Synergy of Pickering Emulsion and Sol‐Gel Process for the Construction of an Efficient,Recyclable Enzyme Cascade System

An efficient, easily recyclable enzyme cascade system based on nanoparticle‐stabilized capsules (NPSCs) is constructed through a synergy of a Pickering emulsion and sol‐gel process. Specifically, oligodopa‐coated titania nanoparticles (biomimetic titania) containing the first enzyme (FateDH) are synthesized through a bioadhesion‐assisted biomimetic mineralization approach. The biomimetic titania is then spontaneously assembled at the interface between the oil phase (hexadecane/butyl titanate (BuTi) mixture) and water phase during the formation of Pickering emulsions. The sol‐gel process of BuTi can produce not only butanol for assisting the formation of Pickering emulsions but also titania gel particles (sol‐gel titania) for cross‐linking the biomimetic titania through catechol‐titanium chelating. The NPSCs obtained, which contain the first enzyme, conjugate the second enzyme (FaldDH) onto the surface for constructing the enzyme cascade system. The system exhibits high activity and stability, particularly, superior recyclability for conversion of CO₂ into formaldehyde. In detail, the system shows a formaldehyde yield of 50.0%, and can quickly float onto the air/water interface soon after stopping the agitation of reaction mixtures, which ensures that the formaldehyde yield keeps almost unaltered after 10 times recycling. This study will be useful for facile construction of a wealth of catalytic systems with efficient, recyclable attributes.     

功率型白光LED平面涂层技术研究

基于水溶性感光胶的白光LED表面涂层技术,阐述了含有荧光粉感光胶悬浮液的配比和封装结构对白光LED出光效率的影响,提出了相应的改进措施,通过实验证实提高了白光LED器件的整体性能.同时,对利用该法得到的功率型白光LED进行了光衰减测试,LED在700mA电流下点亮168 h后,光输出为初始光输出的95.95%,满足实用要求.     

乳化炸药油水相流量控制

以乳化炸药生产线油、水相流量控制系统为研究对象,分析油、水相流量添加过程的滞后性,针对传统PID控制理论的不足,详细分析了自校正PID理论,采用自校正PID控制策略来实现流量的实时控制。现场运行情况表明,这种控制策略符合工业实际,采用的控制器稳定可靠。     

原油乳状液稳定性研究 Ⅱ.原油成分对原油乳状液稳定性的影响

原血成分的表面活性物质及其细微固体颗粒,在油水界面上相互作用是原油乳状液其有稳定性的主要原因。本文采用简单的方法将原油中众多的物质分成两大类,并根椐它们单独时或混合后对癸烷/水乳状液稳定性作用的特征,将其分别称为原油乳化剂和原油破乳剂。试验表明,原油乳状液稳定性的高低主要取决于所含的这两大类物质的多少和相对比例,其相对重要性可由界面张力定性地反映出来;并且由原油/水界面张力的大小可以定性地评估原油乳状液的稳定性。     

热镀锌基板表面缺陷遗传性影响分析及相应措施

研究了酸轧产品表面质量对镀锌产品表面质量的影响,探讨了酸洗质量、乳化液残留、带钢表面粗糙度、冷硬卷表面带状缺陷对镀锌产品表面质量缺陷,如带状锌花偏小或无锌花、片状锌花偏小、线状锌花偏小的影响,并确定了酸洗及轧制过程的关键工艺控制措施,使镀锌产品一级品率提升了1.5% 。     

防雾包装材料用助剂的研究

目的制备一种功能性核-壳结构复合微球。方法以过硫酸铵(APS)引发剂引发苯乙烯(St)、丙烯酸(AA)和甲基丙烯酸甲酯(MMA)进行无皂乳液聚合。采用红外光谱分析仪(FT-IR)对功能微球的结构进行表征,通过扫描电子显微镜(SEM)和激光衍射粒度分析仪对产物的形貌、粒径大小及分布进行分析,采用接触角测定仪(OCA)对材料薄膜与水的接触角进行测定。讨论控制功能微球形态、粒径及分布的影响因素,并研究功能微球薄膜在不同温度下亲水性的变化。结果功能微球为亚微米级核-壳结构,该微球以PSt为核,以亲水性的MMA-AA链段为壳,单分散性良好。结论在25℃时功能微球涂覆薄膜与水的接触角为3°具有最佳的超亲水性能。     

Conversion of aqueous extracts from thermochemical treatment of bagasse into functional emulsifiers

Synthetic emulsifiers in food industries are being replaced with a customer-friendly food ingredient that is derived from biomass using sustainable green technologies. After hydrothermal liquefaction treatment, raw bagasse (21%), pith (26%), and rind portions (25%) were obtained with reduced ash contents. As aqueous extracts, with oligosaccharides and lignin residues, it was used in the preparation of oil-in-water emulsions with 5% soybean oil. Results showed that the emulsions stabilised the oil droplets with particle size between 11 and 17 µm by steric repulsion with raw bagasse-stabilised emulsion showing a better stability at 25 °C (31 days). It was demonstrated that raw bagasse extracts, without alteration, maybe a potential unconventional source for food-grade emulsifiers by integrating a versatile thermochemical conversion of waste without the use of chemicals.     

笋干菜糯米营养保健香肠的开发研究

研究了笋干菜营养香肠的生产工艺,探讨了影响其质量的因素:笋干菜的添加量、糯米的添加量、糯米的颗粒度及肥、瘦肉的比例。并在此基础上采用正交实验得出了最佳工艺条件和配比,结果表明:五花猪肉79%,糯米用量15%,笋干菜用量6%,肥、瘦肉比例2:8,糯米颗粒度30目时香肠质量最佳。     

机械设备对香肠生产工艺的影响（二）

3烟熏蒸煮加工成熟系统 这部分的加工见下图4所示。图43.1设备今天,从事肉类加工的工厂大都装设有自动化的烟熏蒸煮系统,这种系统的时间、温度和湿度是计算机精确控制的。     

十二烯基琥珀酸淀粉酯性质的研究

采用RVA快速粘度测定仪，研究了十二烯基琥珀酸淀粉酯(SSDS)糊的粘度性质。测定了糊的凝沉性质、糊的乳化性质、糊的冻融稳定性、并采用扫描电子显微镜对SSDS的微观结构进行了分析。结果显示：酯化后SSDS的颗粒形貌、糊粘度性质较原玉米淀粉糊有较显著变化、其抗凝沉性、乳化性都明显优于原玉米淀粉，而冻融稳定性比原玉米淀粉差。