填料并用对双组分室温硫化导热硅橡胶性能的影响

以α,ω-二羟基聚二甲基硅氧烷为基胶,Si3N4、AlN、Al2O3为导热填料,制备了填充型双组分室温硫化（RTV-2）导热硅橡胶.研究了填料Si3N4/Al2O3或AlN/Al2O3并用对RTV-2硅橡胶导热性能、工艺性能及力学性能的影响.结果表明,当填料的总体积分数为0.45时,对于Si3N4/Al2O3填充体系,随着体系中Al2O3体积分数的增加,RTV-2导热硅橡胶的热导率先升后降、拉伸强度先增后减,而扯断伸长率则呈逐渐升高的趋势,基料的粘度先减后增;当Al2O3的体积分数为0.14时,RTV-2导热硅橡胶的热导率最高、拉伸强度最大,基料的粘度最小,综合性能最佳.对于AlN/Al2O3填充体系,随着体系中Al2O3的体积分数的增加,RTV-2导热硅橡胶的热导率先升后降、拉伸强度及扯断伸长率先减后增,基料的粘度呈上升趋势;当Al2O3的体积分数为0.07时,RTV-2导热硅橡胶具有较好的导热性能和工艺性能,但力学性能偏低.     

皮革涂料用丙烯酸酯核-壳乳液的研制

采用种子乳液聚合法，以交联型软性聚合物为核，交联型硬性高聚物为壳，合成了具有优异耐寒性及高温抗回粘性聚合物。讨论了乳化剂种类及应用、核／壳比等对聚合物性能的影响。     

对接型销双向斜抽芯注塑模设计

给出了灯罩注塑模实用结构。该模具型芯由主型芯和副型芯组成，采用将副型芯推出方法实现塑件内侧壁凹槽抽芯，在塑件倾斜通孔处采用对接型销双向分型斜抽芯。既满足制品的成型和抽芯要求，又省去了斜抽芯和水平抽芯机构，模具结构紧凑，脱型可靠，成型塑件质量好。     

油田采出水的精细过滤技术

低渗透油层渗透率〈0．1μm^2，孔喉半径小，容易被堵塞，对注入水质要求高，目前缺乏对含有原油、化学添加剂、粉质颗粒和无机盐的油田采出水适应性强的精细过滤设备。本文介绍了油田采出水回注精细过滤材料试验和采用旋流配水、脉冲水流反洗技术的改性聚四氟乙烯滤芯过滤装置的小试和中试研究情况，研究开发的改性聚四氟乙烯精细过滤装置，当进水含油量〈20mg／L、悬浮物含量〈20mg／L时，出水达到了（《碎屑岩油藏注水水质推荐指标》（SY5329-94）规定的A1级注水水质标准。     

(Ag)_核·(Au)_壳复合纳米粒子的制备

以银原子团簇作晶种,采用微波高压液相合成法制备了分散性好、规则球形的(Ag)核·(Au)壳复合纳米粒子。研究了(Ag)核·(Au)壳复合纳米粒子的紫外可见吸收光谱和共振散射光谱特性。结果表明,液相(Ag)核·(Au)壳复合纳米粒子和高压微波合成的液相金纳米粒子的最强共振散射峰均在580nm处,它们的吸收光谱图相似,最大吸收分别在518.5nm和524.8nm。     

Swelling kinetics of a hydrogel of poly(ethylene glycol) and poly(acrylamide‐co‐styrene)

A hydrogel incorporating the hydrophilic polymer poly(ethylene glycol) and a copolymer of acrylamide and styrene was synthesized, and the dynamics of the water‐sorption process were studied. The effects of the composition of the hydrogel and the temperature of the swelling medium were investigated with respect to the water‐sorption characteristics of the hydrogel, and the kinetic parameters, including the swelling exponent and diffusion constant, were evaluated. The hydrogel was also judged for the antithrombogenic property of its surface. The experimental findings were explained on the basis of the core–shell polymeric structure of the hydrogel. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 1419–1428, 2002     

Contraction stress build‐up of anisotropic conductive films (ACFs) for flip‐chip interconnection: Effect of thermal and mechanical properties of ACFs

The important mechanical mechanism for the electrical conduction of anisotropic conductive films (ACFs) is the joint clamping force after the curing and cooling processes of ACFs. In this study, the mechanism of shrinkage and contraction stress and the relationship between these mechanisms and the thermomechanical properties of ACFs were investigated in detail. Both thickness shrinkages and modulus changes of four kinds of ACFs with different thermomechanical properties were experimentally investigated with thermomechanical and dynamic mechanical analysis. Based on the incremental approach to linear elasticity, contraction stresses of ACFs developed along the thickness direction were estimated. Contraction stresses in ACFs were found to be significantly developed by the cooling process from the glass‐transition temperature to room temperature. Moreover, electrical characteristics of ACF contact during the cooling process indicate that the electrical conduction of ACF joint is robustly maintained by substantial contraction stress below T_g. The increasing rate of contraction stresses below T_g was strongly dependent on both thermal expansion coefficient (CTE) and elastic modulus (E) of ACFs. A linear relationship between the experimental increasing rate and E × CTE reveals that the build‐up behavior of contraction stress is closely correlated with the ACF material properties: thermal expansion coefficient, glassy modulus, and T_g. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 2634–2641, 2004     

聚苯胺/涤纶导电织物再掺杂及洗涤性能的研究

采用现场吸附聚合法制备了聚苯胺 /涤纶导电织物 ,采用不同种类的酸对其进行再掺杂 ,研究了酸的种类对织物导电性能的影响 ,并对导电织物进行了洗涤实验及洗涤牢度实验。结果表明 :无机酸对导电织物的掺杂效果优于大多数有机酸。导电涤纶织物的导电性能受洗涤液酸碱度的影响 ,其中碱性洗涤液使导电性能降低 2个数量级 ,酸性洗涤液使导电性能下降 1个数量级 ,而且聚苯胺在涤纶织物表面具有良好的附着性     

LDPE/石墨导电复合材料的研究

为了制备具有低渗滤阈值的导电复合材料，通过溶液插层法，选用三种不同的导电填料（石墨，膨胀石墨，膨化石墨），引入马来酸酐接枝聚乙烯。制备低密度聚乙烯/石墨导电复合材料，导电填料的结构对复合材料的电性能和力学性能有很大的影响，其中膨化石墨可使复合体系具有较低的导电渗滤阈值，但复合材料的力学性能较差。     

临界组成区域的热敏导电材料加工工艺

研究了开炼，密炼及双螺杆挤出３种不同塑炼方式及采用压制，注射，单螺杆挤出３种不同成型方法对临界组成区域的热敏导电材料电性能及力学性能的影响规律，并对开炼，密炼两种工艺的混炼条件，加料方式及加料顺序进行了考察，结果表明，采用密炼工艺，炭黑（ＣＢ）粒子能得到均匀分布，电阻率较低，拉伸强度及断裂伸长率高，适中的剪切速率及温度有利于ＣＢ粒子分散，采用压制成型法所得样品各向同性。