分光光度法测定锌铁合金镀层及镀液中的铁

采用分光光度法，以磺基水杨酸为显色剂、双氧水为氧化剂，锌铁合金镀层用稀盐酸溶解，控制pH值为1.5～3，在等吸收点处测定吸光度，并根据比耳定律计算镀层及镀液中的铁含量。     

Phase transitions and dimensional and morphological changes in an “Aluminum Hydroxide-Alumina” system under a shock-wave action

A method is proposed to study the sequence of phase transitions in powdered materials under a shock-wave action. It is shown that the content/n24320108ml45547/xxlarge8220.gif" alt="ldquo" align="MIDDLE" BORDER="0">aluminum hydroxide-aluminacontent/n24320108ml45547/xxlarge8221.gif" alt="rdquo" align="MIDDLE" BORDER="0"> system has the following sequence of phase transformations under a shock-wave action: bayerite content/n24320108ml45547/xxlarge8594.gif" alt="rarr" align="BASELINE" BORDER="0"> boehmite content/n24320108ml45547/xxlarge8594.gif" alt="rarr" align="BASELINE" BORDER="0"> content/n24320108ml45547/xxlarge947.gif" alt="gamma" align="MIDDLE" BORDER="0">-Al₂O₃ content/n24320108ml45547/xxlarge8594.gif" alt="rarr" align="BASELINE" BORDER="0"> content/n24320108ml45547/xxlarge945.gif" alt="agr" align="BASELINE" BORDER="0">-Al₂O₃. It is found that there are no transitional high-temperature modifications of alumina. A method is developed for obtaining a submicron alumina powder, which allows obtaining materials with a controlled phase composition, including a thermodynamically stable content/n24320108ml45547/xxlarge945.gif" alt="agr" align="BASELINE" BORDER="0">-modification of Al₂O₃. The specific features of the morphological structure and the phase and structural characteristics of powders after a shock-wave action are considered.Translated from Fizika Goreniya i Vzryva, Vol. 41, No. 1, pp. 110–119, January–February, 2005.     

含水量对渠道保温板保温耐久性的影响及保温板厚度设计

北方渠道大多使用保温板防止混凝土衬砌受冻胀破坏。在计算保温板厚度时为了降低成本,容易忽略保温板使用过程中受各种因素的影响导致保温效果变差的情况,使混凝土衬砌达不到设计使用年限便提前被破坏。内蒙古河套灌区试验结果表明,由于受酸雨、冻融作用、含水量等因素的影响,保温板保温效果平均每年降低0.9℃,其中受含水量变化的影响最大。经试验测得:聚苯乙烯保温板(EPS)含水量每增加1%,会导致导热系数增大5%。基于多层材料串联热阻叠加原理和热阻等效原理,对保温板厚度计算公式进行完善,并提出相应的铺设方法和施工技术要求。该设计对保温板在季节性冻土区的推广应用具有一定参考价值。     

Alcohol consumption detection through behavioural analysis using intelligent systems

We describe in this paper a new methodology for blood alcohol content (BAC) estimation of a subject. Rather than using external devices to determine the BAC value of a subject, we perform a behaviour analysis of this subject using intelligent systems. We monitor the user’s actions in an ordinary task and label those data to various measured BAC values. The obtained data-set is then used to train learning systems to detect alcoholic consumption and perform BAC estimation. We obtain good results on a mono-user base, and lower results with multiple users. We improve the results by combining multiple classifiers and regression algorithms.     

多层水平气流带式干燥机的数学模型

根据干燥传质传热学原理和干燥动力学特性，建立了水平气流带式干燥机干燥过程的数学模型。该模型可以预测干燥机合理的通风道高度、带翻转最佳时间和热风风速等。为优化多层带式干燥机的结构或设计新的水平气流带式干燥机提供了理论依据。     

Surface properties of ZSM-5 modified by phosphorus

Phosphorus modification of ZSM-5 leads to extra framework P⁵⁺ and probably incorporation of +3 valence state of P in the framework. The resulting system has increased Brønsted acidity. Theoretical calculations also favour the postulate that phosphorus in +3 valence state can be incorporated into the lattice.     

Host Plant Volatiles Synergize Response to Sex Pheromone in Codling Moth, Cydia pomonella

Plant volatile compounds synergize attraction of codling moth males Cydia pomonella to sex pheromone (E,E)-8,10-dodecadien-1-ol (codlemone). Several apple volatiles, known to elicit a strong antennal response, were tested in a wind tunnel. Two-component blends of 1 pg/min codlemone and 100 pg/min of either racemic linalool, (E)-beta-farnesene, or (Z)-3-hexen-1-ol attracted significantly more males to the source than codlemone alone (60, 58, 56, and 37%, respectively). In comparison, a blend of codlemone and a known pheromone synergist, dodecanol, attracted 56% of the males tested. Blends of pheromone and plant volatiles in a 1:100 ratio attracted more males than 1:1 or 1:10,000 blends. Adding two or four of the most active plant compounds to codlemone did not enhance attraction over blends of codlemone plus single-plant compounds. Of the test compounds, only farnesol was attractive by itself; at a release rate of 10,000 pg/min, 16% of the males arrived at the source. However, attraction to a 1:10,000 blend of codlemone and farnesol (42%) was not significantly different from attraction to codlemone alone (37%). In contrast, a codlemone mimic, (E)-10-dodecadien-1-ol, which attracted 2% males by itself, had a strong antagonistic effect when blended in a 1:10,000 ratio with codlemone.     

反式-1,4-聚异戊二烯的氯化改性

采用水相悬浮法，在常压下对反式-1，4-聚异戊二烯（TPI）进行氯化改性。研究了温度、时间、粒径等对氯化反式-1，4-聚异戊二烯（CTPI）氯含量的影响。得到适宜的反应条件是：采用两阶段升温的方法，控制一定的通氯量，第一阶段，反应温度为35℃，反应时间为2～3h；第二阶段．反应温度为50～55℃，反应时间为1～6h，可获得氯质量分数在50％以内的CTPI，产品为可溶解的白色疏松颗粒。     

Premodification of Pt/γAl2O3 with Cinchonidine for the Enantioselective Hydrogenation of Ethyl Pyruvate: Effect of Premodification Conditions on Reaction Rate and Enantioselection

The premodification of a 5 wt% Pt/content/m51x787331t24l32/xxlarge947.gif" alt="gamma" align="MIDDLE" BORDER="0">-Al₂O₃ catalyst with cinchonidine (0.01 and 0.2 g g^-1 _catalyst) is described and discussed. Premodification is carried out by treating the catalyst with a solution of cinchonidine followed by solvent removal. Catalysts premodified in this way give the same ee and initial rate of reaction for the enantioselective hydrogenation of ethyl pyruvate as those using the standard in situ modification procedure. Investigations of different solvents for premodification and reaction (dichloromethane, ethanol) show that it is the solvent used for the reaction that controls the observed enantioselection. Premodified catalysts also display the initial transient behavior typically observed with in situ modified catalysts in which the ee increases with conversion in the early part of the reaction. Premodified catalysts show an enhanced rate of reaction when ethanol is used as the reaction solvent compared with in situ modified catalysts under the same conditions. Premodification using aerobic conditions gives the best results and premodified catalysts can be stored prior to use for up to a week without loss of catalytic performance.