A-96氧化铝陶瓷机电性能的改进

为了解决由氧化铝粉Na+含量较高导致的A-96氧化铝陶瓷产品性能较差的问题,在陶瓷的三元配方(Al2O3-MgO-SiO2)体系中加入了CaCO3。研究了Ca2+含量对A-96氧化铝陶瓷性能的影响。结果表明,Ca2+的引入抑制了陶瓷中Na+的迁移,从而明显改善了A-96氧化铝陶瓷的性能。在CaCO3质量分数为0.8%时,A-96氧化铝陶瓷基板的机电性能达到国标要求。当CaCO3质量分数为1.0%时,该陶瓷基板的机电性能最佳,体密度最大(3.72 g/cm3),但其颜色发黄,这可能是由于陶瓷中生成了黄色的钙长石。     

植物细胞钙离子检测与成像技术研究进展

钙离子是一种重要的第二信使,参与调节植物多种生理和发育过程.胞内钙离子呈现复杂的时空动态变化,只有实时捕获钙离子在植株整体水平以及亚细胞水平的变化,才能深入理解钙信号的重要功能.过去几十年中,人们在钙离子检测与成像技术方面进行了大量探索,本文总结了近年来植物科学研究中常用的钙离子检测与成像技术,着重介绍了化学荧光探针和基于荧光蛋白钙离子探针的原理、特点、浓度计算方法、在细胞质以及细胞器钙离子检测与成像中的应用等,并总结了化学荧光探针的装载方法.     

Elevating Biomedical Performance of ZnO/SiO2@Amorphous Calcium Phosphate ‐ Bioinspiration Making Possible the Impossible

Here a biomimetic approach is presented to fabricate nanodragon fruits featured by a multitude of tiny quantum dot ZnO seeds embedded in mesosilica (SiO₂) flesh then enclosed in amorphous calcium phosphate (ACP) shell. The nanodragon fruits give rise to a new class of hybrid ZnO/SiO₂@ACP nanocomplex with multimoidal capability: cellular delivering, intracellular targeting, and subcellular imaging. With this particular design, the unusual fluorescent stability of ZnO quantum dots (QDs) in aqueous solution, the specific color selection of the functional ZnO QD seeds, and the stability of transient ACP over a long period of time are made possible. In addition, the nanodragon fruits, capable of targeting mitochondria, have elevated biocompatibility, thus can be of enormous potential applications in treating mitochondrial diseases including inflammation, neurodegeneration, obesity, diabetes, cardiovascular diseases, and cancer. As numerous human disorders are often associated with cellular dysfunctions, this biocompatible carrying platform, capable of delivering, targeting, and imaging subcellular organelles, is therefore highly desirable for efficacious therapeutic and diagnostic treatment.     

井壁强化与堵漏双作用可钻水泥实验研究

针对常规复合堵漏材料之间无胶结、易被钻井液冲刷、使用油井水泥堵漏会造成新井眼的问题,研究开发了井壁强化与堵漏双作用可钻水泥。将超细碳酸钙粉体加入新型胶凝材料硫铝酸盐水泥中,调节胶凝材料的可钻性,研究表明,当超细碳酸钙粉体的加入量不大于7%时,水泥凝胶材料的强度随粉体加入量的增加而增加,而当粉体的加入量大于7%时,水泥凝胶材料的强度随粉体加入量的增加而减小,即可钻性变好;在硫铝酸盐中加入0.4%减水剂、0.3%提黏剂、0.6%缓凝剂时,其稠化时间达到155 min,为安全施工提供了条件;在可钻水泥中加入12%鳞片状云母、1%纤维、1.5%石灰岩颗粒作为堵漏剂,较好地增强了体系堵漏性能,能够较好地封堵3 mm和5 mm缝板裂缝。可钻水泥的研发为实现钻井过程中井壁强化与堵漏双作用提供了技术保障。      

Saturated Solutions of Anhydrous Phases in the System Lime-Silica-Water: Example of β-C2S

Saturated solutions rerely form when the anhydrous constituents of aluminous and portland cement are stirred in water or in lime solutions of increasing concentrations. Apart from monocalcium aluminate, concentration of ions in solution cannot exceed maximum supersaturation with respect to the hydrate most likely to precipitate. The present work shows such a behavior for β-C₂S suspended in water and in lime solutions at low concentration. In more concentrated lime solutions, a short lifetime saturation state with respect to β-C₂S seems to be reached.     

超细活性氧化锌在轿车子午线轮胎胎面胶中的应用

对超细活性氧化锌在轿车子一轮胎胎面胶中的活尼效果分两组配方做了实验。结果表明,超细活性氧化锌由于活性高、等效用量小,与普通氧化锌相比有加快硫化速度的效果,并能改善胶料的加工性能,提高硫化胶的扯断永久变形、耐老化性和耐疲劳性能;超细活性氧化锌胶料加入活性碳酸钙后,能胶料生产成本,提高经济效益。     

Kinetics of decomposition of CaCo3 in an Australian oil shale

The kinetics of decomposition of calcium carbonate in an Australian (Julia Creek) oil shale were measured because the extent of the carbonate decomposition affects the energy balance for combustors burning either raw or spent shale. The apparent activation energy was similar to that previously reported for the decomposition of calcium carbonate in Colorado oil shale but the Julia Creek shale had rate constants which were smaller than those reported for the Colorado shale.     

CPC/SF复合材料的制备

在磷酸钙骨水泥（CPC）粉末中加入丝素（SF）粉制备CPC/SF复合材料。用X射线衍射法、红外光谱法研究材料的结构,用ISO水泥标准维卡仪测定复合材料的凝固时间,用扫描电子显微镜观察材料的表面形态。结果表明,CPC粉末的主要成分为磷酸氢钙、磷酸四钙,在固化过程中磷酸氢钙转化为羟基磷灰石。当液固比相同时,丝素比例在0～3%范围内,在CPC粉末中加入SF粉制成复合材料的凝固时间随着丝素比例的增加而缩短;当丝素比例由3%增加到4%时, CPC/SF复合材料的调制不匀、不具注射性。在本实验条件下,CPC中加入SF粉可增加骨水泥的抗弯强度。     

利用盐湖高钙含钾卤水制取氯化钾工艺试验研究

青海盐湖部分氯化物型卤水中,由于钙的循环积累,其浓度不断增高,这可能对从卤水中提取氯化钾带来一定影响。实验研究了该类型高钙含钾卤水对4#工艺制取氯化钾的影响,研究结果表明卤水中钙含量对4#工艺制取氯化钾影响较小。     

碱性钙对‘秦冠’苹果块贮藏品质及生理特性的影响

目的 研究碱性钙对苹果块贮藏品质及生理特性的影响。方法 以‘秦冠’苹果为材料,采用不同Ca²⁺质量浓度的碱性钙对苹果块进行处理,于(4±1)℃下贮藏12d,研究不同Ca²⁺质量浓度的碱性钙对苹果块质地参数(硬度、咀嚼性、回复性、内聚性、弹性指数)、色泽、可溶性固形物、可滴定酸、可溶性蛋白和可溶性糖等品质指标及细胞膜透性、丙二醛(malondialdehyde, MDA)、多酚氧化酶(polyphenol oxidase, PPO)、过氧化物酶(peroxidase, POD)、超氧化物歧化酶(superoxide dismutase, SOD)和过氧化氢酶(catalase, CAT)等生理指标的影响。结果 与对照相比,不同Ca²⁺质量浓度的碱性钙处理均可不同程度地影响苹果块的贮藏品质及生理特性,其中Ca²⁺质量浓度为2.0 g/L的碱性钙处理效果最好,贮藏结束时硬度、咀嚼性、回复性、内聚性、弹性指数、可溶性固形物、可滴定酸、可溶性蛋白、还原糖、SOD和CAT分别比对照高68.83%、75.10%、...