Allocation of Scarce Water Resources Using Deficit Irrigation in Rotational Systems

On irrigation schemes with rotational irrigation systems in semiarid tropics, the existing rules for water allocation are based on applying a fixed depth of water with every irrigation irrespective of the crops, their growth stages, and soils on which these crops are grown. However, when water resources are scarce, it is necessary to allocate water optimally to different crops grown in the irrigation scheme taking account of different soils in the command area. Allocating water optimally may lead to applying less water to crops than is needed to obtain the maximum yield. In this paper, a three stage approach is proposed for allocating water from a reservoir optimally based on a deficit irrigation approach, using a simulation-optimization model. The allocation results with a deficit irrigation approach are compared for a single crop (wheat) in an irrigation scheme in India, first with full irrigation (irrigation to fill the root zone to field capacity) and second with the existing rule. The full irrigation with a small irrigation interval was equivalent to adequate irrigation (no stress to the crop). It is found that practicing deficit irrigation enables the irrigated area and the total crop production in the irrigation scheme used for the case study to be increased by about 30–45% and 20–40%, respectively, over the existing rule and by 50 and 45%, respectively, over the adequate irrigation. Allocation of resources also varied with soil types.     

Rolling and Lifting Probabilities for Sediment Entrainment

This study addresses the rolling and lifting probabilities for sediment entrainment by incorporating the probabilistic features of the turbulent fluctuation and bed grain geometry. The lognormally distributed instantaneous velocity and uniformly distributed initial grain position, along with a relation between lift coefficient and particle Reynolds number, are used to extend the theoretical formulation of the entrainment probabilities in smooth-bed flows. The two threshold conditions identified herein enable us to precisely define the probabilities of entrainment in the rolling and lifting modes. The results obtained in this study coincide well with the published data. The lifting probability increases monotonously with the dimensionless shear stress θ, which is consistent with the earlier results yet displays improved agreement with the experimental data. The maximum value of rolling probability, with a magnitude of 0.25, occurs at θ ≈ 0.15. For θ<0.05 (or θ>0.6), the rolling (or lifting) probability makes up more than 90% of the total entrainment probability and thus can be used as an approximation to the total probability of entrainment. The proposed rolling and lifting probabilities are further linked to the two separate criteria for incipient motion to explore the critical entrainment probabilities. The results reveal that a consistent probability corresponding to the critical state of sediment entrainment cannot be found.     

Complete oxidation of methane at low temperature over Pt and Pd catalysts for the abatement of lean-burn natural gas fuelled vehicles emissions: influence of water and sulphur containing compounds

The catalytic activity of fresh Pd and Pt catalysts supported on γ-alumina in the complete oxidation of CH₄ traces under lean-burn conditions was studied in the presence or the absence of water or H₂S. Steam-aged catalysts were also studied in order to simulate long-term ageing in real lean-burn natural gas fuelled vehicles (NGVs) exhaust conditions. Without water or H₂S added to the feed, Pd catalysts exhibit a superior catalytic activity in methane oxidation compared to Pt ones, whatever the catalysts were fresh or aged. The addition of 10 vol.% water vapour to the feed strongly affects the activity of the fresh Pd catalyst, thus being only slightly more efficient than the fresh Pt one. H₂S has a strong poisoning effect on the catalytic activity of Pd catalysts, while Pt catalysts are more resistant. The fresh H₂S-poisoned Pd/Al₂O₃ catalyst was studied by TPD in O₂/He. Poisoning species decompose above 873 K as SO₂ and O₂ in relative concentrations consistent with the decomposition of surface sulphate species. However, a treatment in O₂/He at temperatures as high as 923 K does not allow the complete regeneration of the catalytic activity of H₂S-poisoned Pd/Al₂O₃. A mechanism involving the poisoning of PdO by sulphate species is proposed. Different diffusion processes by which these sulphate species can migrate back and forth between PdO and the support, depending on the experimental conditions, are suggested.     

Powder Deposition in Three Parallel-Oriented Dies of Different Shapes

Uniformity of bulk density distribution during the die filling process is required to minimize quality problems, such as distortion and cracking, for powder compacts. Understanding the die filling process is necessary in ensuring a uniform powder deposition. The second-generation pressure deposition tester (PDT-II) was used to investigate the deposition process and final pressure distribution of powder filling in toroidal, cylindrical, and E-shaped dies. All tests were conducted using a spray-dried free-flowing granular powder. The results indicated that for toroidal dies: (1) the area around 0° orientation (the leeward end) had the highest pressure values (1186.7 to 2498.0 Pa), with the average pressure values of the remaining area 353.7-648.0 Pa; (2) the pressure distribution was symmetrical about the centerline parallel to the feed shoe movement direction; (3) the highest feed shoe speed (500 mm/s) led to the most nonuniform pressure distribution among the three speeds; (4) higher feed shoe speed did not always result in higher final pressure values; and (5) the right die tended to have higher final pressure values (215.0 to 2498.0 Pa) than the center die (95.4 to 2052.5 Pa). For E-shaped dies: (1) the final pressure values of the middle leg (308.9 to 760.7 Pa) were higher than those of the left and the right legs (148.9 to 530.3 Pa); (2) the area along the backside had the highest final pressure value (1054.6 to 1303.8 Pa); (3) the pressure distribution was symmetrical about the centerline parallel to the feed shoe movement direction; and (4) neither the center die nor the right die always had higher pressure values than the other one at all locations. Comparison between cylindrical and toroidal dies indicated that: (1) neither of the two die shapes (cylinder and toroid) led to consistently higher or lower final pressure values at all locations and (2) for all three feed shoe speeds, the toroidal die had higher average final pressure values in the 0° orientation.     

Non-steady-state model for kinetics of free radical polymerization, 4. Direct thermal initiation

This paper deals with the non-steady-state kinetics of direct thermal initiated polymerization. The initiation is assumed to be a bimolecular reaction of the monomer. The relationship between the radical concentration and the monomer conversion is rigorously derived. In further treatment a few very close approximations are introduced based on the fact that the number of monomer molecules reacting in the initiation step is much less than that consumed in the propagation step for a process producing high polymer, and the value of the rate constant for propagation or chain transfer is much lower than that for chain termination. Expressions for various molecular parameters, such as molecular weight distribution, number-average and weight-average degrees of polymerization, and dispersity, are given. Several numerical examples are provided.     

分析再热器超温爆漏与水冷壁结焦控制量的关系

文章介绍了宝钢自备电厂在改善锅炉燃烧工况，控制锅炉水冷壁结焦所采取的技术措施，分析了锅炉水冷壁结焦量与锅炉二次再热器烟气出口平均温度的关系，为解决锅炉水冷壁结焦所引发的二次再热器超温爆漏问题提供了依据。     

镨掺杂分布对1.3μm光纤放大器特性影响

对掺氟化镨玻璃光纤放大器的小信号增益，用广义的高斯近似公式可获得精确的分析表达。文中研究了限制光纤芯层中央部分的镨掺杂对光纤放大器特性的影响，结果发现限制镨掺杂分布能改进光纤放大器的工作效率，且截止波长比芯层全部均匀掺镨的光纤更长。     

Finite Element Analysis of a Moving Boundary Value Problem

A finite element formulation and the solution of a set of nonlinear coupled heat and mass transfer equations for a two-phase system with a moving evaporation interface is presented. The interface condition takes into account the moisture transfer balance at the moving boundary. The finite element results were compared with existing results for a single phase system for model validation. In the two-phase system, the movement of evaporation front has an appreciable effect on the temperature and moisture distribution inside the porous medium during drying. The effect of the nondimensional heat of vapourization parameter γ on the evaporation front, temperature and moisture distribution in porous medium was studied. The higher the value of γ, the slower is the movement of the evaporation front. The temperature decreased and the moisture content increased as the nondimensional vapourization parameter γ increased. This model has potential applications in studying the heat and mass transfer characteristics in food and biomaterials.     

大型储罐的罐壁设计

根据十万立方米浮顶油罐罐壁板应力测试的实测结果，运用应力分析程序，对罐壁板应力分布情况进行了分析和比较，通过调整罐壁板的厚度，使新设计储罐的罐壁板应力分布更加均匀、合理。