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31.
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33.
David P. Cormode Jason J. Davis Paul D. Beer 《Journal of Inorganic and Organometallic Polymers and Materials》2008,18(1):32-40
Disulfide and dithiocarbamate functionalized porphyrins have been synthesized and used as protecting ligands for gold nanoparticle
formation either via ligand substitution reactions or by direct synthesis. These nanoparticles have been shown to recognize
anions via changes in the absorbance spectrum of the surface adsorbed porphyrin moieties. Association constants, derived from
quantitative titrations, indicate a remarkable surface enhancement effect where the surface bound porphyrins bind anions much
more strongly than the free receptor in solution. 相似文献
34.
Flammability ranking of foliage species by factor analysis of physical and chemical pyric properties
In this paper, factor analysis is introduced to evaluate the flammability of 55 foliage species that may be used in China for construction of the fuel break network of forest strips with lower flammability. Six pyric parameters, i.e. air dry moisture content, absolute dry moisture content, ignition point, ash content, caloric value and extractive content, are measured and used as variables for factor analysis. The covariance analysis shows that four principal factors can be extracted to reflect the flammability in different physical and chemical senses. In terms of the contributions of the four factors to the variances and the physical significance of the relevant parameters, the four factors are, respectively, termed as ‘flaming factor,’ ‘air dry factor,’ ‘ash factor’ and ‘absolute dry factor.’ The stability of the factor analysis method is examined by a different number of samples considered, and the variation degrees of the orderings indicate that the method has high reliability to measure the total flammability of foliage species. The results of the flammability evaluation are verified by comparison with the recommended tree species in the Chinese technology standard. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
35.
J.H Xiang 《Corrosion Science》2004,46(8):2025-2039
The oxidation of the ternary alloys Ni-45Cu-10Al and Ni-30Cu-10Al has been studied at 800-900 °C under 1 atm O2. The presence of 10 at.% Al reduces significantly the oxidation rate of the corresponding Cu-Ni alloys during the initial oxidation stages, even before the establishment of a complete Al2O3 layer. The weight of individual sample of the two ternary Ni-Cu-10Al alloys at 800 °C increases more rapidly than at 900 °C during the initial oxidation stage. As oxidation proceeds, the weight gain at 800 °C slows down to a degree that the total weight gain after 24 h oxidation at 800 °C is less than that at 900 °C. Due to a faster formation of the Al2O3 layer, which suppresses earlier the further oxidation of Cu and Ni, the external region of the scales grown on Ni-45Cu-10Al contain much less Cu and Ni oxides than those grown on Ni-30Cu-10Al. The transition from the internal oxidation to the selective external oxidation of the most reactive component Al in Ni-Cu-Al alloys is favored by higher values of the Al content, of temperature and of the Cu/Ni ratio. 相似文献
36.
The numerical simulation of comparative elastohydrodynamic lubrication between axisymmetrical and 3D elastic approaches on the radial lip seals is presented in order to determine the 3D effect of the elastic aspect of the seal lip. Indeed, the consideration of 3D model in other words the circumferential variation of the lip elastic deformation indicated a difference in the deformation distribution of the lip compared to the axisymmetrical approach. Consequently, the results show that the presence of the circumferential variation of the seal lip deformation has a significant effect on the pumping rate values. 相似文献
37.
沈国金 《武汉理工大学学报(信息与管理工程版)》2006,28(8):139-142
针对目前大学生职业规划效果不佳的现状,分析了导致大学生职业规划效果不佳的原因,提出了增强大学生职业规划效果的宏观对策。 相似文献
38.
A statistical study of the particle shape and size of pure V2O5 and TiO2, and samples of coprecipitated V2O5---TiO2 catalysts with different V/Ti ratios, has been performed. They were also characterized by XRD, EDAX, SEM and XPS. The results showed that pure vanadium pentoxide is compose by large square or needle-shaped particles, while pure titanium dioxide has small and rounded ones. VTiO samples presented an area and shape, depending on the V/Ti ratio.
These results and the spectroscopical characterization conducted to a particle model of the catalysts. Those VOTi samples with high V/Ti ratio would have large V2O5 crystals acting as support of a V/TiO2 solid solution. In contrast, those samples with a low V/Ti ratio, would have the solid solution supporting vanadium pentoxide crystals. 相似文献
39.
An analytical method is presented for calculating the resonant frequency andQ-factor of a superconducting dielectric disk resonator operating in millimeter-wave regime with whispering-gallery mode. Resonant frequency shift due to the optical generation of quasi-particles in superconducting film is investigated as a function of photon flux. An optically tunable resonant frequency of about 500 MHz is estimated, and good agreement is found between numerical results and experimental ones. 相似文献
40.
《Drying Technology》2007,25(3):475-481
A method to minimize twist has been investigated; i.e., drying the boards in a pre-twisted position. It has been found that Norway spruce boards can be deformed toward straightness by this method. The force exerted by a board on its holders during drying in a pre-twisted position has been measured. When the variation in torsional stiffness as a function of temperature and moisture content is accounted for, it is found that a creep deformation of the board occurs both during the drying phase and the cooling phase. In addition to mechano-sorptive creep, a deformation released by a change in temperature also seems to occur. 相似文献