聚丙烯的官能化及其与尼龙66相容性研究

对聚丙烯（PP）进行官能化，并研究了接枝单体含量，引发剂含量，螺杆转速对接枝率和熔体流动速率的影响。再将不同接枝率的PP与尼龙66共混，研究了接枝率对共混物力学性能及相容性的影响；用扫描电子显微镜观察了共混物的形态，与未增容共混体系相比，增容后共混体系分散相尺寸明显减小，增容共混物的形态依赖于增容剂在共混物中的含量，增容剂的分子量及官能化基团的含量。     

LLDPE-g-GMA对PA66/PE性能影响的研究

研究了LLDPE—g—GMA(甲基丙烯酸缩水甘油酯)对PA66／PE相容性的影响。结果表明LLDPE-g-GMA是PA66／PE合金良好的反应型增容剂，对于PA66／PE合金，LLDPE—g-GMA的加入使合金的拉伸强度、弯曲强度、Izod缺口冲击强度有明显提高。但刚性和耐热性略有降低，并且DMA谱图证实了LLDPE—g-GMA对PA66／PE的反应增容作用，计算出了PA66／PE玻璃化转变活化能。     

Manipulating the phase morphology in PPS/PA66 blends using clay

By adding a small amount of clay into poly(p‐phenylene sulfide) (PPS)/polyamide 66 blends, the morphology was found to change gradually from sea–island into cocontinuity and lamellar supramolecular structure, as increasing of clay content. Clay was selectively located in the PA66 phase, and the exfoliated clay layers formed an edge‐contacted network. The change of morphology is not caused by the change of volume ratio and viscosity ratio but can be well explained by the dynamic interplay of phase separation between PPS and PA66 through preferential adsorption of PA66 onto the clay layers and through layer–layer repulsion. This provides a means of manipulating the phase morphology for the immiscible polymer blends. The mechanical and tribological properties of PPS/PA66 blends with different phase morphologies (different clay contents) were studied. Both tensile and impact strength of the blends were found obviously increased by the addition of clay. The antiwear property was greatly improved for the blends with cocontinuous phase form. Our work indicates that the phase‐separating behavior of polymer blends contained interacting clay can be exploited to create a rich diversity of new structures and useful nanocomposites. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

PA66聚合釜底阀电气控制系统的改进

详细介绍了尼龙(PA)66聚合釜底阀的液压及电气控制原理,分析了国产PA66聚合釜底阀电气控制部分存在的问题,并在现有电气控制图的基础上进行了改进,达到了预期效果。     

用聚丙烯酸酯乳液提高轮胎帘线储存稳定性

研究了一种自交联型五元共聚聚丙烯酸酯乳液的单体种类和配比、加料顺序、表面活性剂的种类和用量、引发剂用量等合成工艺因素与乳液稳定性及其增粘和防紫外线、臭氧老化的关系。用这种乳液改性的ＲＦＬ浸渍液处理锦纶６６轮胎帘线，可以显著改善帘线的储存稳定性。     

MPPO/PA66合金体系流变性能的研究

研究了MPPO／PA66组成、相容剂用量、加工温度等因素对MPPO／PA66合金体系流变性能的影响。结果表明相容剂用量的增加、加工温度的升高等都能降低体系的粘度，改善其加工流动性。     

热裂解气质联用鉴别PA56、PA66和PA6

采用热裂解气质联用（Py-GC/MS）方法鉴别聚酰胺56（PA56）、聚酰胺66（PA66）和聚酰胺6（PA6）及其共混物。结果表明,在550 ℃裂解温度下,PA56与PA66相对丰度100 %的峰为环戊酮,分别具有特征裂解产物1,8-二氮杂环十三烷-2,7?二酮和1,8-二氮杂环十四烷-2,7-二酮,PA6相对丰度100 %的峰为己内酰胺;此方法可用于快速鉴别PA56、PA66和PA6的工业初级品,并成功检出了PA6/PA56共混物、PA6/PA66改性共混物与改性PA66。     

Quantifying requirements volatility effects

In an organization operating in the bancassurance sector we identified a low-risk IT subportfolio of 84 IT projects comprising together 16,500 function points, each project varying in size and duration, for which we were able to quantify its requirements volatility. This representative portfolio stems from a much larger portfolio of IT projects. We calculated the volatility from the function point countings that were available to us. These figures were aggregated into a requirements volatility benchmark. We found that maximum requirements volatility rates depend on size and duration, which refutes currently known industrial averages. For instance, a monthly growth rate of 5% is considered a critical failure factor, but in our low-risk portfolio we found more than 21% of successful projects with a volatility larger than 5%. We proposed a mathematical model taking size and duration into account that provides a maximum healthy volatility rate that is more in line with the reality of low-risk IT portfolios. Based on the model, we proposed a tolerance factor expressing the maximal volatility tolerance for a project or portfolio. For a low-risk portfolio its empirically found tolerance is apparently acceptable, and values exceeding this tolerance are used to trigger IT decision makers. We derived two volatility ratios from this model, the π-ratio and the ρ-ratio. These ratios express how close the volatility of a project has approached the danger zone when requirements volatility reaches a critical failure rate. The volatility data of a governmental IT portfolio were juxtaposed to our bancassurance benchmark, immediately exposing a problematic project, which was corroborated by its actual failure. When function points are less common, e.g. in the embedded industry, we used daily source code size measures and illustrated how to govern the volatility of a software product line of a hardware manufacturer. With the three real-world portfolios we illustrated that our results serve the purpose of an early warning system for projects that are bound to fail due to excessive volatility. Moreover, we developed essential requirements volatility metrics that belong on an IT governance dashboard and presented such a volatility dashboard.     

电子束辐照对尼龙66纤维结构和力学性能的影响

研究了室温空气条件下电子束辐照剂量(范围0~1000 k Gy)对尼龙66纤维结构和力学性能的影响。利用广角X射线衍射仪、差示扫描量热仪、扫描电镜以及YG065型织物强力仪等测试方法研究了不同辐照剂量尼龙66的特性黏数、晶型结构、取向度、结晶和熔融行为,以及表面形貌和力学性能。研究结果表明,在设置的辐照剂量范围内,随着剂量的增加,纤维原有的晶型结构不变,但是,伴随辐照诱导非晶区分子链的重排,纤维的结晶度提高,取向有所改善,而结晶和熔融温度向低温偏移,熔融峰出现宽化。说明辐照主要导致尼龙66分子链氧化降解,降低其热稳定性,在电子束的撞击下,纤维表面产生了微裂纹,增加了应力集中,破坏了纤维的力学性能。     

2A66铝锂合金板材各向异性研究

采用布氏硬度与拉伸性能测试以及OM,SEM和TEM分析,研究2A66铝锂合金板材力学性能的各向异性随时效时间变化的规律和合金时效状态下的显微组织,并探讨影响各向异性的主要因素。结果表明:165℃峰值时效前,随时效时间的延长,2A66铝锂合金力学性能的各向异性程度逐渐下降,过时效后合金的各向异性有所增强,伸长率的各向异性大于强度各向异性。峰时效(64h)时合金的σ_b,σ_(0.2),δ的IPA值均达到了最低值,分别为3.0%,3.0%,12.2%,此时合金也获得了较好的强塑性结合,轴向σ_b,σ_(0.2),δ分别为526.5,448.9MPa,10.1%。不同热处理状态下,2A66铝锂合金平面各向异性的总体表现为:纵向(0°)和横向(90°)的强度最高,45°方向最低;45°方向试样的伸长率最高,纵向和横向最低。