Alkaline treatment kinetics of calcium phosphate by piezoelectric quartz crystal impedance

Calcium phosphate film was prepared by electrochemical deposition technology. Subsequently, the alkaline treatment process of calcium phosphate film in 0.1 mol/L NaOH solution was monitored on real time by the piezoelectric quartz crystal impedance (PQCI) technique. The variations of morphology and composition for the alkaline treatment products were characterized by scanning electron microscopy (SEM), Fourier transform infrared (FT-IR) and X-ray diffraction (XRD), respectively. The dynamic variations of calcium phosphate can be characterized by the change of equivalent circuit parameters. The results show that the forming process of hydroxyapatite (HA) is composed of three stages: (1) acidic calcium phosphate dissolution; (2) phase transformation; and (3) HA formation. Furthermore, the correlative kinetic equations and parameters are obtained by fitting the static capacitance (C _s)—time curves. Foundation item: Project(2005CB623901) supported by the Major State Basic Research and Development Program of China     

Mg2+掺杂的LiFePO4材料的共沉淀合成与表征

提出了一种采用共沉淀法合成镁掺杂的锂离子正极材料LiFePO4的新方法,研究了合成条件,采用XRD,SEM,循环伏安测定,电化学阻抗谱分析,以及充放电测试对合成的材料作了表征分析．结果表明,采用共沉淀合成方法可以获得性能良好的LiFePO4;Mg^2＋掺杂对LiFePO4结构没有产生明显的影响,但掺杂量的大小对LiFePO4的放电性能有较大影响．     

掺Er^3＋镓磷酸盐玻璃的光学性质

利用熔融淬火法制备了摩尔分数为40．8Ga2O3-58．0NaPO3-1．2Er2O3掺Er^3＋镓磷酸盐玻璃,测试并研究了样品中Er^3＋的吸收光谱、1．5μm发射光谱,根据Judd-Ofelt理论计算了Er^3＋离子强度参量Ωt（t=2,4,6）及自发辐射概率、荧光分支比、自发辐射寿命．结果表明,Er3＋1．5μm发射光谱半峰全宽达到40nm．同时,利用McCumber方法计算了Er^3＋4 I13／2→^4I15／2跃迁的受激发射截面,峰值达到6．10×10^-21cm^2,测定了Er^3＋4I13／2能级荧光寿命为4．88ms,^4I13／2能级量子效率为56．3％．     

层状磷酸锆的制备及插层研究

具有层状结构的磷酸锆α-Zr（HPO4）2·H2O通过粉末X-射线衍射（XRD）,振动光谱（红外IR和拉曼光谱Raman）,热分析仪（TG）,透射电子显微镜（TEM）,扫描电子显微镜（SEM）和BET氮气吸附等手段进行了表征.所制备的α-Zr（HPO4）2·H2O的BET表面积为12.29 m^2/g.研究了α-Zr（HPO4）2·H2O的插入行为,与四甲基溴化铵和十六烷基三甲基溴化铵的插入反应表明插入是完全的,层间距分别增加了0.46 nm和1.68 nm,且插入化合物的荧光性质在室温被检测.     

熟料粒度对骨粉/磷酸钙生物骨水泥结构与性能的影响

采用新方法首次将动物骨中的鱼骨引入到磷酸三钙和磷酸氢钙等原料体系中通过高温烧结制备磷酸钙基生物骨水泥（CPC）,以柠檬酸和柠檬酸钠的缓冲液为固化液、按一定的液固比制备固化试样,通过扫描电子显微分析（SEM）和力学性能测试等方法,研究了熟料粒度对其固化试样结构与抗压强度的影响.结果表明：制备过程中骨水泥粉末的粒度对其固化试样的微观结构及其抗压强度有着较为显著的影响,通过调整骨水泥粉末的粒度可达到优化其固化试样的微观结构和改善其力学性能的目的.     

含磷苯丙乳液的合成

采用预乳化工艺,半连续种子聚合法,通过丙烯酸丁酯(BA)、苯乙烯(St)、丙烯腈(AN)、丙烯酸(AA)以及磷酸酯功能性单体Y自由基聚合反应,合成了一种功能性苯丙乳液.考察了乳化剂种类、乳化剂用量、乳化剂复配比、引发剂用量、软硬单体比、功能单体AA的用量以及含磷单体Y的用量对乳液及涂膜性能的影响.结果表明,采用阴离子型...     

高炉法钙镁磷肥探料尺自动跟踪探料技术改造

针对钙镁磷肥生产中高炉探料存在的问题 ,对原自动探料装置的电气控制回路及跟踪装置进行改造 ,增加了探料跟踪最大极限位置 ,获得成功。改造后的自动跟踪探料尺 ,动作准确可靠 ,运行稳定 ,效率高 ,节能降耗 ,直接经济效益每年约 2 5万元 ,提高台时产量间接经济效益每年可达 4 0万元     

黄麦岭磷矿矿石工艺矿相学研究

经红外光谱测试及单矿物化学分析，确定了磷灰石的种类；通过显微镜观察，系统地研究了不同自然类型磷矿石中磷灰石的嵌布嵌镶关系；利用线测法测定了磷灰石的嵌布粒度；采用一粗一精一扫浮选流程，按原来的浮选条件和药剂制度所得精矿，研究了其单体解离度及选矿回收率；提出了改进选矿工艺流程的可能途径和方法。     

Evaluation of the agronomic effectiveness of natural and partially acidulated phosphate rocks in several soils using32P isotopic dilution techniques

The agronomic effectiveness of two natural phosphate rocks (PRs) from North Carolina (USA) and Togo and their 50% partially acidulated products (PAPRs) was evaluated in two greenhouse experiments using³²P isotopic dilution techniques, namely L and A_L values.In the first experiment rye grass was grown in a soil from Ghana. While the proportion of P in the plant derived from the P fertilizer (Pdff) ranged on. the average from about 10% for the PRs up to 80% for the PAPRs, the P fertilizer recovery was less than 1% for a 60-day growth period. In the second experiment, average values of P in the maize plants derived from the PAPRs ranged from 35% to 75% in 3 different soils. Both PRs were ineffective with the exception of North Carolina PR in the Seibersdorf soil. The P fertilizer recovery was 0.25% for the North Carolina PR in this soil whereas the recovery values ranged from 1.2% to 1.6% for the PAPRs.Mean values of the relative fertilizer efficiency estimated from the L values of each soil were less than 1% for the PRs whereas the values for the PAPRs which were dependent on soil type ranged from 20% up to 45%. The coefficient of relative effect of partial acidulation, that was calculated from the ratio of A_L values for PR and PAPR in each soil indicated that partial acidulation increased the effectiveness of the natural PRs in all soils under study.This study showed that the use of³²P isotope dilution techniques allows an accurate measurement of the P availability from natural and modified PR products to crops. Another advantage is that quantitative comparison of the P sources under study, PRs and PAPRs in this case, can be made even in soils where there is no response to the applied P sources.     

瓮福磷矿选矿厂精矿仓设计

瓮福磷矿选矿厂精矿仓首次采用网架式地面矿仓，造价低，空间利用率高，设备运行平稳可靠，操作灵活方便，工作环境好。超长梭式胶带布料机的设计也是成功的。