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41.
Nerea Burgos María Paulis M. Mirari Antxustegi Mario Montes 《Applied catalysis. B, Environmental》2002,38(4):251-258
Pt impregnated metallic monoliths prepared from anodised aluminium foils were tested to study their catalytic activity in complete oxidation of volatile organic compound (VOC) mixtures. The VOCs oxidised were 2-propanol, toluene, methyl ethyl ketone (MEK), acetone and their mixtures. Complete oxidation was obtained in all cases except for the case of 2-propanol, where acetone was found as an oxidation intermediate. Even if the adsorption of the VOC on the Al2O3 is governed by its polarity, the reactivity is mainly affected by the competition of the oxygen atoms chemisorbed on the Pt particles. 相似文献
42.
根据计算机的辅助分析,采用新的钢锭传搁、注后强制水冷却、垫铁脱模等工艺后,入炉钢锭的热焓已超过开坯轧制需要,利用普通均热炉代替钢锭保温车,可完全依靠到钢锭自身潜热与显热进行均热。对不同锭型与钢种采用经试验的最佳时间均热后再轧制,收与保温车均热钢锭直接轧制相同的效果。 相似文献
43.
纤维素酶分子的计算机辅助序列分析 总被引:3,自引:0,他引:3
利用生物大分子数据库(EMBL、SWALL和PDB)及软件技术(DNASIS和AntheProt)对嗜热子囊菌(Thermoascus aurantiacus)的产生的一种纤维素酶分子进行了序列分析及结构预测;通过多种来源的纤维素酶的比较研究,分析了其催化区、活性位点及局部保守序列。 相似文献
44.
Modified Imidazoles: Degradation Inhibitors and Adhesion Promoters for Polyimide Films on Copper Substrates 总被引:1,自引:0,他引:1
Polyimide films on copper substrates that are exposed to elevated temperatures and an oxidizing environment will be subject to degradation. In order to halt this degradation without changing the properties of the system, a polymeric agent could be placed between the polyimide and the copper. This paper will investigate three such materials that will not only slow down the degradation of the polyimide and the oxidation of the copper, but will also improve adhesion within the system. Fourier transform infrared reflection-absorption spectroscopy (FTIR-RAS) will be used to investigate the polyimide/polymeric agent/copper system. 相似文献
45.
It is shown that steady-state kinetic data do not allow the discrimination between the redox and associated mechanisms of the partial oxidation reactions. A discrimination between these mechanisms was performed using transient experiments. The obtained rate expressions are in agreement with experimental kinetic data for catalytic partial oxidation of o-xylene.
An influence of the conjugate oxidation of a catalyst surface on dynamics and kinetics of the heterogeneous catalytic oxidative reactions is considered. Computing simulation of methane oxidative coupling of methane reaction at lowered temperature and elevated pressure has been performed. It showed that the reaction order with respect to oxygen exceeding unity is consistent with the chain branching mechanism of the reaction in the presence of TiSi2 and TiB2 and showed the important role of the branching chain cycles in the low-temperature OCM reaction at elevated pressure. 相似文献
46.
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48.
Duane J. Lewis 《Journal of the American Ceramic Society》1991,74(10):2410-2413
Mixed-oxide systems are of interest in a variety of technical ceramic applications. The key in many systems is to achieve a high degree of homogeneity, approaching the molecular level. A technique for producing mixed oxides via direct oxidation of mixtures of organometallic compounds is discussed as a potential route. Preliminary work performed on producing mullite is discussed. 相似文献
49.
Huseyin Selcuk Jeosadaque J Sene Marc A Anderson 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2003,78(9):979-984
This study addresses the removal of humic acid (HA) dissolved in an aqueous medium by a photoelectrocatalytic process. UV254 removal and the degradation of color (Vis400) followed pseudo‐first order kinetics. Rate constants were 1.1 × 10?1 min?1, 8.3 × 10?2 min?1 and 2.49 × 10?2 min?1 (R2 > 0.97) for UV254 degradation and 1.7 × 10?1 min?1, 6.5 × 10?2 min?1 and 2.0 × 10?2 min?1 for color removal from 5 mg dm?3, 10 mg dm?3 and 25 mg dm?3 HA respectively. Following a 2 h irradiation time, 96% of the color, 98% of the humic acid and 85% of the total organic carbon (TOC) was removed from an initial 25 mg dm?3 HA solution in the photoanode cell. Photocatalytic removal on the same photoanode was also studied in order to compare the two methods of degradation. Results showed that the photoelectrocatalytic method was much more effective than the photocatalytic method especially at high pH values and with respect to UV254 removal. The effect of other important reaction variables, eg pH, external potential and electrolyte concentration, on the photoelectrocatalytic HA degradation was also studied. Copyright © 2003 Society of Chemical Industry 相似文献
50.
Ulla I. Brimberg Afaf Kamal‐Eldin 《European Journal of Lipid Science and Technology》2003,105(2):83-91
The influence of minor amounts of pro‐ and anti‐oxidants on the kinetics of the autoxidation of fat has been evaluated. The reaction rates of oxygen with the substrates were found to follow the same basic equation, hitherto established for pure substrates. There is evidence that the surface of the reaction vessel also acts as a reaction catalyst and its effect is proportional to the area of glass in contact with lipids. Oxidation is enhanced by trace metal ions as well as by surface‐active compounds (e.g. hydroperoxides and sterols). Antioxidants such as α‐tocopherol and butylated hydroxyanisole inhibit the oxidation by delaying the start of oxygen consumption (the induction period) while retarders like amino acids only decrease the rate of oxidation. Thus pro‐ and anti‐ oxidants affect either the start or the rate of oxygen consumption. The empirical formula dx/dt = k [O2] (1‐x/n) f′(t) was found applicable to the different stages of oxidation. 相似文献