磷酸浓缩氟吸收问题的探讨

将我国现有的几种磷酸浓缩流程和实际应用效果进行比较 ,并从氟吸收机理分析探讨氟吸收级数与吸收效率的关系 ;氟硅酸浓度、温度与吸收效率的关系 ;吸收设备和雾沫分离器选型等     

己糖生产甘露醇概述

葡萄糖、果糖和甘露糖同属己糖,均是工业生产甘露醇最直接的原料.介绍了作为生产甘露醇最直接的原料三种单糖,它们之间的关系以及是如何转化为甘露醇与转化过程的机理.     

硫酸钾生产出现问题的机理分析及改进建议

曼海姆法硫酸钾生产装置出现 3个问题 :原料 KCl中有机碳的分析结果非常高 ;测定副产盐酸总酸度 ,加 1～ 2滴甲基橙不显红色 ;分析副产盐酸中 SO4 2含量超标 (≥ 0 .1% )。分析产生以上问题的原因并提出解决措施     

对苯型不饱和聚酯树脂的合成

以对苯二甲酸、乙二醇、丙二醇、富马酸及苯甲酸为原料,在辛酸亚锡作催化剂的条件下,采用直接酯化法合成了不饱和聚酯树脂,探讨了合成反应条件及不饱和聚酯与苯乙烯的相容性。     

换热器表面预处理及防腐工艺

石化换热器许多设备都由碳钢制作,需要涂镀渗防腐,为保证防腐层质量,需要进行严格的表面预处理。概述了机械与化学表面预处理及相关的防腐工艺。     

环氧氯丙烷下游产品生产现状及市场前景

论述了环氧氯丙烷的主要下游产品环氧树脂、合成甘油、氯醇橡胶等的生产现状、市场前景等,指出:我国氯碱行业应该重视这些环氧氯丙烷下游精细化工产品的开发,以促进我国环氧氯丙烷的发展。     

二甲基甲酰胺的生产

二甲基甲酰胺是性能优良的溶剂和化工原料，尤其是高纯二甲基甲酰胺在聚氨酯合成革、聚丙烯腈纤维生产中有独特的用途。本文介绍二甲基甲酰胺的生产方法和国内外生产情况。     

Investigations of surface degradation of high‐density polyethylene materials resulting from tracking,using physicochemical analysis

In the present work tracking phenomena were studied with high‐density polyethylene (HDPE) materials under dc voltage, with NH₄Cl and acid rain as contaminants. It was determined that the tracking time of the material depends on the conductivity and flow rate of the contaminant. Furthermore, physicochemical analysis by wide‐angle X‐ray diffraction studies, differential scanning calorimetry, and luminescence spectroscopy was carried out, whereupon it was concluded that the tracking process is a surface‐degradation process. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 2843–2849, 2002; DOI 10.1002/app.10260     

FTIR estimation of free fatty acid content in crude oils extracted from damaged soybeans

A user-interactive computer-assisted Fourier transform infrared (FTIR) method has been developed for estimation of free fatty acids (FFA) in vegetable oil samples by deconvolution of the infrared (IR) absorbances corresponding to the triglyceride ester and FFA carbonyl bonds. Peak areas were used to determine FFA as a percentage of the total carbonyl areas in weighed standards of refined, bleached, deodorized soybean oil containing from 0 to 5% added oleic acid. These data for percent FFA by FTIR were compared to corresponding FFA data obtained by two titration methods-the AOCS Official Method Ca 5a-40 and the Official Method with a slight modification. Correlation coefficients were 0.999 for the Ca 5a-40, 0.999 for the modified and 0.989 for the FTIR methods. FFA in samples of crude soybean oils extracted from damaged beans (0.5 to 2.1% FFA) were measured by FTIR and compared to data obtained by titration of the same samples (correlation coefficient, 0.869). To whom correspondence should be addressed at National Center for Agricultural Utilization Research, Agriculture Research Service, U.S. Department of Agriculture, 1815 North University Street, Peoria, IL 61604. ¹The mention of firm names or trade products does not imply that they are endorsed or recommended by the U.S. Department of Agriculture over other firms or similar products not mentioned.     

The dynamic adsorption of benzene vapor on the ACF activated by phosphoric acid

The dynamic adsorption behaviors of benzene vapor on phosphoric acid‐activated carbon fiber (ACF‐P) were investigated by gas chromatography. The experimental results showed that ACF‐P that was activated at >350^°C, like steam‐activated carbon fiber (ACF‐W), has good dynamic adsorption properties for benzene vapor. However, the saturation adsorption capacities of ACF‐P and ACF‐W are different. The dynamic adsorption conditions apparently do not affect the effluent concentration before the breakthrough point, but do change the operation loading and usage efficiency. The adsorbed ACF‐P can be regenerated, and good dynamic adsorbability can be recovered by heating treatment. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 1841–1847, 2002