Calculation of single adsorption isotherms from gravimetrically measured binary gas mixture adsorption isotherms on activated carbon at high pressures

A method is developed for the calculation of single-component adsorption isotherms from gravimetrically measured binary gas mixture adsorption isotherms at high pressures, at two temperatures and for different mole fractions of the gas phase. The adsorption of nitrogen/methane on active carbon Norit R1 is taken as an experimental example.     

一种基于并联机构的航天器姿态模拟装置的设计开发

航天器发射升空前进行地面测试和试验是航天器研制过程中的重要环节。文中针对一种基于并联机构的姿态模拟装置的设计开发,从位置分析、速度分析和虚拟样机的建造和仿真分析等方面对3UPS-PU并联机构进行研究,完成姿态模拟装置的设计,为航天器装配、试验和测试设备的设计提供一种新的思路。     

Intergranular oxidation of silicon in 20Cr-25Ni niobium-stabilized stainless steel at 1140–1230 K

The kinetics of intergranular oxidation of silicon in a 20Cr-25Ni Nb-stabilized stainless steel are reported, at temperatures in the range 1140–1230 K, in CO₂ at 40 bar pressure. The depth of attack increased parabolically with respect to time, with an activation energy of 335±30 kJ/mol. The mechanism of growth is discussed in terms of classical internal-oxidation theories, and an alternative explanation based on an available-space theory is developed. The internal oxidation rates in a number of different alloys are compared with diffusivities of metals in the base alloy. It is proposed that intergranular oxidation in the 20–25 Nb steel is controlled by the rate of outward diffusion of iron or chromium in the alloy.     

Deformation transition of intact coal induced by gas injection

Gas migration in coal bed is a multiple-physical process, of which not only includes gas desorption/diffusion through coal matrix and gas Darcy flow through the cleat system, but also results in deform...     

当前网络政治参与中存在的问题与对策

针对我国当前网络政治参与中存在着非法参与行为多、政务信息不公开致使公众政治参与缺乏信息基础、政府对公众网络政治参与的行为与观点缺乏回应等问题,本文提出了采取完善政治参与和网络政治参与的法治化机制,建立健全网络参政相关法规,保障公民网络参政议政权益,规范和打击非法政治参与行为;修改政府信息公开的法律法规,加大政府信息公开力度与规范网络监督机制;建立政府对公民网络政治参与的回应制度,以解决公民网络政治参与的相关问题,推动法治文明.     

Oxidation behavior and mechanism of aluminum oxynitride (AlON) at elevated temperatures

The oxidation behavior and mechanism of aluminum oxynitride (AlON) powder exposed to air at elevated temperatures between 800°C and 1300°C was investigated by X-ray diffractometry (XRD), scanning electron microscope (SEM), electron spin resonance (ESR), nuclear magnetic resonance (NMR), and simultaneous thermogravimetry, differential thermal analysis, and mass spectrometry techniques (TG-DTA-MS). The weight of AlON gradually increases to a maximum value at 1150°C and then decreases with further heating. Meanwhile, AlON powder undergoes chemical changes, as evidenced by lattice expansion, and turns eventually into alumina. ESR spectra reveal the occurrence of lone pair electrons in the oxidized products and the intensity of corresponding resonance signal increases before disappearing with the increase in temperature. Combined with the results of NMR and TG-DTA-MS, the measured data suggest that Al-N in [AlO₃N] tetrahedron and [AlO₅N] octahedron are gradually oxidized into Al-O-N group with lone pair electrons, which causes continuous weight gain and lattice expansion. Further oxidation at higher temperatures results in alumina and N₂.     

Experimental investigations of machining characteristics and removal mechanisms of advanced ceramics in high speed deep grinding

Machining characteristics and surface integrity of advanced ceramics, including alumina, alumina–titania, and yttria partially stabilized tetragonal zirconia, were studied under high speed deep grinding conditions. Material removal mechanisms involved in the grinding processes were explored. The material removal in the grinding of alumina and alumina–titania was dominated by grain dislodgement or lateral cracking along grain boundaries. The removal for zirconia was via both local micro fracture and ductile cutting. It was found that under a feed rate of 500 mm/min and for all the wheel speeds used, an increase in the wheel depth of cut (DOC) from 0.1–2 mm slightly improved the ground surface finish, but greatly prolonged the wheel life. This increase did not deepen the subsurface damage layer for the alumina and alumina–titania, but resulted in a slightly deeper damage layer for the zirconia.     

Anti-oxidation mechanism of SiC-B4C-C composites

Mixture of green petroleum coke, B4 C and SiC together with short carbon fiber were employed as starting materials, the mixture was press formed without any binder after grinding, dense and homogeneous binderless SiC-B4 C-C（carbon/ceramic） composites were then obtained after sintering. Composites thus prepared possess excellent anti-oxidation property, that is, mass loss less than IG within the temperature range from 900 to 1 100 ℃ for 10 h. Anti-oxidation mechanism was also discussed from the viewpoint of thermodynamics, excellent anti-oxidation property of materials thus prepared can be discribed to 1） solid SiO2 formed from SiC, which restrains the filtering of oxygen and simultaneously, its volume expansion brought about by the reaction takes roles both walling up the original pores and making the material more compact; 2） liquid B2O3 from the reaction of B4C not only makes the combination with C, B4 C and SiC tighter through forming solid solution, but also effect of reaction SiC（s）＋2CO（g） =SiO2 （s）＋3C（s） is an expansive process, which improves the microstructure of the material.     

On a novel press system with six links for precision deep drawing

The objective of this paper is to propose a novel press system with six links for precision deep drawing, and verify its feasibility. First, the system is presented and its advantages are discussed. Then, the kinematic analysis of the system is obtained by examining the geometry of the design. Moreover, kinematic dimensions of the variable coupling are found by using optimization method. Furthermore, the proposed approach is illustrated by a design example, its solid model for the proposed design is established, and then kinematic simulation is performed by ADAMS software. Finally, a prototype and an experimental setup are established, and the experiment is conducted. The results show that the proposed new mechanism is feasible and of reasonable accuracy. In addition, it has the advantages of easy manufacture, lower cost, higher precision, and easy adjustability.     

基于多线程和消息的局域网通信程序实现

目前大多数的局域网通信程序工作在服务器/客户机模式下.在此模式下的应用程序工作过程相对复杂且消耗资源较多.介绍了一种基于多线程技术和Windows消息机制的局域网通信程序的实现过程,使得两台网内主机可以在对等模式而不是传统的服务器/客户机模式下进行数据传输,从而简化了常见局域网通信程序编制中较为复杂的工作过程,实现了一种相对便捷的网络数据传输方式.