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61.
以钛酸酯偶联剂为表面处理荆,对粉煤灰进行表面处理,制得橡胶填料,测试了该填料对橡胶的补强作用。实验表明,表面改性后的粉煤灰对橡胶具有较好的补强作用。可完全替代碳酸钙、碳酸镁或陶土,产生较好的补强效果,用来替代部分发黑,可以减少发黑的用量,降低橡胶的成本。 相似文献
62.
以丙烯酰胺(AM)与甲基丙烯酰胺丙基三甲基氯化铵(MAPTAC)为共聚单体,通过紫外光引发聚合法制备阳离子聚丙烯酰胺絮凝剂P(AM-MAPTAC)。通过红外光谱(IR)与差热热重分析(TG/DSC)分别对P(AM-MAPTAC)进行结构表征与热稳定性分析,并采用响应曲面法得到优化制备条件:反应体系pH为4.75,引发剂v-044质量分数为0.07%,EDTA-2Na质量分数为0.20%,n(MATPAC)/n(AM)为0.33,光照时间为60 min。在优化条件下制备P(AM-MAPTAC)絮凝剂,特性粘度可达14.72 dL/g,通过污泥脱水实验可验证该特性粘度下的污泥脱水效果最好,滤饼含水率(FCMC)达70%,污泥比阻(SRF)达6.94×1012m/kg,上清液剩余浊度达9.70 NTU,污泥脱水效果优于市售常用絮凝剂。 相似文献
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67.
Engineering Transition Metal Layers for Long Lasting Anionic Redox in Layered Sodium Manganese Oxide
Natalia Voronina Jun Ho Yu Hee Jae Kim Najma Yaqoob Olivier Guillon Hyungsub Kim Min-Gi Jung Hun-Gi Jung Koji Yazawa Hitoshi Yashiro Payam Kaghazchi Seung-Taek Myung 《Advanced functional materials》2023,33(5):2210423
Oxygen-redox-based-layered cathode materials are of great importance in realizing high-energy-density sodium-ion batteries (SIBs) that can satisfy the demands of next-generation energy storage technologies. However, Mn-based-layered materials (P2-type Na-poor Nay[AxMn1−x]O2, where A = alkali ions) still suffer from poor reversibility during oxygen-redox reactions and low conductivity. In this work, the dual Li and Co replacement is investigated in P2-type-layered NaxMnO2. Experimentally and theoretically, it is demonstrated that the efficacy of the dual Li and Co replacement in Na0.6[Li0.15Co0.15Mn0.7]O2 is that it improves the structural and cycling stability despite the reversible Li migration from the transition metal layer during de-/sodiation. Operando X-ray diffraction and ex situ neutron diffraction analysis prove that the material maintains a P2-type structure during the entire range of Na+ extraction and insertion with a small volume change of ≈4.3%. In Na0.6[Li0.15Co0.15Mn0.7]O2, the reversible electrochemical activity of Co3+/Co4+, Mn3+/Mn4+, and O2-/(O2)n- redox is identified as a reliable mechanism for the remarkable stable electrochemical performance. From a broader perspective, this study highlights a possible design roadmap for developing cathode materials with optimized cationic and anionic activities and excellent structural stabilities for SIBs. 相似文献
68.
高功率、高容量的LiNi_(0.8)Co_(0.15)Al_(0.05)O_2(NCA)正极锂离子电池在电动汽车和定置储能电池等行业中具有非常广阔的应用前景。为使其更具商业竞争力,NCA锂电池的使用寿命至少需要延长至15年,这对现行技术而言是一个很大的挑战。因此,明确NCA锂电池在循环和储存过程中性能衰减机理是延长NCA动力电池使用寿命的关键。大量研究表明正极表面膜的形成、表面盐岩结构类NiO相的出现、显微裂纹的产生、表面导电碳基体的恶化等因素是NCA动力电池衰减的主要原因。通过常规原子掺杂、表面包覆等方法在一定程度上能有效抑制正极材料的恶化,延长锂离子电池的使用寿命。 相似文献
69.
Flexible Cationic Nanoparticles with Photosensitizer Cores for Multifunctional Biomedical Applications
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Rui Wu Xiaokang Ding Yu Qi Qiang Zeng Yu‐Wei Wu Bingran Yu Fu‐Jian Xu 《Small (Weinheim an der Bergstrasse, Germany)》2018,14(22)
One challenge for multimodal therapy is to develop appropriate multifunctional agents to meet the requirements of potential applications. Photodynamic therapy (PDT) is proven to be an effective way to treat cancers. Diverse polycations, such as ethylenediamine‐functionalized poly(glycidyl methacrylate) (PGED) with plentiful primary amines, secondary amines, and hydroxyl groups, demonstrate good gene transfection performances. Herein, a series of multifunctional cationic nanoparticles (PRP) consisting of photosensitizer cores and PGED shells are readily developed through simple dopamine‐involving processes for versatile bioapplications. A series of experiments demonstrates that PRP nanoparticles are able to effectively mediate gene delivery in different cell lines. PRP nanoparticles are further validated to possess remarkable capability of combined PDT and gene therapy for complementary tumor treatment. In addition, because of their high dispersities in biological matrix, the PRP nanoparticles can also be used for in vitro and in vivo imaging with minimal aggregation‐caused quenching. Therefore, such flexible nanoplatforms with photosensitizer cores and polycationic shells are very promising for multimodal tumor therapy with high efficacy. 相似文献
70.
Kiselev NA Kumskov AS Zakalyukin RM Vasiliev AL Chernisheva MV Eliseev AA Krestinin AV Freitag B Hutchison JL 《Journal of microscopy》2012,246(3):309-321
Nanocomposites consisting of one-dimensional (1D) crystals of the cationic conductors CuI, CuBr and AgBr inside single-walled carbon nanotubes, mainly (n, 0), were obtained using the capillary technique. 1D crystal structure models were proposed based on the high resolution transmission electron microscopy performed on a FEI Titan 80-300 at 80 kV with aberration correction. According to the models and image simulations there are two modifications of 1D crystal: hexagonal close-packed bromine (iodine) anion sublattice (growth direction <001>) and 1D crystal cubic structure (growth direction <112>) compressed transversely to the nanotube (D(m) ~1.33 nm) axis. Tentatively this kind of 1D crystal can be considered as monoclinic. One modification of the anion sublattice reversibly transforms into the other inside the nanotube, probably initiated by electron beam heating. As demonstrated by micrographs, copper or silver cations can occupy octahedral positions or are statistically distributed across two tetrahedral positions. A 1DAgBr@SWNT (18, 0; 19, 0) pseudoperiodic 'lattice distortion' is revealed resulting from convolution of the nanotube wall function image with 1D cubic crystal function image. 相似文献