纳米碳酸钙/炭黑并用对丁苯橡胶性能的影响

研究了纳米碳酸钙／N330炭黑并用比对丁苯橡胶性能的影响。结果表明，随着CaCO3／N330并用比的改变，材料的强度有了显著的提高，特别是CaCOa／N330并用比为20／30(质量份)时复合材料的拉伸强度达到了20MPa以上，同时材料具有较好的弹性和较低的硬度；两种处理剂相比，树脂酸处理的碳酸钙具有较好的性能；表面处理的纳米炭酸钙与炭黑并用，可以降低炭黑填充橡胶的动态滞后，表面处理的纳米碳酸钙的加工性能比纳米炭黑好，可以通过并用纳米碳酸钙来改善炭黑胶料的加工性能。     

炭黑对复合型导电高分子材料电性能影响

阐述了炭黑填充型导电高分子复合材料的导电机理，讨论了炭黑基本物性、填充量以及分散状态对材料导电性的影响，并探讨了影响炭黑分散状态的因素。     

Effect of adhesive‐coated glass fiber in natural rubber (NR), acrylonitrile rubber (NBR), and ethylene–propylene–diene rubber (EPDM) formulations. II. Effect of cyclic loading,abrasion, and accelerated aging

Treated glass fibers (RICS, 3 and 6 mm in length) were added at a concentrations of 10, 20, and 30 phr in natural rubber (NR), nitrile rubber (NBR), and ethylene–propylene–diene comonomer (EPDM) formulations, in both plain and carbon black mixes. The compounds were mixed in two‐roll mill and were evaluated for their resistance to hot‐air aging, abrasion, compression set, Goodrich heat buildup, De Mattia fatigue, and for NR mixes, adhesion in the tensile mode. The vulcanizates of the three rubbers showed resistance to hot‐air aging. Abrasion resistance was poor for NR, and it improved with carbon black addition in the presence of treated glass fiber in NBR. In carbon‐black‐added EPDM vulcanizates, the abrasion resistance and fatigue resistance were better. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 1124–1135, 2004     

3种杀菌剂拌种防治向日葵黑茎病药效试验研究

进行了3种杀菌剂对向日葵黑茎病的拌种药效试验,结果表明,3种药剂拌种后对向日葵出苗安全,不产生药害;各个处理的防效均随着向日葵生育进程的推进而下降,以出苗后35 d防效最为理想,此时2.5%咯菌腈FS 11.25 mL/hm2、2.5%咯菌腈FS 9 mL/hm2和50%多菌灵WP 13.5 g/hm2的防效为71.7%～83.4%,显著高于50%多菌灵WP 9 g/hm2、70%甲基硫菌灵WP 13.5 g/hm2和70%甲基硫菌灵WP 9 g/hm2,经方差分析证明处理间差异达到显著水平。     

炭黑掺量对水泥基材料微波吸收性能的影响及机理

以隧道效应理论为基础建立炭黑水泥基复合材料（carbonblack-filled cement-based composites,CBCC）的隧道电阻率模型,推导隧道电阻率与材料内部微观结构参数、载流子运动参数以及外加电场强度的关系表达式,反映CBCC材料的隧道电阻率与宏观炭黑体积掺量V以及炭黑粒子直径D之间的内在关系...     

掺杂和密闭透窗对炸药激光起爆感度的影响

用Bruccton法测定了掺杂碳黑和碳纳米管的RDX和PETN炸药的起爆阈值,同时比较了K9玻璃和蓝宝石两种玻璃透窗下激光起爆感度的区别,以及自由振荡和调Q两种激光模式对RDX和PETN起爆感度的影响.结果表明,掺杂碳黑和碳纳米管均可提高RDX和PETN的感度,碳黑的掺杂效果好于碳纳米管,其中掺杂质量分数1%碳黑的RD...     

不饱和树脂／炭黑复合材料的制备与性能研究

采用球磨和超声两种制备工艺分别制备了炭黑填充不饱和树脂复合材料,研究和对比了两种不同工艺对复合材料性能的影响。结果表明,两种制备方法得到的复合材料渗滤阀值均在质量分数1．8％。不饱和树脂／炭黑复合材料的拉伸强度和弹性模量随炭黑含量不同而变化,当其质量分数为1％时,两者出现最大值。相比纯的不饱和树脂,球磨法制备的复合材料的拉伸强度和弹性模量提高了89％和95．8％,而超声法提高了38．37％和23．12％。     

纳米四氧化三铁吸附水溶液中砷的研究

采用水热法合成出纳米Fe3O4,借助X射线衍射、透射电子显微镜和比表面积分析等对其进行了表征.结果表明:所制备的样品为面心立方晶型的Fe3O4纳米薄片,比表面积为35.25m2/g.用所制备的Fe3O4样品作为吸附剂去除水溶液中的五价砷,通过分光光度法计算出其去除率接近90%.通过单因素实验对所合成Fe3O4样品吸附去...     

The mechanism for the colour change of iron chromium black pigments in glazes through transmission electron microscopy techniques

Black iron-chromium (Fe-Cr) bearing oxide pigments are generally utilised as effective colourants in a wide variety of applications. However, in the case of their use within ZnO-containing glazes, they yield an undesirable brown colour instead of expected black colour. In order to understand the colour change in this system, we report the use of focused ion beam (FIB) sample preparation technique followed by the use of analytical transmission electron microscopy (TEM) characterisation techniques. According to the results, the formation of a reaction layer between the pigment and glaze was identified with an average composition of Zn_0.48Fe_0.79Cr_1.32O₄. Additionally, the valance of Fe was determined as 3+ in the pigment grain, whereas 2+ in the reaction layer and the glaze, respectively. Therefore, it was concluded that the colour change is occurring as result of the valence variation of Fe, the formation of Zn_0.48Fe_0.79Cr_1.32O₄ compound and the outward diffusion of Fe into the glaze.     

建筑外墙反射隔热涂料节能效率探讨

选坐落于广州的一幢1梯2户6层为特定的参照建筑,用JGJ 75—2003《夏热冬暖地区居住建筑节能设计标准》的方法,计算该建筑物外装饰材料的太阳能辐射吸收率ρ与建筑物空调年耗电量指数(ECFc)的关系。结果表明:ρ值越低,建筑物ECFc越低,越节能;当ρ≤0.65时,ECFc≤0.5,即该建筑符合JGJ 75—2003的节能设计;证明反射隔热涂料的基本要求之一就是要降低涂料的ρ值。测量涂料的太阳能总反射比(TSR)结果表明:使用铬铁黑、铬铁红等颜料,在中等深度颜色到深颜色范围内,涂料的TSR能够提高10%～20%,节约空调年耗电量10%左右。