基于模拟分析技术和随机搜索算法的化工过程能量集成方法研究

夹点和模拟分析技术已在化工能量集成中广泛应用.今以夹点技术为基础,对化工过程系统用能进行诊断,根据"过程用能一致性"原则提出能量集成改造方案,通过改变塔压实现塔顶冷凝器与塔底再沸器的热集成多效蒸馏.夹点技术实现的优化目标仅是热回收最大或公用工程能耗最小,不能实现包括设备整体费用最小的过程全局最优化.研究基于模拟技术,通过灵敏度分析,得到精馏塔各操作参数的样本映射数据,通过多项式拟合得到参数关联方程,并在遗传算法及模式搜索中设计过程费用函数,提出了将模拟分析技术与随机搜索算法相结合的,以过程费用函数最小化为优化目标的能量集成方法.工业实例的成功设计应用证明了其有效性和可行性.     

Synergic effect of Pd/γ-alumina and Cu/ZSM-5 on the performance of NO x storage reduction catalyst

NO _x reduction with a combination of catalysts, Pd catalyst, NO _x storage reduction (NSR) catalyst and Cu/ZSM-5 in turn, was investigated to elucidate for the high NO _x reduction activity of this catalyst combination under oxidative atmosphere with periodic deep rich operation. The catalytic activity was evaluated using the simulated exhaust gases with periodically fluctuation between oxidative and reductive atmospheres, and it was found that the NO _x reduction activity with this catalyst combination was apparently higher than that of the solely accumulation of these individual activities, which was caused by the additional synergic effect by this combination. The Pd catalyst upstream of the NSR catalyst improved NO _x storage ability by NO₂ formation under oxidative atmosphere. The stored NO _x was reduced to NH₃ on the NSR catalyst, and the generated NH₃ was adsorbed on Cu/ZSM-5 downstream of the NSR catalyst under the reductive atmosphere, and subsequently reacted with NO _x on the Cu/ZSM-5 under the oxidative atmosphere.     

风机及泵用差动调速装置的节能效果分析

差动调速装置是一种适用于大中型风机及泵类的高效节能传动装置,它能有效调节风机及泵的流量或使其运行于高效工作区。该装置具有调速方便、效率高、节能效果显著、造价低、可靠性高等一系列优点。     

规模储氢技术及其研究进展

介绍了几种常用的储氢技术如高压压缩储氢技术、吸氢物质强化压缩储氢技术、液化储氢技术和金属氢化物储氢技术的研究进展,并对规模储氢技术的发展前景进行了预测和展望,指出规模储氢技术目前急待解决的问题是提高储氢密度、储氢安全性和降低储氢成本。     

高分子聚合物约束阻尼复合结构的计算

摘 要 论述了高分子聚合物约束阻尼复合结构损耗因子的有限元计算方法，并详细研究了模态应变能法的理论分析及其在ANSYS软件上计算约束阻尼复合结构损耗因子的计算程序。     

读写频繁云存储网络应用的数据备份方法

文章根据读写频繁的云存储网络应用的数据存储特点,提出了一种新的数据备份方法,旨在最优化地利用已有的系统资源,为用户提供更好的用户体验。文章中的数据备份方法包括基于数据节点废弃度计算与用户访问预测的副本创建机制和基于存储平衡预测算法与副本健康度计算的负载调整机制。文章的数据备份方法与现有技术相比针对日益流行的社交类云存储网络应用进行了优化,将多种数据参数加权计算作为衡量数据节点优劣和副本文件价值的标准,在保证用户使用体验的前提下使各数据节点达到负载的均衡,并且避免了云服务器端将有限的计算资源浪费在频繁的副本调整过程中。     

纺丝侧吹风空调系统的节能措施分析

分析了纺丝侧吹风空调机组及送回风系统设计及其自动控制系统配置的节能措施。合理选择送风余压、送风量、送风温度、送风相对湿度等工艺参数以及空调机组的形式,正确利用回风和自动控制方式,加强生产运行管理,有利于节能。     

Study of mass transfer in a vertically moving particle bed electrode

A study was made of the influence of process parameters on the mass-transfer coefficient in a flow-through cell with a cascade of rotating drums partially filled with conductive particles (called the vertically moving particle bed). Copper deposition from an acidic sodium sulphate solution was used as the model reaction. To evaluate the experimental data a macrohomogeneous mathematical model of potential and current density distribution inside the cell was developed. The electrolyte flow distribution between the empty space above the particle bed and through the bed was evaluated. On the basis of these results the following correlation is proposed:

型腔体组件装配尺寸检测技术分析与运用

为解决型腔体组件装配尺寸的检测问题,以某枪型的型腔体组件为例,分析该型腔体组件的结构特点,设计组合型检测装置,实现准确检测目的.归纳总结了型腔体组件装配尺寸检测技术运用过程中检测装置的设计要领,采用设计与被测型腔体组件相匹配的组合型检测装置,有效解决了型腔体组件装配尺寸检测过程中的定位困难、操作繁琐、检测准确性差等问题.该检测技术对确保型腔体组件装配尺寸的检测稳定性、检测可操作性、检测准确性等方面具有现实的指导意义.     

Kinetic study of radical polymerization. II. Solid‐state bulk polymerization of sodium methacrylate by differential scanning calorimetry

The solid‐state radical polymerization of sodium methacrylate was investigated. It was initiated by azobisisobutyronitrile, which was used as a radical initiator. Differential scanning calorimetry (DSC) was used to observe the endothermic and exothermic transitions during the polymerization reaction. Structural studies were performed with the DSC thermograms and Fourier transform infrared and ultraviolet–visible spectra, and all of the results confirmed the progress of the reaction. The obtained data revealed that the polymerization reaction proceeded completely with a 100% conversion. ΔH of this reaction was calculated with various amounts of the initiator, and the peak temperatures were determined at different heating rates. The activation energy (19.7 kcal mol^?1) was also obtained by the Kissinger method for this type of solid polymerization reaction. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 1648–1654, 2003