有机EL的稳定性和寿命

介绍了有机ＥＬ在稳定性及寿命方面的最新研究动态，着重描述了器件功能层组合的相互接触、阴极、空穴传输层玻璃化温度和驱动条件等对有机ＥＬ稳定性和寿命的影响。     

Hydride Vapor Phase Epitaxy of GaN Thick Films by the Consecutive Deposition Process Using GaCl3

GaN buffer and main layers were grown by the conventional hydride vapor phase epitaxy technique using GaCl₃ consecutively. The deposited buffer layers were investigated by atomic force microscopy and X-ray analysis. To examine the behavior of the buffer layers at main layer growth temperature, heat treatment was conducted at 900°C. Based on the results of the buffer layer study, GaN thick films were grown at 1050°C. Optimum deposition conditions of buffer layer from the buffer and main layer studies generally coincided. On the φ scanning pattern, the GaN films grown on (0001) Al₂O₃ were single-crystalline. Band-edge emission dominated photoluminescence was observed at room temperature.     

Influence of Lanthanum on Fluorescence Properties of Ag-BaO Thin Films

Ag-BaO thin films doped with lanthanum were prepared by vacuum deposition. Compared with the normal Ag-BaO thin film, there is almost no change with the shape and the peak site of the fluorescence spectrum; however, fluores-cence emission strength of the whole observation band(325 -600 nm)increases about 40%, and the increase of short wavelength range is more remarkable than that of long wavelength range, which we named “blue-stronger“ phenomenon. Analytic results show that, with the forming of intermetallic compounds between silver and lanthanum, the 4f-state energy levels lie just below the Fermi level within 5 eV. It is the energy exchange between the 4f energy levels and the conduction band that causes the increase effect of fluorescence emission, and it is the optical absorption cross section of 4f electron, which increases with the increase of energy of incidence photon, that gives rise to the “blue-stronger“ phenomenon.     

小型密闭压力容器测试系统重复性的研究

小型密闭压力容器测试（MCPVT）法是安全工程领域中近几年发展起来的、评价有机过氧化物及自反应物质受热分解反应激烈程度的新方法。pmax是MCPVT方法中用来表征自反应物质受热分解反应激烈程度的物理量之一。文中通过大量实验，研究了样品容器容积V、升温速率R及样品质量M对pmax重复性误差的影响，研究了一系列典型的有机过氧化物和自反应物质在标准实验条件下pmax重复性误差。结果表明，小型密闭压力容器测试系统重复性好，测试结果可靠，从而为MCPVT法最终成为国际上评价自反应物质受热分解反应激烈程度标准方法奠定了基础。     

Hysys软件在分析精丙烯硫化物来源中的应用

气体分馏装置原料液化石油气 (LPG)中有机硫化物形态复杂 ,考察分析工业装置精丙烯硫化物含量变化难度大。利用Hysys模拟 ,分析判断LPG中小分子有机硫化物在气体分馏产品的分布并提出了控制措施。考虑操作条件对精丙烯硫含量的影响 ,并对工业装置精丙烯总硫超标原因进行了分析。     

低压宽温高频铝电解电容器工作电解液

在传统的己二酸铵/乙二醇加水体系中,通过增加水的含量实现高电导率,同时在电解液中添加多种有机高分子物质形成复合添加剂,改善工作电解液的高温稳定性,使电容器上限工作温度扩展到105℃,形成高频宽温低阻抗工作电解液。     

Alternating,all-trans polyenynes: Model compounds for poly(diacetylene)s with defined conjugation length

The syntheses of polyenynes as model compounds for poly(diacetylene)s (PDAs) are described. Variation of properties (UV–VIS, Raman, NMR and bond geometries) as a function of the chain length was investigated. After extrapolation to infinite chain length these data were compared to those for PDAs. From UV–VIS spectra a value of λ = 551 nm (2.25 eV) was calculated corresponding to the electronic transition of a single polyenyne chain. This energy is located at the low energy end of a yellow PDA solution spectrum. From Raman scattering v_(C?C) = 2108–2128 cm^?1 and v_(C?C) = 1505–1532 cm^?1 were calculated after extrapolation. Similarly sp-C¹³C NMR data yielded a shift of δ = 100 ppm. These data are almost identical to data known for yellow PDA solutions. Bond geometries are almost identical to those of poly(diacetylene)s and theoretical data.     

Facile optical resolution of amino acid esters via hydrolysis by an industrial enzyme in organic solvents

Racemic amino acid esters were optically resolved via hydrolysis in organic solvents by the catalysis of an industrial alkaline protease, “Alcalase”. The products which were composed mainly of L-amino acids were insoluble and easily separated by filtration. The activity of the enzyme and enantiomeric excess of the products were significantly dependent on the nature of solvent and the water content in the reaction media. Generally, high values of enantiomeric excess were obtained at low water contents. Many natural and unnatural amino acids were resolved by this method.     

肥料中有机质分析方法的探讨

探讨肥料中有机质的分析方法。通过对两个肥料标准中有机质的分析方法进行比较，对各标准中有机质检验过程中的影响因素进行了分析，确定了本地区有机肥料中有机质适宜的分析方法。