Preparation of submicrometer-sized titania hollow spheres by templating sulfonated polystyrene latex particles

Submicrometer-sized titania hollow spheres with tunable shell thickness and smooth surfaces have been successfully synthesized by employing sulfonated polystyrene (PS) latex particles as a template in sol-gel method. The structure of the particles was characterized by scanning electron microscopy and transmission electron microscopy. The shell thickness was readily tuned by altering the concentration of titanium tetrabutoxide (TBOT) in ethanol solutions. The surface roughness as well as the shell thickness has the tendency to increase with the increase in the concentration of TBOT. The diameter of the hollow spheres was on the average of 20-26% smaller than the diameter of template PS latex particles. Some titania fragments were also observed for the sample with the highest TBOT concentration.     

Describing metal surfaces and nanostructures with orbital-free density functional theory

Orbital-free density functional theory (OF-DFT) can be made to scale linearly with sample size, allowing thousands of atoms to be treated explicitly with quantum mechanics. State-of-the-art kinetic energy density functionals and ion–electron pseudopotentials are used to obtain accurate structural property predictions for nanoparticles, nanowires, extended surfaces, and nanoindentation of simple metals.     

Determining stress intensity factors of composites using crack opening displacement

The main purpose of this paper is to find the mixed-mode stress intensity factors of composite materials using the crack opening displacement (COD). First, a series solution of the composite material with a crack was used to evaluate COD values. Then, the least-squares method was used to calculate mixed-mode stress intensity factors. This algorithm can be applied to any method that generates or measures COD values. The major advantage of this method is that COD values very near the crack tip are not necessary. Both finite element simulations and laboratory experiments were applied to validate this least-squares method with acceptable accuracy if the even terms of the series solution are removed.     

Symmetric BEM formulations for 2-D steady-state and transit potential problems

This paper presents a new concept for symmetric boundary element method (SBEM) applicable to 2-D steady-state and transit potential problems. Two kinds of SBEM formulations are derived. Symmetry is obtained simply through matrix manipulation, and no hypersingularity appears. Therefore, SBEM is much easier than the traditional symmetric Galerkin BEM. Compared with the traditional asymmetric BEM, the present SBEM can reduce the computational cost for time domain problems only. However, when applied to BEM/FEM coupling procedure, SBEM can reduce the computational cost for both steady-state and time domain problems. Three numerical examples are included to illustrate the effectiveness and accuracy of the present formulations.     

Linear Algebra Considerations for the Multi-Threaded Simulation of Mechanical Systems

A solution method suitable for the multi-threaded simulation ofmechanical systems represented in Cartesian coordinates isproposed and analyzed. In a state-space framework for thesolution of the Differential Algebraic Equations (DAE) ofMultibody Dynamics, the position/velocity stabilization and theacceleration computation are based on iterative solvers applied toequivalent reduced problems. The most in-depth computationalaspect analyzed is the preconditioning, i.e., the direct solutionof the reduced systems. Provided a topology index reduction is first applied to the model, the effort for the direct solution of the reduced systems is shown to be of order O(N _J ), where N _J is the number of joints in the model. The recurring theme of thepaper is the central role that the topology of the mechanicalsystem plays in the overall performance of the numericalsimulation. Based on the topology of the model, parallelcomputational threads can be established to start in the equationformulation and continue through the iterative numericalalgorithms employed for the numerical solution. Task schedulingthese parallel threads is expected to redeem real-time performancefor certain classes of complex applications.     

漫谈钢铁企业用空分装置的流程选择

钢铁企业的氧气厂要深入了解本企业的用氧情况及周边市场的需要，据此确定拟新增空分装置的设计参数，选定最适宜的空分流程。探讨了空分流程选择时要考虑的几个方面。介绍了一种对空分装置的投资和长期运行费用之间进行经济性分析的定量计算公式，并得出了四点结论。     

节能降耗提高矿山效益

节能降耗是每一个矿山提高经济效益的有效途径。我们采取提高球磨机处理能力，降低单耗；利用“分时计价”政策，采用“避峰作业”；使用新设备等措施节能降耗，提高矿山经济效益。     

Case Study of an Aerosol Explosion and a Method to Determine Explosion Temperatures

A failure analysis case study is presented for a two-piece aerosol containing tetrafluoroethane, commonly referred to as Refrigerant 134a. A gentleman was preparing to recharge the air conditioning system of an automobile when the bottom exploded off the aerosol container, propelling the body of the aerosol container like a rocket, which hit the man in the eye and blinded him in that eye. The aerosol was never connected to the air conditioner, therefore backpressure from the air conditioner (AC) compressor was ruled out as a cause for the explosion. The objective of the study was to determine why the aerosol exploded. Several recently developed test methods were used, including two types of heat-to-burst tests and a puncture chamber to measure the pressure-versus-temperature behavior of aerosols. More common test methods were also used, such as water bath pressure tests, hydro pressure burst tests, pneumatic pressure burst tests, hardness measurements, weight measurements, metallography, scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), and an accident scenario recreation. A semi-empirical correlation between the hardness and weights of the container bottoms was used to determine the explosion temperature and/or pressure. This semi-empirical correlation agrees in principle with an analysis of the explosion pressures using finite-element analysis (FEA). The root cause for the explosion was determined to be a lack of strength of the bottom of the two-piece aerosol coupled with heating the aerosol to temperatures significantly above room temperature.     

Model for Nanoscopic Domain Formation in Dipalmitoyl-PC/Dilauroyl-PC/Cholesterol Mixture

We describe the lyotropic liquid crystalline phase transitions in the lipid mixture dipalmitoil-PC/dilauroy-PC/cholesterol by 3D spin-1 lattice model. The formation of nanoscale domains with the characteristic size about 300 nm was studied in experiments on confocal fluorescence microscopy (CFM) (G. V. Feigenson and J. T. Buboltz, Biophys. J. 80, 2775 (2001)). The structure parameters of the lamellar vesicle in dipalmitoil-PC-rich phase, corresponding to these regions, are verified by numerical Monte Carlo simulations on the lattice. We point its superconductivity analogy properties at the region of phase stability for composition-dependent nanoscopic region.     

换填法建筑地基处理的工程实录

结合某工程的地基处理，对换填法的应用作了较详细的阐述。