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The kinetics of l-cystine hydrochloride reduction have been studied at a mercury-plated copper rotating disc electrode (RDE) and at a stationary mercury disc electrode (SMDE) in 0.1 mol dm−3 HCl at 298 K. The reduction of the disulphide is irreversible and hydrogen evolution is the major side reaction. In contrast to steady state electrode kinetic studies at a mercury drop electrode (which shows a well-defined limiting current), the mercury-plated Cu RDE shows overlap between disulphide reduction and hydrogen evolution. These effects are attributable to strong reactant adsorption with a calculated surface coverage close to 100%. A Tafel slope of −185 mV per decade is found with a cathodic transfer coefficient of 0.32 and a formal rate constant of 6.7 × 10−9 m s−1. The relative merits of steady state voltammetry at a mercury-plated copper RDE and linear sweep voltammetry at the SMDE are discussed, as is the mechanism of l-cysteine hydrochloride formation. 相似文献
136.
以对氨基苯甲酸乙酯(苯佐卡因EPABA)为原料,经过N-烷基化、水解、酯化三步反应得到盐酸丁卡因粗品,产品收率 高达85.09%。采用FTIR、1HNMR和HPLC对产物进行了表征。对N-烷基化过程、水解条件、酯化条件进行了反应条件优化。结果表明:盐酸丁卡因被成功合成。N-烷基化的最佳工艺条件为:反应温度60℃, n(三乙胺):n(EPABA):n(1-溴丁烷)=1.2:1:4.6 ,合成对丁氨基苯甲酸乙酯(I),产品收率为75.69%;与现有工艺路线相比,在生成关键中间体对丁氨基苯甲酸乙酯(I)时成功减少了双丁基化副产物的产生;水解反应的最佳合成条件为:原料配比为n(NaOH)∶n(对丁氨基苯甲酸乙酯)=1.4:1、反应温度为50℃、反应时间为8h, 合成对丁氨基苯甲酸(Ⅱ),产品收率为99.78%;酯化反应的最佳反应条件为:原料配比为n〔(β-氯乙基)二甲胺盐酸盐〕: n(对丁氨基苯甲酸) =1.3:1、反应温度为116℃、溶剂为甲基异丁基甲酮,合成盐酸丁卡因,产品收率为85.09%。 相似文献
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Specific Ion Effects of Salt Solutions on Colloidal Properties of Octadecylamine Hydrochloride
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Flotation continues to be a major technique for the production of potash from low grade, complex systems containing a variety of ores and ions. The specific ion effects on the behavior of the flotation collector in the KCl flotation system becomes important to the interpretation of the flotation mechanism. In this work, specific ion effects on the turbidity, surface tension and aggregation behavior of the common collector in KCl flotation, octadecylamine hydrochloride (ODA), have been investigated. The results from turbidity and surface tension studies of ODA solutions show that both cations and anions can affect the colloidal properties of ODA. Molecular dynamics simulations show that the binding that energy barrier between ODA headgroups and anions is principally responsible for the specific anion effect of γ CAC of ODA solutions. In addition, the ion effect on the ODA aggregation particle size was also studied by using transmission electron micrographs (TEM) and dynamic light scattering. The data reveal that the presence of salt ions can induce the formation of larger ODA colloidal particles, on which the cation effect is more significant. This work provides detailed information of specific ion effect on colloidal properties of ODA, which may promote a further understanding of the flotation mechanism and help to improve the flotation of KCl from brine sources. 相似文献
139.
建立了离子色谱-柱后衍生测定灭多威中痕量盐酸羟胺的新方法。样品经净化后,采用Ion Pac CS16离子交换色谱柱、安培检测器检测,外标法定量。结果表明:盐酸羟胺在0.02~1.0 mg/L质量浓度范围内,线性关系良好,线性相关系数为0.999 8。方法回收率为95.3%~98.1%,相对标准偏差均小于3%。检出限(信噪比3)为2.5μg/L。该方法简便,灵敏度高,无杂质干扰,前处理简便,可用于灭多威中痕量盐酸羟胺的测定。 相似文献
140.
The equilibrium solubility of three pharmaceutical salts, namely, sodium naproxen (Na.NAP), procaine hydrochloride (PC.HCl), and lysine clonixinate (Lys.Clon), was determined in propylene glycol (PG) + water mixtures at 298.15 K. If the mole fraction concentration scale is considered, the mixtures’ composition-dependence on solubility was different for these drugs. Thus, the solubility of Na.NAP increased nonlinearly from pure water to pure PG. By contrast, the solubility of PC.HCl decreased nonlinearly from pure water to pure PG. In a different way, the solubility of Lys.Clon increased from pure water to the mixture with mass fraction of PG, w1 = 0.80, and later, it decreased to reach a lower value in pure PG. A good correlation of the solubility data was obtained by using the modified NIBS/R-K model. Otherwise, the apparent specific volumes at saturation of these drugs were also calculated in all the mixtures under study. 相似文献