中温相变蓄热材料研究进展

对中温相变蓄热材料(PCM)的定义范畴、应用领域、国内外发展现状进行了评述。中温PCM主要针对90~550℃的热动力环境,在太阳能热发电、有机朗肯循环、移动蓄热技术、分布式能源系统等方面有广阔的应用前景。指出进一步的研究方向是拓展中温PCM的应用场合,规范长期稳定性的表征与测试手段,重视与换热器开发以及应用领域的整合,并提出硝酸盐熔融盐混和物将是今后一段时期内中温PCM研发和培育的重点产品对象。     

低氟含量低表面能自清洁氟碳涂料的研究

以氟单体和丙烯酸酯类单体通过聚合物的分子结构设计，合成了一类总氟含量不超过12％的低氟含量的含氟丙烯酸树脂，所制备的氟碳涂料的涂层的表面能低，具有自清洁功能。分析了该涂层中极性与非极性官能团的分子取向机理，测定了纯水水珠在不同含氟单体均聚物和共聚物清漆漆膜上以及在含氟丙烯酸树脂涂层上的接触角，探明了含氟丙烯酸树脂涂层的总氟含量与表面能的关系、含氟官能团在涂层中的分布，探讨了低氟含量的含氟丙烯酸树脂涂料的涂层自清洁机理。     

硫酸工艺和设备选择中的节能问题

介绍了硫酸生产中能量利用及我国硫酸工业能源利用状况。分析了硫酸工艺和设备选择中的节能降耗问题,做好投资费用与能耗的技术经济评估及塔设备、干吸塔除雾器、主鼓风机等主要耗能设备的设计与选型,合理地选择工艺、设备及其参数,提高能量利用率,实现投资最小化和节能最大化,构筑“节能型”硫酸工业。     

碳纳米管(CNT)及其储氢特性研究进展

综述了碳纳米管的不同制备和提纯方法，重点对碳纳米管在储氢实验方面的研究进行了介绍。并提出了今后碳纳米管储氢研究的方向。     

Study on the synthesis of thiirane

In this study, a thiirane resin was synthesized by the reaction of corresponding epoxy resin with KSCN. The synthetic conditions influencing the conversion of epoxy group were systematically investigated, such as the reaction temperature, reaction media, reaction time and the ratio of KSCN to epoxy group. It was found that the conversion of epoxy group increased with the increasing reaction temperature, improving the solubility of the mediate, extending reaction time, and the enhancing ratio of salt (KSCN) to epoxy group. Wherein, the reaction temperature and the ratio of the KSCN to epoxy group were more effective. For example, when the molar ratio of KSCN to epoxy group was equal to 2.0, the conversion of epoxy group got the maximum value, 0.65. In addition, the hot plate method was used to measure the gelling time of the resultant thiirane resin at different temperatures. It was found that the gelling time was reduced to 47–85% times as the corresponding epoxy resin depending on the conversion of the epoxy group, and the curing activation energy was diminished from 39 kJ/mol of epoxy resin to 17 kJ/mol. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 4023–4027, 2006     

Effect of hydrophobic hexafluoroisopropylidene group on the water sorption behaviors of rigid poly(p‐phenylene pyromellitimide) polyimide thin films

We prepared poly(p‐phenylene pyromellitimide) (PMDA–PDA), poly(p‐phenylene 4,4′‐hexafluoroisopropylidene diphthalimide), and their copolyimides with various compositions to explore the relationship between the water sorption and structure. The water sorption behaviors were gravimetrically investigated as a function of composition and temperature and interpreted with a Fickian diffusion model in films. Overall, the water sorption behaviors were strongly dependent on the changes in morphological structure, which originated from the variations in composition. When the content of the bulky hexafluoroisopropylidene group (6FDA) was increased, the water uptake decreased from 5.80 to 3.18 wt %, whereas the diffusion coefficient increased from 3.6 × 10^?10 to 11.3 × 10^?10 cm²/s. The relatively high water uptake in the PMDA–PDA polyimide film was successfully healed by the incorporation of 6FDA, which may have resulted from the increases in the intermolecular packing order and hydrophobicity. The degree of orientation and crystallinity, which are in‐plane characteristics, were directly correlated to the diffusion coefficient and activation energy in the polyimide film. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 3442–3446, 2003     

Failure load prediction of structural adhesive joints : Part 2: Experimental study

The objective of this study was to determine how the fracture of adhesive joints depends on elastic beam parameters describing the adherends and the applied loads. The basic specimen geometry was the cracked lap shear joint constructed of aluminium alloy with various adherend and bondline thicknesses. Loads were applied in different combinations of bending, tension and shear to generate a failure envelope for each adhesive and specimen geometry. It was found that crack propagation for precracked specimens occured at a critical strain energy release rate but was also a function of the G_I/G_II ratio and the bondline thickness. The experiments also showed that the loads required to propagate a crack in a precracked specimen were always lower than the loads required to break the fillet. Hence, by treating uncracked joints as being cracked, where the fictitious crack tip is assumed to coincide with the location of the fillet, a conservative estimate of the failure load is obtained.     

基于EMD和互信息熵的微震信号自适应去噪

针对强干扰背景下的微震信号提取,提出一种基于经验模态分解（Empirical Mode Decomposition,EMD）和互信息熵的自适应提取算法。通过EMD对微震信号进行分解,得到高频和低频两部分信号,并对分解得到的各阶固有模态分量求出能量和能量熵值。根据互信息准则,通过依次计算相邻分量能量熵之间的互信息值来区分高频和低频信号。将经过自适应阈值滤波后的高频信号和低频信号一起进行信号重构,得到新的微震信号。仿真结果表明,在对微震信号去噪时,该方法可以有效地去除噪声信号,信噪比均提升了10 dB以上。工程上的微震信号通过该方法处理后,也取得了较好的效果。     

一种能量高效的无线传感器网络拓扑控制算法

通过对现有拓扑控制算法的研究,针对无线传感器网络中节点能耗分布不均匀的问题,提出了一种能量高效的拓扑控制算法(EETCA)。该算法以均衡全局能耗为目标,综合考虑了节点的剩余能量、簇的规模、数据最优传输跳数等因素,避免了部分节点能量消耗过快,从而有效地均衡网络负载。仿真结果表明:EETCA在能耗均衡方面均优于原来的算法,延长了无线传感器网络的生命周期。     

人体局部代谢率监测系统设计

在实现将温度、湿度及辐射传感器集成于独立检测探头基础上,设计了一种人体局部代谢率监测系统。系统通过采集人体指端生理参数,根据人体能量代谢守恒法,建立数学模型并计算静息代谢率。经过实验验证:该系统可以实现代谢率的方便测量,测试结果能够反映人体正常的代谢情况。由于系统设计简便、成本低,可被广泛用于人体的能量代谢率检测。