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111.
A newly developed catalyst type DVR-1 for catalytic cracking of Daqing vacuum resid was put into use in a commercial VRFCC unit,This catalyst features uniquely active matrix and modified ultra-stable zeolite.The commercial application results show that the DVR-1 type catalyst has the advantage of high heavy oil conversion,good metal tolerance nd gooed stability for catalyst regeneration,The FCC tests have shown Favorable product distribution,acceptable product quality and enormaous economic benefits whe processing the feedstock containin 75%-100% Daqing VR. 相似文献
112.
采用溶胶-凝胶法制备具有介孔结构的降硫基质材料,选择具有降硫选择性的活性元素对合成的基质材料进行改性处理,考察不同的改性方法对制得的催化裂化原位降硫助剂性能的影响,并对基质材料和降硫助剂的结构进行表征。采用美国进口的ACE-R小型催化裂化评价装置将降硫助剂与催化裂化催化剂匹配进行性能评价,在不改变原催化裂化产品分布和产品性质的同时,降低原料的总硫含量,总硫降低可达40%以上。 相似文献
113.
详述了国内外最新渣油催化裂化、多产柴油催化裂化、低碳烯烃催化裂化、生产清洁燃料催化裂化及催化剂的技术进展,同时根据我国实际情况对今后催化裂化技术的发展提出了建议。 相似文献
114.
催化裂化装置结焦问题的探讨 总被引:9,自引:0,他引:9
针对中国石化股份公司所属56套催化裂化装置近两年半以来由于结焦造成非计划停工的原因,进行分析、探讨并提出了解决办法。指出催化裂化装置的结焦虽然是不可避免的、但通过采取有效措施,可以把结焦对装置安全生产的危害降低到最小程度。 相似文献
115.
Ti-45Al-10Nb合金的高温氧化行为 总被引:4,自引:0,他引:4
研究了Ti—45A1—10Nb(原子分数,%)合金在800-960℃在氧气和空气中的氧化行为.结果表明,该合金具有较好的高温抗氧化性能,其氧化增重速率与铁基耐热不锈钢相似或略优.与Ti—50A1合金相反,Ti-45A1-10Nb合金在空气中的氧化增重速率明显低于在纯氧中的氧化增重速率.X射线衍射与能谱分析表明,Ti-45Al一10Nb合金在氧气中的氧化产物主要有TiO2和Al2O3,但在空气中的氧化产物中有TiN相.这是降低氧化速率的主要原因,同时,合金元素Nb稳定了氧化层中的TiN相,因而提高了合金在空气中的抗氧化性能. 相似文献
116.
P. Cañizares J. García-Gómez C. Sáez M.A. Rodrigo 《Journal of Applied Electrochemistry》2003,33(10):917-927
The electrochemical oxidation of 4-chlorophenol, 2,4-dichlorophenol and 2,4,6-trichlorophenol aqueous wastes using boron-doped diamond electrodes was studied. This treatment led to complete mineralization of the wastes regardless of the operating conditions. A simple mechanistic model is consistent with the voltammetric and electrolysis results. According to this model, the electrochemical treatment of chlorophenol aqueous wastes involves the anodic and cathodic release of chlorine followed by the formation of non-chlorinated aromatic intermediates. Subsequent cleavage of the aromatic ring gives rise to non-chlorinated carboxylic acids. Chlorine atoms arising from the hydrodehalogenation of the chlorophenols are converted into more oxidized molecules at the anode. These molecules react with unsaturated C4 carboxylic acid to finally yield trichloroacetic acid through a haloform reaction. The non-chlorinated organic acids are ultimately oxidized to carbon dioxide and the trichloroacetic acid into carbon dioxide and volatile organo-chlorinated molecules. Both direct and mediated electrochemical oxidation processes are involved in the electrochemical treatment of chlorophenols. 相似文献
117.
The catalytic activity of fresh Pd and Pt catalysts supported on γ-alumina in the complete oxidation of CH4 traces under lean-burn conditions was studied in the presence or the absence of water or H2S. Steam-aged catalysts were also studied in order to simulate long-term ageing in real lean-burn natural gas fuelled vehicles (NGVs) exhaust conditions. Without water or H2S added to the feed, Pd catalysts exhibit a superior catalytic activity in methane oxidation compared to Pt ones, whatever the catalysts were fresh or aged. The addition of 10 vol.% water vapour to the feed strongly affects the activity of the fresh Pd catalyst, thus being only slightly more efficient than the fresh Pt one. H2S has a strong poisoning effect on the catalytic activity of Pd catalysts, while Pt catalysts are more resistant. The fresh H2S-poisoned Pd/Al2O3 catalyst was studied by TPD in O2/He. Poisoning species decompose above 873 K as SO2 and O2 in relative concentrations consistent with the decomposition of surface sulphate species. However, a treatment in O2/He at temperatures as high as 923 K does not allow the complete regeneration of the catalytic activity of H2S-poisoned Pd/Al2O3. A mechanism involving the poisoning of PdO by sulphate species is proposed. Different diffusion processes by which these sulphate species can migrate back and forth between PdO and the support, depending on the experimental conditions, are suggested. 相似文献
118.
119.
Nerea Burgos María Paulis M. Mirari Antxustegi Mario Montes 《Applied catalysis. B, Environmental》2002,38(4):251-258
Pt impregnated metallic monoliths prepared from anodised aluminium foils were tested to study their catalytic activity in complete oxidation of volatile organic compound (VOC) mixtures. The VOCs oxidised were 2-propanol, toluene, methyl ethyl ketone (MEK), acetone and their mixtures. Complete oxidation was obtained in all cases except for the case of 2-propanol, where acetone was found as an oxidation intermediate. Even if the adsorption of the VOC on the Al2O3 is governed by its polarity, the reactivity is mainly affected by the competition of the oxygen atoms chemisorbed on the Pt particles. 相似文献
120.
在SHBWR汽液平衡方程、幂函数型动力学方程的基础上,假定每个催化床层为-全混流反应器,建立了碳三催化蒸馏选择加氢数学模型,利用二阶P-K算法进行收敛计算。提出了给反应速率方程添加收敛引子,结合“向上逐层累加”法使模型收敛的方案。 相似文献