Restoration of the red colour of photo-bleached carthamine in calcium-alginate gel membranes

The restoration of the red colour of carthamine (photo-bleached in polymeric heterosaccharide gels) was investigated using sodium salts, potassium salts, and alkali. Ca-alginate gel was stained with carthamine, and the red-dish membranes were exposed to fluorescent light for 2·5, 4·0 and 20 h (at 28°C). The resulting orange-yellow gel membranes were treated with Na- or K-citrate solution and the restoration of the red colouration was followed spectrophoto-metrically. The results indicate that the red colour of carthamine can be retained within the gel membranes, while yellow-coloured compounds were removed and/or transformed by the alkaline salt solutions.     

地震和测井联合反演储层波阻抗技术

通过地震和测井联合反演，可以获得高分辨率的井间地层波阻抗分布的信息。综合应用波动方程反演和神经网络分析来反演地层波阻抗参数，其过程分3步：第一步，应用先验地质知识，对地震数据和测井曲线进行地质解释，并对油井曲线进行对层和标定，然后求取相应的层速度的低频信息，旨在搞清井间地层结构状况，为线性反演提供地层产状的先验信息；第二步，应用非线性波动方程反演，在层速度界面及井中物性参数约束下，从地震数据中反演高分辨率的反射系数及波阻抗参数；第三步，应用CUSI神经网络分析方法，以高分辨率的反射系数及波阻抗等参数作为约束，以沿层求取的地震特征作为输入，以井中反演的波阻抗参数为期望输出，对非线性波动方程反演出的波阻抗参数进行非线性标定，得出井间的地层绝对波阻抗物性参数。     

高层建筑损伤识别中的补偿算法

本文在已有研究工作的基础上，提出了处理激励测量信息不完备情况下的补偿算法。此方法主要针对高层建筑动力检测中强迫激励的情况，是一种基于时域的识别方法，该方法实际上是利用客观工程实际中结构系统激励所具有的物理持征作为识别计算的辅助条件，来解决测量信息的不完备性问题。算例分析表明了该方法的可行性。     

关于彩涂压型钢板构件设计中的选材问题

近年来 ,在彩涂压型钢板构件设计应用中 ,由于不重视、不了解如何合理选材 ,在实际工程的材料订货中也都不提出对材料性能的技术要求 ,致使供货材质、材性不能满足使用要求 ,存在降低彩板构件承载力或减少其使用寿命的隐患 ,应引起设计人员的注意。同时对当前如何按使用条件及材料供应条件合理地选定彩板材料的性能技术要求 ,包括基板钢材的级别及力学性能、板厚及公差控制要求、镀锌层质量与彩涂层类别以及参照的技术标准等 ,提出了一些建议 ,供设计应用参考。最后还对板的强度、厚度以及镀铝锌板的选用问题进行了讨论     

Modeling of a power electronic converter for EMC in the conduction emission frequency band

With the advancement of high‐frequency switching devices, electromagnetic interferences (EMI) have become problems in power electronic converter designs. It is necessary for an electromagnetic compatibility (EMC) design to prospect and consider its possible EMI levels. This paper describes how to compute effects from a power converter to an object point to reduce conduction EMI noises effectively by an appropriate design. Modeling techniques for converter elements are discussed for a model in the conduction emission frequency band by the parameter tuning method and for line constants by an analytical derivation. Then a derived model is simulated for harmonic distributions of loop currents and their magnetic fields. © 2002 Scripta Technica, Electr Eng Jpn, 139(1): 44–50, 2002: DOI 10.1002/eej.1145     

Rhizobium trifolii capsular polysaccharide: a novel biopolymer with striking physical properties

The physical properties of the capsular polysaccharide of Rhizobium Trifolii (CPS) were investigated. Viscosity measurements provided information about the hydrodynamic volume of single coils, the perturbation of solvent flow and the shear-thinning behaviour of concentrated solutions. Changes in chain geometry and the development of an intermolecular network as a function of temperature were monitored using the techniques of optical rotation and dynamic oscillation. Finally, analysis of calorimetric thermograms elucidated the type of interactions between CPS and the bacterial levan. Overall, the Rhizobium polysaccharide was found to form thermally-reversible gels at an extremely low 'minimum critical gelling concentration' (c_o∼ 0.35gl^-1). At temperatures above the gel melting point (∼ 48°C), however, the compact polymer coils entangled at comparatively high concentrations (about 60 times higher than c_o). In the presence of a highly branched levan, the thermal stability of ordered CPS structures increased as a consequence of thermodynamic incompatibility between the two polymers.     

凝土温度特性参数反分析及其应用

建立混凝土温度场材料特性参数反演分析模型,并用有限单元法仿真计算和可变容差法编制了优化反演程序。数值算例表明该算法是稳定的,收敛速度较快,并给出具体的在建工程实例的应用情况。通过现场温度观测值,进行优化反演计算得到混凝土温度的有关特性参数,这将成为部分或全部替代仅靠实验室选取参数的行之有效的途径之一。     

二维地震过障碍观测系统模式及其参数设计

在二维地震勘探中,为了避免因地表障碍物使地震反射剖面出现间断现象,需要改变观测系统设计,跨越障碍物(江河、城镇等),以保证反射同相轴能连续追踪对比。在以往地震勘探中,有时因过障碍观测系统设计不合理,不但增加勘探费用,而且影响采集质量。因此只有科学合理地设计过障碍观测系统模式和参数,才能保证地震测线顺利通过障碍物,得到较好的障碍物下方的地震资料并降低勘探成本。为此本文在调查和研究大量野外实际的过障碍观测系统的基础上,总结归纳成三大类过障碍观测系统模式,并分析其特点和应用范围。采用图解法,推导出主要模式的跨越宽度、最小炮检距及最大炮检距等参数公式。采用这套过障碍观测模式不仅可以得到和障碍区两侧等质量的地震资料,而且可以有效地降低勘探成本。     

固定化酵母粒子中生产乙醇的定态分岔行为研究

运用变分原理和打靶法将分布参数系统的非线性边值问题转化为集总参数系统的初值问题，基于延拓算法，研究了固定床中球形固定化酵母粒子表面乙醇和葡萄糖浓度随参数的变化关系，得出了单颗粒固定化酵母生产乙醇的多定态特性。结果表明：随系统尺度三的变化，方程出现分岔点；方程的解与液相主体浓度有关。在某些条件下酵母粒子表面浓度有三个定态：在多定态区域，随三的增加，方程一个解支的乙醇浓度迅速增加，从而可以在固定床中通过控制粒径而使反应器达到较高的产率。研究结果为固定床反应器的开工及控制提供了重要的理论依据。     

Phase equilibria of quasi-binary systems consisting of multicomponent polymers 1 and 2. IV: Poly(ethylene oxide)/poly(propylene oxide) systems

To confirm the reliability of the theory of phase equibria of multicomponent polymer 1/multicomponent polymer 2 systems (i.e. quasi-binary systems) and the method of computer experiment based on this theory (Brit. Polym. J., 23 (1990)285; 23 (1990)299; Polym. Int., 29 (1992)219), could point curves (CPC), two-phase volume ratios ( R ) and critical solution points (CSP) have been determined experimentally for the quasi-binary mixtures of poly(ethylene oxide) (M¯_w = 647, M¯_w/M¯_n = 1.15; M¯_w and M¯_n, the weight-average and numberaverage molecular weights, respectively) and poly(propylene oxide) (M¯_w = 2028, M¯_w/M¯_n = 1.08; and M_w = 2987, M_w/M_n = 1.13). The hydroxyl end groups of both polymers were methoxylated in advance by the Cooper & Booth method (Polymer, 18 (1977)164). The thermodynamic interaction parameter between both polymers, χ₁₂, and the concentration dependence parameters for the above quasi-binary systems were determined by the method proposed in a previous paper (Brit. Polym. J., 23 (1990)299). CPC, R and CSP values calculated on the basis of the theory are in good agreement with the values determined experimentally.