传感器用双组分加成型硅凝胶的研究

以聚甲基乙烯基硅氧烷为基胶、含氢硅油为交联剂、氯铂酸配合物为催化剂、含乙烯基的MQ树脂为补强填料、含环氧基的硅氧烷为增粘剂 ,配制加成型双组分硅凝胶 ;研究了聚甲基乙烯基硅氧烷基胶摩尔质量、交联剂的用量、催化剂的用量、MQ树脂的用量、增粘剂的用量等对硅凝胶性能的影响。结果表明 :选用粘度为 12 0 0～ 15 0 0mPa·s的基胶 ,按基胶质量计交联剂用量为 3 5 %～ 4 0 % ,MQ树脂用量为 6 0 %～ 8 0 % ,增粘剂用量为 0 9% ,铂催化剂用量 60× 10 - 6 ,可制得外观无色透明 ,硫化时间 3～ 6h、针入度大于 10 0的硅凝胶     

可量测实景影像在城市部件管理中的应用

介绍了移动测量系统采集的可量测实景影像在城市部件管理中的应用,通过对城市立面街景影像与部件地图、属性关联技术,利用实景影像对部件量测技术,提出了一种集成地图、部件属性库和多角度影像的城市部件管理新手段．     

一种自适应入位固持装置及试验研究

为解决飞机数字化装配中难以对机身大部件增加辅助固持并保持大部件位姿不变的技术难题,提出一种基于气浮和万向球座的大部件位姿跟随固持方法,并设计制造称之为随动定位器的专用柔性工装.结合某工程,进行定位器关键参数的分析计算和相关工艺试验研究,并对油压波动、相关零件磨损对锁紧力的影响以及芯轴自由端关键参数选择与入位可靠性问题进行了研究.结果表明,在芯轴角度偏差较小时,随动定位器可以在确保大部件位姿不被破坏的情况下,实现芯轴的小阻力自适应入位,并可以根据选定的工作油压和配合间隙可靠固持大部件,其性能可以满足工程要求.     

Manipulation of gasification coal feed in order to increase the ash fusion temperature of the coal enabling the gasifiers to operate at higher temperatures

Coal is a crucial feedstock for South Africa’s unique synfuels and petrochemicals industry and used by Sasol as a feedstock to produce synthesis gas via the Sasol-Lurgi Fixed Bed Dry Bottom (FBDB) gasification process. The ash fusion temperature (AFT) gives detail information on the suitability of a coal source for gasification purposes, and specifically to which extent ash agglomeration or clinkering is likely to occur within the gasifier. Ash clinkering inside the gasifier can cause channel burning and unstable operation.Sasol-Lurgi FBDB gasifiers are currently operated with the philosophy of adding an excess of steam to the process to control the H₂/CO ratio of the syngas produced, but indirectly also to control the maximum gasifier temperature below the AFT of the coal. An opportunity exists to increase the AFT of the coal fed to the gasifiers by adding AFT increasing minerals to the coal blend before it is fed into the gasification process. For the aim of this study a South African coal source was investigated, as being used by the gasification operations in Secunda.With the specific aim of this study, to increase the AFT, the determination of the AFT of the coal blends where acidic components such as silica (SiO₂), alumina (Al₂O₃) and titania (TiO₂) were added was conducted. The Al₂O₃ had the biggest and most significant effect on the AFT with the least addition to the coal blend. The effect of SiO₂ and TiO₂ were very similar, but the effect was much smaller and further Al₂O₃ was needed to increase the AFT to a similar AFT level in comparison to the SiO₂ used. Kaolinite, roof and floor components (containing mainly Al₂O₃ and SiO₂) were also added, also showing an increase in the AFT with up to 4 mass% addition. Another observation was that the AFT was non-additive (not a linear weighted calculated average) and not the weighted average AFT as was expected for the other coal properties such as the ash content, for example. The ash slagging characteristics is a non-additive property of individual coal sources in the blend and therefore difficult to predict.In general it can be concluded that the unique opportunity exists to increase the AFT, was tested, proven and mechanistically outlined in this study on the coal source fed to the Sasol-Lurgi FBDB gasifiers. The AFT can be increased to >1350 °C by adding AFT increasing minerals or species to the coal blend before it is fed into the gasification process. By increasing the AFT, the direct effect will be that steam consumption can be decreased, which in turn will improve carbon utilization.     

柴油加氢工艺动态仿真研究与应用

柴油加氢工艺是通过加氢反应来提高油品质量,对于环境保护和大气污染防治起着至关重要的作用.由于柴油的组成纷繁复杂,使得柴油组分难以确定,一直以来是加氢工艺动态仿真模拟中的难点问题.为解决上述问题,采用真实组分法确定了柴油组成,建立了组分分率模型,进而实现了柴油加氢工艺的全流程动态仿真.仿真结果与实际相吻合,证明了该方法用于柴油加氢工艺的动态仿真是行之有效的.     

PEAK-INSENSITIVE NON-PARAMETRIC SPECTRUM ESTIMATION

Abstract. We study the problem of non-parametric spectrum estimation of a stationary time series that might contain periodic components. In this case the periodogram ordinates have a significant amplitude at frequencies near the frequencies of the periodic components. These can be regarded as outliers in an asymptotically exponential sample. We develop a non-parametric estimator for the spectral density that is insensitive to these outliers in the frequency domain. This is done by robustifying the usual kernel estimator (smoothed periodogram) by means of M-estimation in the frequency domain. We propose to use data-tapered periodograms, which yield a drastic improvement of the procedure, typically for the contaminated situation. This is both shown theoretically and supported by means of simulation. We show consistency of the resulting estimator in the general case, and asymptotic normality in the special case of a Gaussian time series, whether contamination is present or not. Finally we illustrate the finite sample performance of the estimating procedure by some simulation results and by application to the Canadian lynx trappings data.     

ICP-AES法测定粉煤灰全组分化学元素的研究

采用偏硼酸锂熔样 ,电感耦合等离子体原子发射光谱 (ICPˉAES)法对粉煤灰实现一次熔样 ,全组分同时分析。对影响光谱测量的各种因素进行了较详细的研究 ,确定了最佳测定条件。该法的检出限为 0 .0 0 9～ 0 .83 1μg·ml-1,回收率为 91.5 4%～ 10 4.45 % ,RSD <3 .2 2 %。方法准确、快速、简便 ,用于粉煤灰中全组分测定 ,结果满意。     

加工中心部件故障相关度评估

为实现加工中心系统部件间故障相关度评估,采用相关故障机理分析与图论相结合建立系统部件故障传递有向图的方法,将系统部件相关度评估转化为复杂网络节点重要度计算,进而由邻接矩阵及其转置变换并结合pagerank算法,实现加工中心系统部件故障相关度求解.计算结果表明:故障相关度的大小与部件间故障关联关系成正比,存在故障相关的部件的故障相关度大于不存在故障相关的部件的故障相关度.若部件被影响度大,影响度小,说明该部件是故障表象部件;反之,影响度大而被影响度小的是故障源部件.提出的方法有助于故障诊断与维护.     

一种无锁相环的ip－iq法的谐波检测方法

有源电力滤波器是对电力系统中谐波和无功功率补偿的重要装置,其关键环节之一就是能够实时准确地检测出谐波电流。在介绍传统的基于三相瞬时无功功率的i_p-i_q法基本原理的基础上,指出其检测到的基波电流出现误差的原因是由于电网的电压与其正序电压存在相位差。针对该问题提出一种无锁相环的i_p-i_q法,通过对称分量法提取电网电压的正序电压,最后用MATLAB仿真软件搭建仿真模型进行验证。     

Caking property and active components of coal based on group component separation

The content and the caking index of the heavy,the dense medium and the loose medium components of coal,obtained by extraction and stripping with CS_2/N-methyl-2-pyrrolidinone mixed solvent(1:1 by volume),were studied and correlated with the caking property of raw coals.Images of the three group components after heat treatment were analyzed.The results show that both caking index(G) and maximum thickness of plastic layer(Y) of coals have a good linear relationship with the content of the medium component;the dense medium and the loose medium components are the two key factors to determine the caking property of raw coals-they are the source materials of fluidity and swelling of coal,respectively;the heavy component without the swelling and fluidity was cohered by the other components;two new indexes,which can extend current understanding of the caking properties,were introduced.