Influence of two-step process and of different stoichiometric ratios on morphologies generated in castor oil epoxy resins

Phase separation during polymerization was studied in a model system consisting of a diepoxide based on diglycidyl ether of bisphenol A (DGEBA), variable amounts of ethylenediamine (EDA) and the mass of castor oil (CO) necessary to obtain a mass fraction equal to 0-15 in a final system where the stoichiometric ratio of amine to epoxy equivalents, r, was equal to 1. A two-step polymerization process was performed by curing first a system with r = 0-5, during variable times before phase separation, and then carrying the system to r = 1. Thermodynamic analysis of samples with different r values led to a linear relationship between the Flory-Huggins interaction parameter and r. The concentration (P) and average size (D?) of dispersed-phase particles followed opposite trends, i.e. P increased while D? decreased, when either r was increased or the time of curing in the first step of a two-step process was decreased. This was explained by assuming that the competition between nucleation and growth was determined by the viscosity at the cloud point, η_cp. Low values of η_cp favoured growth over nucleation and led to fewer but larger particles.     

无间隙原子钢的微观结构特征和塑性应变比

采用Ｘ射线衍射的ＯＤＦ和ＬＰ分析技术，ＳＥＭ电子通道花样和蚀坑技术观测，研究了超深冲无间隙原子钢板的微观结构特征。结果表明：控制化学成分、保证基体纯净、优选工艺参数，促进强的γ－〈１１１〉∥Ｎ．Ｄ纤维织构的形成是获得优异成型性的关键。用ＣＭＴＰ方法，由ＯＤＦ织构数据从理论计算了塑性应变比（ｒ），表明ｒｍ值高达３．１８。文中讨论了再结晶织构形成机制。     

90°分束偏光镜光强分束比研究

给出了90°分束偏光镜的e,o光光强分束比的计算公式,以及光强分束比随光波长的变化曲线;在6328Å测得的光强分束比与计算值是一致的。     

In-chain functionalization by alternating anionic copolymerization of styrene and 1-(4-dimethylaminophenyl)-1-phenylethylene

Anionic copolymerizations of styrene (M₁) with excess 1-(4-dimethyl-aminophenyl)-1-phenylethylene (M₂) were conducted in benzene at 25°C for 24h, using sec-butyllithium as initiator. Narrow molecular weight distribution copolymers with M?;_n = 16.1 × 10³ g/mol (M?_w/M?_n = 1.04) and 38.2 × 10³g/mol (M?_w/M?_n = 1.05), and 24 and 38 moles of M₂ per macromolecule, respectively, were characterized by size exclusion chromatography, ¹H NMR spectroscopy and DSC. The monomer reactivity ratio, r₁ = 5.6, was obtained from the copolymer composition at complete consumption of M₁, assuming that the rate constant k₂₂ =0,i.e. r₂ =0. The polymers exhibited T_g values of 128 and 119°C, respectively, which correspond to an estimated T_g = 217°C for the hypothetical homopolymer of M₂.     

SDH中泊松分布下误块率与误码率的关系分析

本文较详细地介绍了ＳＤＨ中的ＢＩＰ误码校验方式，推导了泊松分布下，ＢＩＰ误块率与误码率的一般关系式，给出了ＳＤＨ中几种典型的误块率与误码率的关系曲线，并做了计算机模拟验证     

氢/空气火焰在半开口有障碍管道中的传播特性

针对氢／空气混合物，通过实验研究了其预混火焰在半开口管道中的火焰传播加速现象。结果表明，火焰传播状态随着氢气当量比的变化而发生改变。当氢／空气混合物被点燃后，由于障碍物的扰动，火焰在管道中不断加速传播，并最终到达一准稳态传播。在氢气当量比0．34附近时，火焰速度发生跃变。当氢气当量比足够大时，火焰传播由爆燃态转变为爆轰态。在本实验条件下，爆燃转准爆轰的临界条件是d/λ=2.6(d是圆环形障碍物内径，λ是爆轰格胞尺度）。障碍物阻塞比的变化对最大火焰速度和压力提升的影响不明显。     

鱼雷罐喷粉预处理优化研究

在已经得到的描述鱼雷罐喷粉处理基本参数具体表达式的基础上，运用多目标非线性优化方法，对工艺操作参数进行优化。     

OFDM技术及其应用

首先对OFDM的发展以及应用做了简要的介绍,然后讨论了当前OFDM研究过程中的两个关键技术问题,最后展望了OFDM的未来发展。     

Application of Wavelet Packet De-noising in Time-Frequency Analysis of the Local Wave Method

The local wave method is a very good time-frequency method for nonstationary vibration signal analysis. But the interfering noise has a big influence on the accuracy of time-frequency analysis. The wavelet packet de-noising method can eliminate the interference of noise and improve the signal-noise-ratio. This paper uses the local wave method to decompose the de-noising signal and perform a time-frequency analysis. We can get better characteristics. Finally, an example of waveletpacket denoising and a local wave time-frequency spectrum application of diesel engine surface vibration signal is put forward.     

塔里木盆地塔中沙漠区高分辨率地震勘探效果

塔中沙漠区地表被北东—南西向条带状沙层所覆盖,地形起伏剧烈,松散沙层厚度变化巨大,给地震资料采集、处理、解释带来了很大的困难。通过联合攻关,从地震波激发能量下传和反射波接收的研究入手,实现了全部潜水面以下激发,因地制宜、避高就低埋置检波器优化观测系统;针对该区石炭系和志留系低幅度构造、薄储层圈闭难以落实,奥陶系内幕地震资料反射波能量弱、信噪比低、叠加成像困难等问题,开展了沙丘对地震波吸收衰减分析和补偿技术、地表一致性处理技术、多域迭代静校正技术、精细速度场模型确立和偏移成像等配套技术的研究开发与应用。从而极大地改善了塔中沙漠区地震资料的品质,使中深层的石炭系、志留系、奥陶系对应的地震剖面主频从18～20Hz提高到36～40Hz;形成了塔中沙漠区油气勘探技术系列,精细刻画了塔中Ⅰ号带,锁定了油气勘探目标,推动了台盆区油气勘探再掀新高潮。