全文获取类型
收费全文 | 78710篇 |
免费 | 7696篇 |
国内免费 | 3869篇 |
专业分类
电工技术 | 3185篇 |
技术理论 | 9篇 |
综合类 | 5263篇 |
化学工业 | 22474篇 |
金属工艺 | 5800篇 |
机械仪表 | 3404篇 |
建筑科学 | 7103篇 |
矿业工程 | 2724篇 |
能源动力 | 3976篇 |
轻工业 | 4499篇 |
水利工程 | 1148篇 |
石油天然气 | 3372篇 |
武器工业 | 890篇 |
无线电 | 3990篇 |
一般工业技术 | 14687篇 |
冶金工业 | 5318篇 |
原子能技术 | 798篇 |
自动化技术 | 1635篇 |
出版年
2024年 | 343篇 |
2023年 | 1363篇 |
2022年 | 2311篇 |
2021年 | 2658篇 |
2020年 | 2665篇 |
2019年 | 2353篇 |
2018年 | 2191篇 |
2017年 | 2688篇 |
2016年 | 2812篇 |
2015年 | 2636篇 |
2014年 | 4222篇 |
2013年 | 4341篇 |
2012年 | 5288篇 |
2011年 | 5782篇 |
2010年 | 4426篇 |
2009年 | 4729篇 |
2008年 | 3838篇 |
2007年 | 5328篇 |
2006年 | 4946篇 |
2005年 | 4333篇 |
2004年 | 3604篇 |
2003年 | 3316篇 |
2002年 | 2696篇 |
2001年 | 2149篇 |
2000年 | 1904篇 |
1999年 | 1475篇 |
1998年 | 1198篇 |
1997年 | 912篇 |
1996年 | 801篇 |
1995年 | 648篇 |
1994年 | 586篇 |
1993年 | 414篇 |
1992年 | 282篇 |
1991年 | 213篇 |
1990年 | 181篇 |
1989年 | 133篇 |
1988年 | 94篇 |
1987年 | 67篇 |
1986年 | 44篇 |
1985年 | 72篇 |
1984年 | 50篇 |
1983年 | 53篇 |
1982年 | 29篇 |
1981年 | 7篇 |
1980年 | 18篇 |
1976年 | 6篇 |
1963年 | 4篇 |
1959年 | 9篇 |
1955年 | 4篇 |
1951年 | 27篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
31.
32.
Zhongyu Qiu Xiaowen Ge Naibao Huang Shixian Zhou Junjie Zhang Jiaping Xuan 《International Journal of Hydrogen Energy》2021,46(3):2952-2959
Polyethylene oxide (PEO)-polypropylene oxide (PPO)-polyethylene oxide block copolymer having different molecular weights are used as precursors of carbon materials to prepare Hollow -Derivatives carbon material as an electrocatalyst through block copolymer self-assembly. The composition and microstructure of the prepared catalysts are shown by Raman spectroscopy, X-ray diffraction (XRD), Test of nitrogen adsorption and desorption curves, High resolution transmission electron microscopy (HR-TEM) and scanning electron microscopy (HR-SEM). Oxygen was passed into alkaline electrolyte solution until the solution reached saturation state. With molecular weight increasing, the obtained sample gradually changed from block to hollow and spherical. When the molecular weight was 12600 g mol?1, the evenly hollow carbon nanocages was acquired (C-12600). In O2 saturated alkaline electrolyte (0.1 M KOH solution), C-12600's limited current density,half-wave potential and initial potential are 5.23 mA cm?2@0.4 V, 0.72 V and 0.81 V, respectively. And most important is that half-wave potential and onset potential have barely change after 2000 cycles of cyclic voltammetry. As a result, the porous carbon materials exhibited excellent electrocatalytic activity while maintaining high stability in alkaline KOH solution. 相似文献
33.
Zehu Xie Na Peng Tingting Liu Xing Cheng Wuquan Ye Runtian Zheng Jundong Zhang Haoxiang Yu Jie Shu 《Ceramics International》2019,45(9):11812-11818
Here, LiY(WO4)2 nanotubes are prepared via a feasible electrospinning technique. This new anode material shows excellent electrochemical properties. The capacity loss of LiY(WO4)2 nanotubes is as low as 6.9% after 156 cycles, while bulk LiY(WO4)2 presents the capacity loss higher than 55.0%. Even after 600 long-life cycles, the capacity loss of the nanotubes is only 9%. It can be seen that the hollow structure with a rough surface and a porous morphology contributes to the improvement of electrochemical performance. Furthermore, online X-ray diffraction (XRD) method is firstly applied to understand the lithium ions insertion/extraction mechanism of LiY(WO4)2 nanotubes. It can be concluded that it is an asymmetrical two-phase reaction. A phase transformation from LiY(WO4)2 to Li3Y(WO4)2 can be obviously seen from the in situ XRD during discharge process. While Li2Y(WO4)2 appears as an intermediate phase with a reverse charge reaction. In addition, in situ XRD also demonstrates that LiY(WO4)2 nanotubes have surprised electrochemical reversibility. All the above results indicate that LiY(WO4)2 nanotubes can be expected to be anode candidate for rechargeable lithium ion batteries (LIBs). 相似文献
34.
Isaac Isarn Leïla Bonnaud Lluís Massagus ngels Serra Francesc Ferrando 《Polymer International》2020,69(3):280-290
The enhancement of the thermal conductivity, keeping the electrical insulation, of epoxy thermosets through the addition of pristine and oxidized carbon nanotubes (CNTs) and microplatelets of boron nitride (BN) was studied. Two different epoxy resins were selected: a cycloaliphatic (ECC) epoxy resin and a glycidylic (DGEBA) epoxy resin. The characteristics of the composites prepared were evaluated and compared in terms of thermal, thermomechanical, rheological and electrical properties. Two different dispersion methods were used in the addition of pristine and oxidized CNTs depending on the type of epoxy resin used. Slight changes in the kinetics of the curing reaction were observed in the presence of the fillers. The addition of pristine CNTs led to a greater enhancement of the mechanical properties of the ECC composite whereas the oxidized CNTs presented a greater effect in the DGEBA matrix. The addition of CNTs alone led to a marked decrease of the electrical resistivity of the composites. Nevertheless, in the presence of BN, which is an electrically insulating material, it was possible to increase the proportion of pristine CNTs to 0.25 wt% in the formulation without deterioration of the electrical resistivity. A small but significant synergic effect was determined when both fillers were added together. Improvements of about 750% and 400% in thermal conductivity were obtained in comparison to the neat epoxy matrix for the ECC and DGEBA composites, respectively. © 2019 Society of Chemical Industry 相似文献
35.
介绍机械制造厂燃煤锅炉的烟尘特点,分析滤料失效的原因,提出一套针对该工况的滤料解决方案。介绍针对复杂工况条件所选用的纤维种类以及复合面层原料成分配比的确定,最终选用针刺工艺加工并对该新产品的基本性能进行了测试分析。 相似文献
36.
Meifang Luo Chaozhong Guo Xinyi Luo Zhaoxu Li Yuan Qin Weizhong Zhang 《International Journal of Hydrogen Energy》2021,46(2):2117-2127
It is of great urgency to design inexpensive and high-performance oxygen reduction reaction (ORR) electrocatalysts derived from biowastes as substitutes for Pt-based materials in electrochemical energy-conversion devices. Here we propose a strategy to synthesize three-dimensional (3D) porous nitrogen-doped network carbons to catalyze the ORR from two-step pyrolysis engineering of biowaste scale combined with the use of a ZnCl2 activator and a FeCl2 promotor. Electrochemical tests show that the synthesized network carbons have exhibited comparable ORR catalytic activity with a half-wave potential (~0.85 V vs. RHE) and outstanding cyclical stability in comparison to the Pt/C catalyst. Beyond that, a high electron transfer number (~3.8) and a low peroxide yield (<7.6%) can be obtained, indicating a four-electron reaction pathway. The maximum power density is ~68 mW cm?2, but continuous discharge curves (at a constant potential of ~1.30 V) for 12 h are not obviously declined in Zn-air battery tests using synthesized network carbons as the cathodic catalyst. The formation of 3D porous structures with high BET surface area can effectively expose the surface catalytic sites and promote mass transportation to boost the ORR activity. This work may open a new idea to prepare porous carbon-based catalysts for some important reactions in new energy devices. 相似文献
37.
38.
Yuhuan Sun Hongshuang Qin Zhengqing Yan Chuanqi Zhao Jinsong Ren Xiaogang Qu 《Advanced functional materials》2019,29(14)
Recently, quorum sensing (QS) inhibitors (QSIs) have been combined with antibiotics to enhance antibiofilm efficacy in vitro and in vivo. However, targeting QS signals alone is not enough to prevent bacterial infections. Drug resistance and recurrence of biofilms makes it difficult to eradicate. Herein, photodynamic therapy (PDT) is selected to unite QSIs and antibiotics. A synergistically antibiofilm system, which combines QSIs, antibiotics, and PDT based on hollow carbon nitride spheres (HCNSs) is envisaged. First, HCNS provides the multidrug delivering ability, enabling QSIs and antibiotics to be released in sequence. Subsequently, multistage releases sensitize bacteria effectively, potentiating the chemotherapeutic effects of the antibiotics. Finally, the integration of QSIs and PDT not only minimizes the possibility of drug resistance, but also overcomes the problem of limited mass and extension of PDT. Even after 48 h of incubation, the bacterial biofilm is obviously inhibited. And its biofilm disperse efficiency exceeds 48% (compared with QSI‐potentiated chemotherapy group) and 40% (compared with PDT group). Besides, the inhibition of the QS system influences phenotypes related to virulence factor production and surface hydrophobicity, which weaken biofilm invasion and formation. Eventually, this system is applied to disperse bacterial biofilm in vivo. Overall, PDT and QS modulation are devoted to eradicate drug resistance and recurrence of the biofilm. 相似文献
39.
40.
Thermosetting materials are widely used as encapsulation in the electrical packaging to protect the core electronic components from external force, moisture, dust, and other factors. However, the spreading and curing behaviors of such kind of fluid on a heated surface have been rarely explored. In this study, we experimentally and numerically investigated the spreading and curing behaviors of the silicone(OE6550 A/B, which is widely used in the light-emitting diode packaging) droplet with diameter of ~2.2 mm on a heated surface with temperature ranging from 25 ℃ to 250 ℃. For the experiments, we established a setup with high-speed camera and heating unit to capture the fast spreading process of the silicone droplet on the heated surface. For the numerical simulation, we built a viscosity model of the silicone by using the Kiuna's model and combined the viscosity model with the Volume of Fluid(VOF) model by the User Defined Function(UDF) method. The results show that the surface temperature significantly affected the spreading behaviors of the silicone droplet since it determines the temperature and viscosity distribution inside the droplet. For surface temperature varied from 25 ℃ to 250 ℃, the final contact radius changed from ~2.95 mm to ~1.78 mm and the total spreading time changed from ~511 s to ~0.15 s. By further analyzing the viscosity evolution of the droplet, we found that the decreasing of the total spreading time was caused by the decrease of the viscosity under high surface temperature at initial spreading stage, while the reduction of the final contact radius was caused by the curing of the precursor film. This study supplies a strategy to tuning the spreading and curing behavior of silicone by imposing high surface temperature, which is of great importance to the electronic packaging. 相似文献