熔体快淬La1-xNdxFe11．5Si1．5（x=0，0．3，0.5）化合物磁性能和磁熵变

利用熔体快淬法制备了La1-xNdxFe11．5Si1．5（x=0，0．3，0.5）快淬带。通过X射线衍射和振动样品磁强计测试了回火态（1000℃，5h）La1-xNdxFe11．5Si1．5）快淬带的相组成和磁性能。结果表明：不同成分快淬带回火后均可得到稳定的NaZnl，型化合物。和常规的熔炼法相比，用熔体快淬法通过短时间的回火（1000℃，5h）可以制成具有大磁熵变的NaZn13型的化合物。用Nd替代部分的La后，居里温度略有提高，同时保持有大的磁熵变｜△S｜；并且随着Nd含量的增加，有效制冷温区有变宽的趋势。     

冷喷涂钛涂层与1Cr13不锈钢的电偶腐蚀行为

以氮气为载气,在压力为2.0MPa,载气温度为500℃的状态下,用冷喷涂的方法在1Cr13不锈钢基体上制备了钛金属涂层。经SEM观察,发现涂层的厚度较大,没有直接贯穿到基体的孔隙存在,距离基体越近的区域,涂层的孔隙率越小,XRD分析表明,涂层基本无氧化物相生成;从热力学和动力学两方面研究冷喷涂钛涂层与1Cr13不锈钢的电偶腐蚀行为,发现两者的电偶腐蚀倾向较小。     

Surface modification of spherical LiNi1/3Co 1/3 Mn1/3O2 with Al2O3 using heterogeneous nucleation process

To improve the cycle stability at high voltage and high charge/discharge rate, spherical LiNi1/3Co1/3Mn1/3O2 was coated with Al2O3 by using heterogeneous nucleation process, and the physical and electrochemical properties were studied. The SEM images show that there is a uniform coating on the modified spherical LiNi1/3Co1/3Mn1/3O2. The electrochemical tests indicate that the properties of LiNi1/3Co1/3Mn1/3O2 coated with 0.5% aluminum oxide are the best. The initial capacities are 150 and 173 mA.h/g at the rate of I C in the voltage range of 2.7-4.3 V and 2.7-4.6 V, respectively, and the discharge capacities maintain about 99% and 85% after 30 cycles, respectively. While those of the bare LiNi1/3Co1/3Mn1/3O2 are only 90% and 75%, respectively. The CV tests of LiNi1/3Co1/3Mn1/3O2 show that Al203-coating can restrain the oxide-reduction peak currents fading during the charge/discharge course.     

F/B复相钢JB800的焊接冷裂纹敏感性

采用斜Y坡口对接裂纹试验对F／B复相钢板JB800进行了抗冷裂试验，对不同预测止裂温度的碳当量公式进行了对比。结果表明,钢材的碳含量低时，可以在较高的碳当量条件下，具有较低的冷裂纹敏感性。对F／B复相钢采用CET公式预测止裂温度较为准确。同时采用计算机测定了焊接热循环，根据t100预测不同板厚的焊接止裂温度。     

Influence of chromium on the local structure and morphology of ferric oxyhydroxides

The extended X-ray absorption fine structure (EXAFS) method and transmission electron microscopy (TEM) have been used for characterizing the local structure and morphology of ferric oxyhydroxides, α-FeOOH and γ-FeOOH, with and without chromium. These ferric oxyhydroxide powders were prepared from aqueous solutions containing iron and chromium ions. Radial structural functions for iron obtained by Fe K edge EXAFS spectra showed that the linkage of structural units formed by FeO₆ octahedra in γ-FeOOH is distorted by chromium addition, while such distortion in α-FeOOH is not clearly detected. On the other hand, Cr K edge EXAFS spectra showed that the local structure around chromium does not necessarily correspond to the local structure around of iron, which is observed by Fe K edge EXAFS spectra. This suggests that the structural units containing iron and chromium are heterogeneously distributed in these ferric oxyhydroxides. The local structural information was discussed coupled with morphological features of these ferric oxyhydroxides observed by TEM.     

强化均匀化对7B04铝合金铸态组织与性能的影响

研究了强化均匀化 (大幅度延长均匀化时间 ,略高于传统均匀化温度 )对 7B0 4铝合金铸态组织和性能的影响。结果表明 :在 4 6 8℃× 4 8h的均匀化制度下 ,材料的铸态组织得到明显的改善 ,非平衡凝固形成的多相组织基本上转变成均匀化组织 ,材料的伸长率较传统均匀化提高 14 % ,为后续压力加工和热处理奠定了基础。     

ZAlSi12Cu2Mg1微弧氧化陶瓷膜层形成过程研究

通过控制微弧氧化时间,研究了ZAlSi12Cu2Mg1在不同氧化时间下膜层的生长过程,分析了氧化过程中正向电流密度、膜层厚度的变化.结果表明微弧氧化阶段又分为氧化过渡阶段和氧化烧结阶段.氧化过渡阶段陶瓷层以向外生长为主;生成Al2O3非晶氧化物;氧化烧结阶段膜层以向内生长为主,此阶段膜层生长速率最快,生成Al2O3晶体和莫来石.氧化烧结阶段对陶瓷膜层的形成起重要作用,对氧化烧结阶段的控制可直接影响膜层的厚度以及膜层中Al2O3晶体含量.     

Influence of geometry on galvanic corrosion of AZ91D coupled to steel

The influence of geometric factors on the galvanic current density distribution for AZ91D coupled to steel was investigated using experimental measurements and a BEM model. The geometric factors were area ratio of anode/cathode, insulation distance between anode and cathode, depth of solution film covering the galvanic couple and the manner of interaction caused by two independent interacting galvanic couples. The galvanic current density distribution calculated from the BEM model was in good agreement with the experimental measurements. The galvanic current density distribution caused by the interaction of two independent galvanic couples can be reasonably predicted as the linear addition of the galvanic current density caused by each individual galvanic couple.     

压铸模具钢4Cr5MoSiV1的热处理工艺及组织

介绍了压铸模具钢4Cr5MOSiV1的材质和热处理工艺及组织，分析了组织缺陷，得出了常见缺陷的解决办法。此外，还对4Cr5MOSiV1铜的未来发展趋势进行了展望。