散剂、在加入分散剂的母料中再加入助交联剂MAH(顺丁烯二酸酐)这4种条件下LDPE的交联情况,讨论了DCP的加入量对LDPE交联度的影响,同时讨论了交联度随交联时间的变化。 相似文献
105.
106.
In the present study, the effects of charge‐transfer complex formation and intramolecular fragmentation (side‐chain lactonization) in radical copolymerization of tert‐butyl vinyl ether (t‐BVE) with anhydrides of maleic (MA) and citraconic (CA) acids and the structure–thermal behavior relationships of the resulting copolymers were examined using the 1H‐NMR, FTIR, DSC, and TGA analysis methods. It was shown that copolymerization under the chosen conditions proceeded through intramolecular fragmentation with the formation of γ‐lactone units. Side‐chain fragmentation of t‐BVE–MA and t‐BVE–CA copolymers also was confirmed by TGA and DSC analysis. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2455–2463, 2006 2006 相似文献
107.
Thermal characterization of maleic anhydride‐styrene‐allyl propionate (MA‐St‐AP) terpolymer and its ester derivatives named as n‐alkyl maleate and shown as nPr MA‐St‐AP, nBu MA‐St‐AP, nPn MA‐St‐AP, and nBz MA‐St‐AP was carried out. The thermal characterization was performed using thermal analysis techniques such as TGA, DTA, DSC, and TMA. Different results were observed between the original terpolymer and its ester derivatives. Thermal stabilities of the terpolymer and its ester derivatives were compared by using various measurements plotted as TGA, DTA, DSC, and TMA curves. The increase in the alcohols' carbon numbers added to the original terpolymer results in ester derivatives with different thermal stability behavior. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 600–604, 2007 相似文献
108.
Douglas G. Hayes Robert Kleiman 《Journal of the American Oil Chemists' Society》1995,72(11):1309-1316
Eight lipases were screened for their ability to synthesize estolides from a mixture that contained lesquerolic (14-hydroxy-11-eicosenoic)
acid and octadecenoic acid. With the exception ofAspergillus niger lipase, all 1,3-specific enzymes (fromRhizopus arrhizus andRhizomucor miehei lipases) were unable to synthesize estolides.Candida rugosa andGeotrichum lipases catalyzed estolide formation at >40% yield, with >80% of the estolide formed being monoestolide from one lesquerolic
and one octadecenoic acyl group:Pseudomonas sp. lipase synthesized estolides at 62% yield, but the product mixture contained significant amounts of monoestolide with
two lesquerolic acyl groups as well as diestolide. ImmobilizedR. miehei lipase was chosen to catalyze the esterification of mono-and polyestolide, derived synthetically from oleic acid, with fatty
alcohols or α,ω-diols. Yields were >95% for fatty alcohol reactions and >60% for diol reactions. In addition, the estolide
linkage remained intact through the course of the esterification process. Esterification of estolides improved the estolide’s
properties—for example, lower viscosity and higher viscosity index—but slightly raised the melting point. Estolides and, particularly,
estolide esters may be suitable as lubricants or lubricant additives. 相似文献
109.
利用豆油脚脂肪酸-松香-甘油-苯酐,采用脂肪酸法制备松香改性醇酸树脂。通过实验得到较佳工艺条件,确定经济合理的配方和各种原料用量,制备出符合标准的醇酸树脂产品,为加工成各色醇酸调合磁漆和脂肪酸调合磁漆奠定基础。此方法有效利用了废弃的大豆下脚料以代替市场紧缺的天然桐油和亚麻油,为豆油脚在涂料工业上的开发和利用开辟了新途径。 相似文献
110.