Preparation and Properties of Sintering Additives Coated Si3N4 from Heterogeneous Nucleation Processing

The sintering additives such as Al2O3 and /or Y2O3 were coated on the surfaces of Si3N4 particles via heterogeneous nucleation processing using a buffered pH solution as the precipitation reagent .They nucleated and grew only on the surfaces of Si3N4 and did not form sol particles in solution by TEM observation .The isoelectric point(IEP) of coated Si3N4 was different from that of as-received Si3N4.The IEP of Al(OH)3-coated Si3N4 occurred at pH8.4, which is close to that of alumina .When Al(OH)3-coated Si3N4 particles were coated with Y(OH)3,the IEP of coated Si3N4 powder shifted from pH8.4 to pH9.2 ,similar to that of yttria.In addition ,the rheological data showed that Al2O3 and /or Y2O3 coated Si3N4 suspension is nearly Newtonian and that added Si3N4 suspension shows a shear rate thinning behavior.     

电磁胀形磁场力的有限元分析

研究电磁胀形过程中工件受到的磁压力沿长度方向和厚度方向的分布是工件变形分析的基础。采用有限元方法对电磁胀形过程中作用工件上的磁场力进行了数值模拟。在磁场特性理论分析的基础上确立了模型的边界条件，得到了磁场力沿工件长度和厚度方向的分布规律。模拟结果与测量值基本吻和。     

硫化胶交联结构及其性能

综合讨论了聚合物／聚合物之间的交联结构及聚合物／填料之间的偶联结构对硫化胶抗硫化返牟性，抗氧老化性及动态疲劳性能的影响。     

Effects of a Nd—Fe—B magnetic filler on the crystallization of poly(phenylene sulfide)

The crystallization of poly(phenylene sulfide) (PPS) in a polymer–magnetic Nd—Fe—B powder suspension was studied. Isothermal crystallization behavior was analyzed by way of differential scanning calorimetry, and the kinetics were described via the Avrami equation. The Avrami parameters and the crystallization times were strongly affected by both the particle size and the presence of a coupling agent coated on the filler particles. The small Nd—Fe—B particles exhibited long induction and half‐times, whereas the large particles tended to have short crystallization times. Particles ranging from 38 to 150 μ appeared to have similar crystallization times and to have no significant change in the value of Avrami index with melt crystallization temperature. As a result of these analyses, the dynamic mechanical properties were determined to correlate the fundamental polymer crystallization characteristics and the physical properties of the PPS binder. The enhancement of the wetting of the filler to the binder was promoted through the coupling agent, as confirmed by dynamic mechanical testing performed on the samples. The storage modulus typically decreased because of the presence of the uncoated small particles. Conversely, the loss modulus was enhanced because of the presence of the coated small particles in the PPS binder. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 1091–1102, 2002     

用于高压电容器的SrTiO3基陶瓷

报道ＳｒＴｉＯ３基陶瓷的制备方法和介电性质，给出了用此种陶瓷制成的高压电容器的试验结果，并对它位进行了讨论。     

LaCrMnNiO系热敏陶瓷的微观结构控制

通过对不同配方、工艺下的ＬａＣｒＭｎＮｉＯ系热敏陶瓷的微观结构研究，指出材料的相组成对其宏观电性能的影响，并提出了通过复合工艺利用“过渡相”的形成，对材料的“最终相”加以控制的方法。文中列出了使用ＸＲＤ及ＸＰＳ手段对材料微观结构的分析结果及有关电性能的测试数据。     

Li2O在保护渣中的作用

采用在不同玻璃性的两种基渣中加入Ｌｉ２Ｏ为研究Ｌｉ２Ｏ对保护渣粘度，熔化温度及玻璃性能的影响，并对Ｌｉ２Ｏ改善保护渣玻璃性的机理进行了探讨，提出了寻找高速连铸保护渣中Ｌｉ２Ｏ的代用物的一种方法。     

压电复合材料PT－P（VDF／TeFE）的静水压压电性

用热轧辊机制备了压电复合材料ＰＴ－Ｐ（ＶＤＦ／ＴｅＦＥ），并利用ＬＣＲ电桥和Ｂｅｒｌｉｎｃｏｕｒｔ电路分别测量了其介电常数和压电常数，实验结果表明它具有良好的静水压压电特性。最后讨论了该复合材料在水听器中的应用     

ZnO陶瓷材料的负阻特性

介绍了ＺｎＯ陶瓷的负阻特性，主要研究了ＭｎＯ２掺杂和Ｎｉ２Ｏ３掺杂对ＺｎＯ陶瓷负阻特性的影响。     

丙烯酸酯单体对聚氯乙烯密封胶粘剂的改性作用

丙烯酸酯有较大的反应活性，能与聚氯乙烯发生接技共聚反应。本文中，我们着重研究不同结构丙烯酸酯单体对聚乙烯基密封胶粘剂的改性作用。以PVC为100份，分别加入甲基丙烯酸一缩二乙二醇双脂（DEGDMA），甲基丙烯酸乙二醇双酯（EGDMA）和丙烯酸一缩二乙二醇双酯（DEGDA）各为10份、20份、30份的试验结果看出，随着丙烯酸酯单体添加量的增加，PVC片基的硬度增大，拉伸强度提高，而伸长率降低。不同的单体其影响也不同。就硬度和拉伸强度有EGDMA＞DEGDA＞DEGDMA的规律伸长率的降低则为DEGDMA＞DEGDA＞EGDMA。就丙烯酸…