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51.
52.
Gold (Au) and platinum (Pt) were used as the working electrode material to detect cholesterol in solution through enzymatically generated hydrogen peroxide (H2O2). Both gold and platinum were capable of detecting cholesterol through the electrochemical oxidation of H2O2, and could be used as the working electrode material. By comparison, however, Au was preferable over Pt in terms of higher response current and better sensitivity. Therefore, Au was chosen as the working electrode material for the fabrication of a thick-film screen-printed cholesterol biosensor consisting of three electrodes on an alumina substrate (working: Au, reference: Ag/AgCl, and counter: Au). The immobilization of the enzyme cholesterol oxidase (ChOx, E.C. 1.1.3.6) on the Au working electrode was achieved using a self-assembly approach. A thiol, 3-mercaptopropionic acid (MPA), was self-assembled onto the gold working electrode forming a thin organic layer that served as the anchor for the enzyme immobilization. 1-Ethyl-3(3-dimethylamino propyl)carbodiimide methiodide (EDC) was then used to immobilize the enzyme ChOx covalently on the gold working electrode through the carbodiimide coupling between the carboxyl (–COOH) groups of the self-assembled MPA layer and the amino (–NH2) groups of the enzyme. Electrochemical measurements showed that this biosensor responded well to cholesterol, confirming that the self-assembly immobilization method was effective. The reproducibility, the interference, and the storage stability of the biosensor were studied and assessed. 相似文献
53.
分析了污水厂钢丝绳牵引式粗格栅机的使用情况,针对粗格栅机效率低、易出故障等缺点,提出了利用PLC对其进行改进和全方位监控的方法。基于PLC的粗格栅机全方位监控方案增加了启动报警、运行超时报警、液位报警和皮带机报警等部件,对PLC程序流程网进行了详细说明。实际应用表明,该控制系统结构简单、可靠性高、较好地实现了提高工作效率、保护粗格栅机的目的。建议可在各大中型现代化城市中推广。 相似文献
54.
Efim Broide 《Journal of Superconductivity and Novel Magnetism》2008,21(2):97-105
A novel system of electromagnetic separation (EMS) employing an alternating magnetic field (RMF) of suspended HTSC-particles
in liquid nitrogen is described (Broide in Supercond. Cryoelectron. Summer:33, [1998]; Broide in Superconductor Week 12, No. 21, [1998]; Broide in US Patent 5,919,737, [1999]; Broide et al. in International Conference, Barcelona, Spain, [1999]).
The EMS method is realized at temperatures close to those of the HTSC transition by extracting particles of YBaCuO, BiSrCaCuO,
BiPbSrCaCuO, and NdBaCuO with optimal physical properties from the powders, concentrating particles with a greater critical
current at one side. This process has shown great promise in its ability to produce high quality superconducting materials,
being also an effective method of testing and analyzing powders to determine if synthesis adjustments are necessary in order
to achieve optimal materials properties.
In addition, a correlation between the speed of YBa2Cu3O
x
particles and the percentage of oxygen (O
x
) was discovered. Since the temperature of the superconducting (SC) transition (T
c
) practically has a linear dependence on the oxygen percentage, the knowledge of the speed of the HTSC-particles during the
separation, one may immediately give (within 10 s) the percentage of the oxygen in the chemical structure of the new HTSC
materials.
The EMS method enables statistical improvement in the uniformity of HTSC powders by decreasing the quantity of defective zones
in the separated powders, the number of nonvalid admixtures, and thus, an increase in T
c
and I
c
(critical current). At the same time, ΔT
c
the width of the SC-transition is decreased.
Three YBa2Cu3O
x
thick films have been produced by the paint method on MgO substrates from the source material, the separated high-quality
concentrate, and the low-quality remnant (tail).
The films exhibit different structural and electrical properties, in particular, different I
c
, and ΔT
c
.
For the film that was made from the high-quality concentrate, ΔT
c
is decreased from 5–7 K to 1–2 K. I
c
is increased by a factor of 2–5 from the I
c
of the source material (before EMS) and T
c
is changed from 89 K to 93 K. Thick films, which had been produced from low-quality remnant (tail) do not have SC transition
down to 77 K.
相似文献
55.
Giovanni Bolelli Johannes Rauch Valeria Cannillo Andreas Killinger Luca Lusvarghi Rainer Gadow 《Materials Letters》2008,62(17-18):2772-2775
High-Velocity Suspension Flame Spraying (HVSFS) has recently emerged as a potential alternative to conventional HVOF-spraying: employing liquid suspensions instead of dry powder feedstock enables the use of very fine grain-sized particles, resulting in small-sized lamellae. Thin, low-porosity coatings can thus be manufactured. This paper details the first attempt at manufacturing glass coatings using the HVSFS technique: these coatings can have multiple applications (anti-corrosion coatings on metal and ceramic substrates, bio-compatible coatings, etc). A CaO–ZrO2–SiO2 glass frit was selected for this attempt. Excellent potentialities emerged (very low porosity), but some problems still existed (big “droplet-like” features on the coating surface), which have recently been largely overcome thanks to process modifications. 相似文献
56.
Hayato Takasago Eishi Gofuku Mitsuyuki Takada Yoshiyuki Morihiro 《Journal of Electronic Materials》1989,18(5):651-655
When electric resistivity of Thick Film Resistor (TFR) is adjusted to the desired value, laser beam is irradiated onto the
resistor material so that a part of the resistor material is instantaneously vaporized and cut away. This conventional laser
trimming method to adjust the resistivity of TFRs is an indispensable technique for manufacturing elec-tronic devices such
as hybrid ICs. A peculiar phenomena was revealed by us, that is, when specially selected pulse laser beams were irradiated
to TFR, the TFR was surface modified without cutting grooves, and then resistivity of the TFR was decreased. We completed
the advanced laser process to apply this peculiar phenomena. 8 By comparing with conventional trimming processes, we can show
prominent features of the advanced process, for example, resistivity of fine size TFR (300 micrometers-width and under) can
be easily controlled. The decrease in resistivity of the TFR is considered to result from the decrease in specific resistivity
of glass in the TFR. Because it is considered that the glass in the TFR is heavily doped with ruthenium impurities during
the surface modification due to results of morphology observations and x-ray diffraction analysis. We have applied this advanced
laser process to fine size TFR (300 micrometers-width), and developed high density hybrid ICs. 相似文献
57.
The cure degree must be as uniform as possible during the manufacture cycle of polymer–matrix composite laminate to obtain parts without defects. Thermal cycle recommended by technical sheet is usually suitable for thin components, so its redesign is necessary to solve unconformities for thick laminate parts, which usually show these problems. In this study, a methodology to optimize the cure cycle of a thick composite laminate, presented in previous studies, has been validated by a more reliable direct method based on dielectrical analysis through the use of an interdigital sensor capable to measure the local cure degree trend. 相似文献
58.
59.
国内外厚煤层大功率电牵引采煤机机电一体化新技术 总被引:2,自引:0,他引:2
介绍国内外大功率厚煤层电牵引采煤机的机电一体化新技术,包括总体技术、交流变频电牵引技术、工况检测、故障诊断技术、自动调高技术、远程通讯和集中控制技术。 相似文献
60.
一种测量混浆浓度的新型传感器,其结构简单、成本低、精度高且可靠性强。不仅可以应用于混浆浓度的测量,而且能够应用于其它酸、碱、盐等强腐蚀性溶液的浓度测量,在生产实际中应用前景广阔。 相似文献