竹浆Co-salen仿酶预处理TCF漂白的研究

研究了竹浆Co-salent仿酶预处理TCF漂白,结果表明,竹浆Co-salent仿酶处理方式以单独预处理为宜,适宜条件：Co-salen用量0.03％、吡啶与Co-saler摩尔1：1、NaOH用量3％、H2O2用量1.5％、氧压0.2MPa、浆浓5％、温度90℃、时间5h;竹浆经OCoEpPaP流程漂白后的白度为90.5％,比空白样提高了5.3个百分点。黏度为620mL／g,比空白样降低99mL／g;Co-salen仿酶预处理能在一定程度上提高TCF终漂纸浆物理性能,降低漂白废液COD、BOD、SS负荷,并减少后续P缓和暇漂剂用量40％以上。     

微波辐射辅助竹浆漂白研究

以漂后浆料白度、残氯为考察指标时,用微波辐射辅助竹浆次氯酸钠漂白的最佳工艺条件为:微波辐射功率640 W,辐射时间6 min,有效氯含量8%.竹浆白度达69.2%ISO,与相同条件下传统水浴加热90 min竹浆达到的白度(70.6%ISO)相当;残氯为0.221 7 g/L,比相同条件下传统水浴加热90 min稍高(0.203 4 g/L).微波辐射竹浆漂白可以缩短时间、提高生产效率、节约能源,在造纸工业中的应用值得进一步研究.     

金属离子对马尾松硫酸盐浆碱性过氧化氢漂白的影响

进行添加几种金属离子的H2O2漂白试验,表明在碱性条件下,金属离子对过氧化氢分解作用比在酸性条件下大。各种金属离子中,Cu^2 、Mn^2 、Co^2 对H2O2催化分解最为严重。在有浆条件下,Co^2 对漂浆的粘度、白度损害最大,漂白的选择性最差。添加适当Mg^2 ,有明显的稳定H2O2、提高H2O2漂浆白度和粘度的作用,选择性最好。     

治理漂白工段污染的途径与方法(1)

介绍了造纸工业漂白工段废水对环境的污染问题,以及解决此问题的两个途径,即研究应用无或少污染制浆漂白技术及研究应用漂白废水净化治理技术。本部分主要简述了目前无或少污染制浆漂白技术研究的进展研究。     

棉短绒浆聚合度影响因素的初步研究

研究了不同的蒸煮工艺条件下各因素对棉短绒浆聚合度的影响情况。结果表明：棉短绒碱一过氧化氢蒸煮的优化工艺条件为：最高温度120℃，用碱量11％，H2O2用量3％，保温时间60min。还简单探讨了漂白对聚合度产生的影响，通过漂白获得低聚合度的浆较改变蒸煮条件更合理可行。     

几种造纸填料对废纸浆过氧化氢漂白的影响

本文利用原子吸收光谱对轻质碳酸钙、高岭土、滑石粉、二氧化钛等常用造纸填料的元素组成进行分析。测定了轻质碳酸钙和高岭土两种填料悬浮液不同浓度下的ξ电位。研究填料的存在对纸浆碱性过氧化氢漂白的影响。结果表明，所用填料悬浮液的ξ电位随着填料加入量的增加而绝对值增加且均为负值，纸浆中不同的填料及其用量对过氧化氢纸浆漂白效果有不同的影响。     

Antioxidant activity screening of extracts from Sideritis species (Labiatae) grown in Bulgaria

Plant samples from several species and populations of the genus Sideritis (Labiatae) grown in Bulgaria (S scardica, S syriaca and S montana) were extracted with different solvents. Their antioxidant activities were determined by the β‐carotene bleaching test (BCBT), 2,2′‐diphenyl‐1‐picrylhydrazyl (DPPH^?) radical scavenging method and static headspace gas chromatography (HS‐GC) and compared with the antioxidant activity of two reference compounds of different polarity, viz butylated hydroxytoluene (BHT) and rosmarinic acid. The pure reference compounds were applied in a ten‐times lower concentration than the plant extracts. The highest antioxidant activity in the BCBT, close to that of BHT, was observed for the more apolar extracts. The inhibitory effect on β‐carotene bleaching of the polar extracts and rosmarinic acid was much lower than that of BHT. The inhibition of hexanal formation in bulk safflower oil by most of S syriaca and S scardica extracts was as effective as BHT but less so than rosmarinic acid. S montana extracts showed weak antioxidant or even pro‐oxidant properties. Extracts from butanol and from ethyl acetate and the total methanol extracts from all Sideritis plants studied showed a strong radical scavenging activity against DPPH^?, close to that of rosmarinic acid. S montana extracts were, as a whole, slightly weaker radical inhibitors than the extracts from the other two species. The antioxidant activity of Sideritis extracts was attributed to the presence of flavonoid and phenylpropanoid glycosides. Copyright © 2003 Society of Chemical Industry     

练漂工程的探讨和实践

阐述我国练漂技术的发展过程，并对发展过程中出现的各种工艺和设备进行了评价，重点介绍了近年来各种短流程工艺的进展情况以及今后的发展方向。     

建议开发的印染助剂新品种

根据文献介绍，从提高染色牢度、节能节水以及多道工序合一工艺等方面，阐述了国外已经研制开发的新型助剂品种，为国内的开发研究提供参考．     

蓝桉硫酸盐法制浆和漂白性能研究

对蓝桉硫酸盐法制浆和漂白性能进行了研究。结果表明,蓝桉具有优良的制浆造纸性能,其较佳的蒸煮工艺条件为:用碱量14％(Na_2O),硫化度30％,液比1:5,H-因子1000。采用有元素氯漂白、ECF漂白和TCF漂白程序,均可制得高白度、高强度的蓝桉漂白硫酸盐浆。其中采用CEpH、DEpP漂白程序,漂白浆白度均在86％ISO以上,抗张指数分别达到85.26N·m/g和78.12N·m/g,撕裂指数分别达到7.48mN·m~2/g和9.06mN·m~2/g。