Neutral poly(3,4-ethylenedioxythiophene-2,5-diyl)s: preparation by organometallic polycondensation and their unique p-doping behavior

Neutral and non-doped poly(3,4-ethylenedioxythiophene), PEDOTh(Ni), and its hexyl derivative, PEDOTh-C₆(Ni), have been prepared by organometallic dehalogenation polycondensation of 2,5-dichloro-3,4-ethylenedioxythiophene and its hexyl derivative with a zerovalent nickel complex. PEDOTh-C₆(Ni) was soluble in organic solvents and ¹H NMR data indicated that it had an M_n of 11,000. MALDI-TOF mass analysis of PEDOTh(Ni) gave M_n and M_w of about 1700 and 2400, respectively. PEDOTh-C₆(Ni) showed a UV-Vis absorption peak at 546 nm in CHCl₃. Electrochemical oxidation of PEDOTh-C₆(Ni) started at about −0.40 V vs Ag⁺/Ag and gave a peak at 0.20 V vs Ag⁺/Ag. Chemical and electrochemical oxidation (or p-doping) of PEDOTh-C₆(Ni), both in solutions and in a solid state, led to weakening of the original π-π^∗ peaks and rise of new peak(s) in a region of 800-1500 nm. The p-doping of PEDOTh-C₆(Ni) caused not only a decrease in the intensity of ¹H NMR signals of the bridging ethylene hydrogens but also a decrease in that of the hexyl side chain, suggesting a strong interaction of the p-dopant with the side chain. NMR data of poly(3-methoxythiophene-2,5-diyl) also supported an assumption that p-doping brings about a severe change in electronic state of the substituent attached to the polythiophene main chain. PEDOTh(Ni) had a density of 1.71 g cm⁻³; the molecular packing mode of PEDOTh(Ni) is discussed based on the density of the polymer and its XRD data.     

地域通信网的干扰技术研究

本文在分析地域通信网结构及组成的基础上,研究了对地域通信网实施的节点破坏、末端信息封锁、局部阻塞瘫痪等对抗方法,并使用干扰地域通信网的程度、节点干扰率、末端节点封锁率和传递信息误差率等指标对干扰效果进行评估。     

几种航空有源电子干扰装备的比较

本文对远距离支援干扰飞机、随队支援干扰飞机、机载自卫电子对抗系统以及最近国外正在大力发展的分布式电子干扰系统等几种航空有源电子干扰装备的作战对象、战术应用、功能、使用局限性等特点进行了比较 ,探讨了综合发展和运用这几型装备的重要意义     

加快纺织企业信息化建设 提升企业竞争力

纺织行业作为传统产业 ,信息滞后 ,反映迟缓 ,已不能适应日益激烈的市场竞争环境。信息技术的应用涉及企业的各项经济活动 ,可以直接影响企业价值链的任何一环的成本 ,信息化成为改造纺织企业 ,提高企业的综合竞争能力的主要手段     

DZX-2B型电子学综合实验装置常见故障与分析

介绍DZX-2B综合实验装置的组成、常见故障，及如何快速、准确的判断并排除故障的方法。     

虚拟仪器在教学中的应用

主要介绍了Multisim2001中虚拟仪器库中函数发生器、示波器的使用方法及功能；并在Multisim2001环境中仿真单管放大电路、桥式整流滤波电路。由调试结果，分析了其在教学中应用的可行性。     

Modified CIELAB formula tested using a textile pass/fail data set

The proposed new color-difference formula of CIE TC 129, which is a modified version of CIELAB, was tested with a recently published data set of textile pass/fail judgments. Goodness of fit is improved, if the parameter of lightness is set near 2, and if, additionally, a weight function for lightness is defined that reduces the weight of a lightness difference with lightness level in relation to chroma or hue scaling. © 1994 John Wiley & Sons, Inc.     

PE/PP共混物卷绕丝微观结构的研究

用透射和扫描电子显微镜研究PP/PE共混物在熔融纺丝时 ,PE掺入对PP结构的影响。研究结果表明 :PE与PP存在一定程度的相互作用 ,PP中加入PE能改变卷绕丝中PP结晶结构 ;PP中加入质量分数低于 10 %的PE时可以顺利纺丝 ,所得的卷绕丝断裂伸长率较大 ,具有良好的可拉伸性     

用扫描电镜研究硅酸盐、硼酸盐和磷酸盐玻璃的表面

本文采用扫描电镜及能谱仪分别研究了硅酸盐、硼酸盐和磷酸盐玻璃的风化、离子注入和离子交换，观察了表面形貌、离子交换的深度分布及离子注入对表面析晶的影响。     

纺织机械零件CAPP技术的应用研究

要提高产品的竞争能力，必须在企业中加大CAPP的应用力度，笔者通过应用思普CAPP系统（SIPM/CAPP）编制纺织机械零件工艺文件的实践，证明了在企业中应用CAPP是提高产品的市场竞争能力，提高企业工艺快速反应能力的有力工具。