含硅聚氨酯的制备及其动力学研究

以3-氨基丙基三乙氧基硅烷（KH550）、丙烯酸羟乙酯（HEA）、2,4-甲苯二异氰酸酯、对甲酚为原料,制备含硅聚氨酯。用红外光谱对反应合成过程进行跟踪测定,发现端-NCO的聚氨酯预聚物和对甲基苯酚的封端反应在无催化剂条件下为二级反应,当加入催化剂三乙胺后该反应在发生初期为一级反应。无催化剂条件下该反应的活化能为46.96 kJ/mol,催化剂加入量为0.1%时反应的活化能为30.28 kJ/mol,催化剂加入量为0.3%时反应的活化能为18.16 kJ/mol,反应的活化能随催化剂加入量的增加而降低。     

Synthesis of acicular α-Bi2O3 microcrystals by microwave-assisted hydrothermal method

ABSTRACT

Materials based on bismuth(III) oxide are candidate to be used in optical and electronic devices because of their properties such as a variable band gap, photoconductivity, photoluminescence, high refractive index, and dielectric permittivity. These properties are dependent of several factors, e.g., present phases and crystal morphology. The microwave-assisted hydrothermal method (MAH) is a fast and efficient approach of synthesis to obtain semiconductor powders. However, the synthesis of monoclinic bismuth oxide (α-Bi₂O₃) with acicular morphology by MAH was not found in literature. In this paper, microcrystals of acicular α-Bi₂O₃ (monophasic) were successfully obtained by MAH using a synthesis temperature of 80°C for 0.5?h. X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron, and transmission electron microscopies showed the formation of a monoclinic structure (space group P21/c) with acicular morphology that grew along the [001] direction. The temperature and time necessary to synthetize acicular microcrystals were significantly lower than those found for acicular microcrystals obtained by conventional hydrothermal method.     

水热法制备粉煤灰钙基脱硫剂

文章研究了利用粉煤灰和Ca(OH)2为原料水热反应制备钙基脱硫剂。影响钙基脱硫剂钙剂利用率最主要的因素是水浴温度(TH),它的最佳值是90℃;温度上下浮动5℃,利用率将降低20%。其次还有水浴温度、粉煤灰与Ca(OH)2质量比(FC)、水固比(LS),这些因素的波动对利用率的影响相对较小。水浴时间(tH)达到8 h以上,FC在5～10的范围内变化,LS在8～18的范围内变化均能制备具有较高利用率的钙基脱硫剂。     

浦钢搬迁工程施工准备规划与实践

结合浦钢搬迁工程,从自然条件、平面及空间布置、资源需求、施工进度控制等方面,对新建大型冶金工程项目施工准备工作总体规划和组织实施工作进行了总结。     

数据准备软件DPS的开发与设计

对于SMT工艺技术人员来说,一个重要的工作就是从CAD设计系统中获取必要的特征数据,经过相应的整理、转换,使之能成为符合要求的格式。在数据准备过程中发现了一些问题,例如CAD设计系统和SMT设备定义的元件角度不一样等。为解决这些问题,文中开发了数据准备系统DPS,它能自动检查并修正元件角度。此外,DPS能处理多种格式的CAD数据,大幅度提高生产效率,证明了本解决方案的优越性和高效性。文中详细介绍了DPS软件的设计与开发中的思想、方法和经验,并着重探讨了坐标数据的处理和转换。     

细颗粒LLM-105的制备及其热性能

采用溶剂-非溶剂重结晶技术制备了类球形和立方体结构两种不同晶形的细颗粒2,6-二氨基-3,5-二硝基吡嗪-1-氧化物(LLM-105),重均平均粒径D50分别为2.750 μm和6.206 μm,撞击感度为35.5 cm和34.7 cm.采用热重-微商热重(TG-DTG)和差示扫描量热法(DSC)对LLM-105进行了...     

一种用于流水线A/D转换器的低功耗采样/保持电路

文章介绍了一种适用于10位20MS／s流水线A／D转换器的采样／保持（S／H）电路。该电路为开关电容结构，以0．6μm DPDM CMOS工艺实现。采用差分信号输入结构，降低对共模噪声的敏感度，共模反馈电路的设计稳定了共模输出，以达到高精度。该S／H电路采用低功耗运算跨导放大器（OTA），在5V电源电压下，功耗仅为5mW。基于该S／H电路的流水线A／D转换器在20MHz采样率下，信噪比（SNR）为58dB，功耗为49mW。     

环氧化天然橡胶制备反应动力学

采用适当提高反应温度、减小甲酸和过氧化氢用量的方法制备不同环氧化程度（Ｂ）的环氧化天然橡胶（ＥＮＲ）,并利用质量作用定理,从ＥＮＲ的制备基本反应式推导出ＥＮＲ的制备反应动力学方程,讨论了Ｂ与反应温度和时间及甲酸、过氧化氢用量的关系。结果表明,用过氧甲酸对ＮＲ进行环化改性制备ＥＮＲ的反应为二级反应,对ＮＲ和过氧化氢的反应则为一级反应。求出的反应速率常数ｋ４为１１２５×１０－４ｄｍ３·（ｍｏｌ·ｓ）－１,活化能为８２６７４ｋＪ·ｍｏｌ－１;Ｂ与过氧化氢用量之间为线性关系     

Sample selection for visual domain adaptation via sparse coding

Visual domain adaptation has attracted much attention and has made great achievement in recent years. It deals with the problem of distribution divergence between source and target domains. Current methods mostly focus on transforming images from different domains into a common space to minimize the distribution divergence. However, there are many irrelevant source samples for target domain even after the transformation. In order to eliminate the irrelevant samples, we develop a sample selection algorithm using sparse coding theory. We do the sample selection in a common subspace of source and target data to find as many as relevant source samples. In the common subspace, data characteristics are preserved by using graph regularization. Therefore, we can select the most relevant samples for our target image classification task. Moreover, in order to build a discriminative classifier for the target domain, we use not only the common part of source and target domains learned in the common subspace but also the specific part of target domain. The algorithm can be extended to handle samples from multiple source domains. Experimental results show that our visual domain adaptation method on the image classification tasks can be very effective for the state-of-the-art datasets.     

数据准备软件DPS的开发与设计

对于SMT工艺技术人员来说,一个重要的工作就是从CAD设计系统中获取必要的特征数据,经过相应的整理、转换,使之能成为符合要求的格式。在数据准备过程中我们发现了一些问题,例如CAD设计系统和SMT设备定义的元件角度不一样等等。为解决这些问题,作者开发了数据准备系统DPS,它能自动检查并修正元件角度,此外,DPS能处理多种格式的CAD数据,犬幅度提高生产效率,证明了本解决方案的优越性和高效性。文章详细介绍了DPS软件的设计与开发中的思想、方法和经验,并着重探讨了坐标数据的处理和转换。