改进的基于移动小波树的数据流异常检测方法

针对移动小波树数据流异常检测算法的不足,提出了一种改进的移动小波树异常检测方法,利用比率阈值去除颠簸数据的干扰,提高了检测精度;利用二分查找检测算法,提高了检测的效率;结合实时增量更新算法满足了数据流在线处理的要求;改进了阈值设定方法,可实现双边异常检测。用射线数据和电能质量扰动数据进行仿真实验,结果验证了方法的有效性。     

由平方剩余差集与差集偶构造二元ZCZ序列偶集

提出了一种利用平方剩余差集(4t-1,2t-1,t-1) DS和差集偶(N,p,q,e,λ) DS
P构造二元零相关区(ZCZ)序列偶集的方法. 由平方剩余差集获得其二元特征序列,并由差集
偶获得其特征二元序列偶,将二者进行交织构造生成一类新的二元ZCZ序列偶集. 该方法解
决了现有二元ZCZ序列偶集构造中含有少量非二元元素的问题,通过选择适当的差集偶可使构造的二元ZCZ序列偶集在失配滤波检测中获
得较高的能量效率,从而提高了通信性能.     

井下无线传感器网络地址分配优化研究

针对现有井下无线网络拓扑存在的问题,即分布式地址分配机制中的网络深度受限及资源浪费和随机地址分布机制中的地址冲突等问题,提出了二进制地址分配机制,即通过向父节点或子节点申请未使用的地址来优化网络拓扑。仿真分析和实际应用结果表明,二进制地址分配机制大大提高了节点入网率和井下无线数据传输的实时性和可靠性。     

像素聚类改进二进制描述子鲁棒性

目标：本文通过挖掘图像局部区域特征信息,提出了一种鲁棒性更高的二进制描述子。针对BRIEF关于旋转和视角变化鲁棒性差的问题,本文通过图像补丁分层处理、增加关键点图像补丁个数来捕获更多的局部特征信息,对BRIEF描述子改进。方法：首先,根据灰度序列对补丁内所有像素点分类,像素的一个聚类形成了一个亚补丁,然后在每个亚图像补丁上进行类似BRIEF的随机测试。其次,由于原图像补丁大小、尺度大小影响补丁的像素点成分,从而影响像素聚类的效果,所以在原图像关键点周围分割出多个不同大小的图像补丁,或是将原图像补丁根据尺度金字塔确定几个尺度大小不同的补丁,然后再对图像补丁进行分层、测试。所构建的描述子不仅包含了补丁像素的灰度比较信息,而且包含了灰度排序信息和像素群聚信息,提高了描述子的鲁棒性。结果：通过性能对比实验,发现所提的描述子的性能提高了,而且好于对比的浮点描述子。结论：所以挖掘图像补丁的特征信息能提高二进制描述子的鲁棒性。     

基于Dragon描述符与改进的决策树-遗传算法的反应溶剂设计方法

反应溶剂被广泛应用于液-液均相有机合成中，能够大幅度提高反应速率与选择性，有助于绿色合成新工艺路线的开发。提出了一种基于Dragon描述符与SMILES (simplified molecular-input line-entry system)编码的计算机辅助(computer-aided molecular design, CAMD)反应溶剂设计方法。首先，利用决策树-遗传算法构建可定量预测反应速率常数k的反应动力学模型；基于构建的反应动力学模型，提出了集成决策树-遗传算法与CAMD设计方法，通过SMILES分子编码算法生成同分异构体，并利用Dragon软件计算描述符大小，建立由目标函数与约束方程组成的混合整数非线性规划(mixed integer nonlinear programming, MINLP)模型，进一步采用分解算法对模型进行优化求解，从而实现反应溶剂设计目标；最后，以Diels-Alder反应为例，验证了该方法的可行性与有效性。     

The role of lanthana loading on the catalytic properties of Pd/Al2O3-La2O3 in the NO reduction with H2

The role of La₂O₃ loading in Pd/Al₂O₃-La₂O₃ prepared by sol–gel on the catalytic properties in the NO reduction with H₂ was studied. The catalysts were characterized by N₂ physisorption, temperature-programmed reduction, differential thermal analysis, temperature-programmed oxidation and temperature-programmed desorption of NO.

The physicochemical properties of Pd catalysts as well as the catalytic activity and selectivity are modified by La₂O₃ inclusion. The selectivity depends on the NO/H₂ molar ratio (GHSV = 72,000 h⁻¹) and the extent of interaction between Pd and La₂O₃. At NO/H₂ = 0.5, the catalysts show high N₂ selectivity (60–75%) at temperatures lower than 250 °C. For NO/H₂ = 1, the N₂ selectivity is almost 100% mainly for high temperatures, and even in the presence of 10% H₂O vapor. The high N₂ selectivity indicates a high capability of the catalysts to dissociate NO upon adsorption. This property is attributed to the creation of new adsorption sites through the formation of a surface PdO_x phase interacting with La₂O₃. The formation of this phase is favored by the spreading of PdO promoted by La₂O₃. DTA shows that the phase transformation takes place at temperatures of 280–350 °C, while TPO indicates that this phase transformation is related to the oxidation process of PdO: in the case of Pd/Al₂O₃ the O₂ uptake is consistent with the oxidation of PdO to PdO₂, and when La₂O₃ is present the O₂ uptake exceeds that amount (1.5 times). La₂O₃ in Pd catalysts promotes also the oxidation of Pd and dissociative adsorption of NO mainly at low temperatures (<250 °C) favoring the formation of N₂.     

Optimal binary codes and binary construction of quantum codes

This paper discusses optimal binary codes and pure binary quantum codes created using Steane construction. First, a local search algorithm for a special subclass of quasi-cyclic codes is proposed, then five binary quasi-cyclic codes are built. Second, three classical construction methods are generalized for new codes from old such that they are suitable for constructing binary self-orthogonal codes, and 62 binary codes and six subcode chains of obtained self-orthogonal codes are designed. Third, six pure binary quantum codes are constructed from the code pairs obtained through Steane construction. There are 66 good binary codes that include 12 optimal linear codes, 45 known optimal linear codes, and nine known optimal self-orthogonal codes. The six pure binary quantum codes all achieve the performance of their additive counterparts constructed by quaternary construction and thus are known optimal codes.     

The design and analysis of unequal error protection fountain coding for multiple source networks over binary erasure channels

A novel network model of multiple source fountain coding is developed and a novel class of generic multiple source fountain codes with unequal error protection(UEP)property is proposed.The And–Or tree analysis technique is generalized to analyze the asymptotic performance of the proposed codes and a joint optimization method employing both linear and nonlinear programs is developed to optimize the degree distributions.Furthermore,we propose three basic methods to achieve UEP property and the performance of each method is discussed.We employ these analytical results and optimization method to design and discuss several UEP codes with two and four sources for different application scenarios.Simulation results verify that the proposed codes can be applied to the networks with any number of sources and can provide strong UEP property in various ways based on the proposed three basic methods.     

Initial density dependence of experimental viscosities and of calculated diffusion coefficients of the binary vapor mixtures methanol-benzene and methanol-cyclohexane

The paper reports experimental results for the viscosity of the vapor mixtures methanol-benzene (five mole fractions with densities up to 1.5kg·m^–3 and 0.022 mol·L ^–1) and methanol-cyclohexane (four mole fractions with densities up to 1.9kg·m^–3 and 0.026 mol·L ^–1). In analogy to the pure components, the measurements on the mixtures were carried out with an oscillating-disk viscometer with small gaps, completely made of quartz, beginning as near as possible to room temperature and continuing to a maximum temperature of 630 K. A first evaluation by means of the Chapman-Enskog theory of dilute gases has shown differences in the resulting values of the interaction viscosity _ij ⁽⁰⁾ in the limit of zero density exceeding the experimental errors. Consistent results were obtained by taking into account the initial density dependence of the viscosity within the framework of the modified Enskog theory for gaseous mixtures. The values of _ij ⁽⁰⁾ were also used to estimate binary diffusion coefficients of the mixtures.     

Viscosity of binary mixtures. I. mono-, di-, and tri-n-butyl and -n-octylamine with cyclohexane

Viscosities for six binary mixtures of n-butylamine, di-n-butylamine, tri-n-butylamine, n-octylamine, di-n-octylamine, and tri-n-octylamine with cyclohexane have been measured at 303.15 K with an Ubbelohde suspendedlevel viscometer. Deviations of viscosities from a rectilinear dependence on mole fraction are attributed to H-bonding and to the size of alkylamine compounds. The application of the Eyring's theory of activation energy is examined. The free volume theory of Prigogine-Flory-Patterson (PFP) and the experimental excess enthalpy have been used to estimate excess viscosity ln = (ln / ₁ ⁰ – x ₂ ln ₂ ⁰ / ₁ ⁰ ) and corresponding free volume, enthalpy, and entropy contributions for five binary mixtures of tri-n-alkylamine: triethyl, tripropyl, tributyl, trihexyl, and trioctylamine with cyclohexane. A comparison of experimental and theoretical excess viscosities indicates a failure of the PFP theory when two components of the mixture differ considerably in size. The size difference contribution to excess viscosity is related to (V ₂ ^*1/2 – V ₁ ^*1/2 ), where V ₁ ^* and V ₂ ^* are hard-core volumes of two components of the mixture.