NIT-Ph-p-BEN氮氧自由基的制备及催化降解性

以对醛基苯甲酸为原料，通过醛酸与2,3-二甲基-2,3-二羟胺基丁烷缩合，再经NaIO4氧化最终制得4-(4,4,5,5-四甲基-1,3-二氧化物)咪唑基-1-苯甲酸（NIT-Ph-p-BEN氮氧自由基）。采用FTIR、UV、ERP（电子顺磁共振波谱仪）和元素分析等对其结构进行表征；通过催化降解废水中有机染料甲基橙、甲基蓝和罗丹明B对其催化活性进行了评估。结果表明，当甲基橙、甲基蓝和罗丹明B浓度为15 mg/L，NIT-Ph-p-BEN质量浓度为0.15 g/L，H2O2浓度为30 mmol/L时，NIT-Ph-p-BEN对甲基橙有更好的催化降解性，仅在1 h内甲基橙的降解率达到94.26%。此外，反应机理表明，H2O2有助于实现NIT-Ph-p-BEN自由基的再生和循环利用。     

Zinc hydroxystannate and zinc stannate as flame‐retardant agents for flexible poly(vinyl chloride)

The flame‐retardant and smoke‐suppressant properties of inorganic tin compounds such as zinc hydroxystannate (ZHS) and zinc stannate (ZS) were investigated in a comparison with alumina trihydrate, magnesium hydroxide, and Sb₂O₃ through the limiting oxygen index test and smoke density test. The flame‐retardant mechanisms were studied through the char yield test, SEM, quantitative analysis, thermogravimetry and differential thermal analysis. The thermal degradation in air of flexible PVC treated with the above compounds was studied by thermal analysis from ambient temperature to 800°C. The results showed that tin compounds such as ZHS and ZS could be used as a highly effective flame retardant for flexible PVC, and it appears that the tin compound may exert its action in both the condensed and vapor phases, but mainly in condensed phases as a Lewis acid. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 1469–1475, 2005     

On the thermal stability of xanthan gum

The thermal stability of xanthan gum in dilute aqueous solutions at 90°C is considered. The relative viscosity as a function of ageing time is discussed, and it has been found to depend on the polymer concentration and conformation as well as on the salt content. The effectiveness of a quencher demonstrates the existence of a free-radical process in the degradation. During ageing, the molecular weight first decreases by rapid random hydrolysis of the main chain and loss of the pyruvate and acetate substituents. Later, oligomers are formed corresponding to a breakdown of both the side chain and the main chain. The identification of cellodextrins in the oligomer pool demonstrates the second effect.     

介质阻挡放电反应器降解邻二甲苯的特性研究

采用介质阻挡放电(DBD)降解常压下流动态的邻二甲苯模拟废气,系统地考察了放电极值电压,气体的初始质量浓度、停留时间以及相对湿度等工艺参数对邻二甲苯降解的影响,并初步探讨了邻二甲苯的降解产物.实验研究结果表明:在7.0kV的放电极间电压下,邻二甲苯的初始质量浓度为1 500mg/m3,停留时间为9s,其去除率可达到80%以上.降解产物主要为CO2、H2O以及苯甲酸、苯乙酸、苯乙醛等有机物,并且经降解后产物的生物可生化性得到提高,因而为后续的等离子-生物法联合处理VOCs提供了依据.     

2-（4-氯苯氨基）甲基苯酚降解的动力学研究

采用高效液相色谱技术,开展了Fenton试剂对2-（4-氯苯氨基）甲基苯酚（CMP）的氧化降解动力学的研究。考察了初始双氧水摩尔浓度、亚铁离子摩尔浓度和温度等因素对CMP降解速率的影响,结果表明,当双氧水摩尔浓度、亚铁离子摩尔浓度增大和温度升高时,CMP的氧化速率明显加快。在30~45℃的温度范围内,其氧化降解符合假一级反应动力学模型,反应的表观活化能Ea为102.90kJ/mol。     

Degradability and biocompatibility of bioglass/poly(amino acid) composites with different surface bioactivity as bone repair materials

Bioglass (BG) possesses excellent bioactivity and has been widely used in the manufacture of biomaterials. In this study, a composite with different surface bioactivity was fabricated via in situ melting polymerization by incorporating BG and poly(amino acid) (PAA) at a suitable ratio. The structure of the composite was characterized by Fourier transform infrared spectroscopy and XRD. The compressive strength of the BG/PAA composites was 139 MPa (BG:PAA = 30:70). The BG/PAA composites were degradable, and higher BG in composite showed higher weight loss after 4 weeks of incubation in simulated body fluid. In addition, the BG/PAA composite maintained adequate residual compressive strength during the degradation period. The SEM results showed the differences in surface bioactivities of the composites directly, and 30BG/PAA composite showed thicker apatite layer and higher Ca/p than 15BG/PAA. in vitro MG-63 cell culture experiments showed that the composite was noncytotoxic and thus allows cells to adhere, proliferate, and differentiate. This indicates that the composite has good biocompatibility. The implantations in the bone defects of rabbits for 4 and 12 weeks were studied. The composites had good biocompatibility and were capable of guiding new bone formation without causing any inflammation. The composite may be successfully used in the development of bone implants.     

Modeling Instrumental Rationality, Land Tenure and Conflict Resolution

Full instrumental rationality and perfect institutions are two cornerstoneassumptions underlying neoclassical models. However, in the real world, thesetwo assumptions never hold, especially not in developing countries. In thispaper, we develop a game theoretical model to investigate if relaxations inthe full instrumental rationality and perfect institutions premise can explainthe conflicts that have been occurring between the various principals in theNarok district in Kenya with regard to land tenure and use.     

Performance of Sewage Sludge Treatment and Electricity Generation by Different Configuration Microbial Fuel Cells

This paper compared the degradation efficiency of sludge organic matters and electric-production by two typical microbial fuel cells——dual-chamber microbial fuel cell(DMFC)and single chamber air cathode microbial fuel cell(SAMFC),and the variations of sludge protein,polysaccharide and ammonia nitrogen within the systems were also investigated.The results showed that the concentration of sludge soluble chemical oxygen demand,protein and carbohydrate of DMFC are higher than these of SAMFC during the systems operation,while DMFC can achieve a better ammonia nitrogen removal than SAMFC.Under the same operation condition,the stable voltage output of DMFC and SAMFC is 0.61 V and 0.37 V;the maximum power density of DMFC and SAMFC is 2.79 W/m3and 1.25 W/m3;TCOD removal efficiency of DMFC and SAMFC is 34.14%and 28.63%for 12 d,respectively.Meanwhile,DMFC has a higher coulomb efficiency than SAMFC,but both are less than5%.The results showed that DMFC present a better performance on sludge degradation and electric-production.