PET共聚阻燃改性研究进展

该文综述了近年来聚对苯二甲酸乙二醇酯(PET)以共聚改性方式制备高性能阻燃PET的最新研究进展,主要从磷系共聚阻燃、高温交联、高温重排、高温离子聚集和高温端基捕获链扩展5个方面对阻燃改性PET的阻燃机理和阻燃性能进行阐述,并总结了不同阻燃共聚改性方法的特点,对未来PET共聚阻燃的研究方向提出展望.     

热处理前后丙烯腈／溴乙烯共聚纤维的热性能和阻燃性能研究

分析了热处理前后丙烯腈／溴乙烯共聚纤维的热性能与溴乙烯含量、升温速率或热处理时间的关系，并对纤维的阻燃性与溴含量或热处理时间关系进行了研究。结果表明，溴含量的增加或热处理时间的延长对热稳定性和阻燃性的提高有较大影响，而且经热处理后纤维的阻燃性与溴无关。     

PN—101纸张阻燃剂的研制及应用

采用含磷、含氮化合物，复配制备ＰＮ－１０１纸张阻燃剂；采用该品阻燃处理的纸张，阻燃性能优良，耐热性能好，强度有所增加。     

聚丙烯/蒙脱石阻燃纳米复合材料的研究

阐述了纳米复合材料阻燃性研究的进展,介绍了其制备方法、微观结构的表征手段(XRD)及阻燃性测试技术(锥形量热仪,TGA,氧指数仪),讨论了其燃烧特性和阻燃机理.指出了这种阻燃方法目前存在的问题,展望了该阻燃材料开发应用前景.     

钛石膏作水泥缓凝剂的试验研究

试验了钛石膏中亚铁含量对水泥性能的影响，并检测了用处理后的钛石膏作缓凝剂的水泥物理性能及所配混凝土的收缩值，结果表明，掺钛石膏的水泥与掺天然石膏的水泥标准稠度用水量、凝结时间基本一致；钛石膏的掺量达4％～7％时，水泥的各龄期强度均比掺天然石膏的高；所配混凝土的收缩值基本相同。并进行了大磨中试，表明处理后的钛石膏完全可以代替天然石膏作水泥缓凝剂。     

火焰喷涂塑料粉末

介绍了塑料粉末火焰喷涂的原理、装置及工艺,聚乙烯、EVA树脂、尼龙、聚苯硫醚、氯化聚醚等涂层材料,以及这些涂层材料的耐腐蚀性能。     

三聚氰胺系阻燃剂在尼龙中的应用

介绍了三聚氰胺系阻燃剂的阻燃机理、协同作用、特点，及其在尼龙中的应用；提出了该类阻燃剂的发展趋势。当三聚氰胺系阻燃剂的添加量为尼龙的10％～30％（质量分数）时，材料的阻燃性能达到UL-94V-0级。     

Effect of Vortex Restructuring on Heat Transfer in an “Inverted” Flame

The papers deals with formation of vortex structures during combustion of a fuel gas–air mixture injected vertically down through a hole in a flat plate. It has been established that the shape, position, and number of vortex cells are determined by the flow rate and composition of the fuel mixture. It is shown that as the flow rate increases from the minimum critical value for which a vortex structure arises, the number of vortex cells decreases from five or six to one. A further increase in the gas flow rate leads to transition to turbulence of the combustion product flow. The presence of a vortex structure increases the critical Reynolds number at which the flow becomes turbulent. Reverse transition to the structure with an increased number of vortex cells occurs with a delay in the gas flow rate (gas discharge hysteresis). Variation in flow rate is accompanied by bifurcation of the number of vortex cells.     

Role of atomic hydrogen diffusion in a hydrogen flame

A numerical modeling study of the propagation of a laminar flat homogeneous gas flame has shown that in a hydrogen-air flame, a rapid increase in the concentration of OH radicals begins in the range of low temperatures and the concentration profile has two maxima. The first maximum in the low-temperature region of the front is related to the diffusion of H atoms, formation of HO₂ radicals, and the quadratic branching reaction H + HO₂ → OH + OH. The second maximum in the OH concentration profile is due to the classical high-temperature branching reactions H + O₂ → OH + O and O + H₂ → OH + H. __________ Translated from Fizika Goreniya i Vzryva, Vol. 43, No. 2, pp. 3–9, March–April, 2007.     

Latent catalyst effects in halogen‐free epoxy molding compounds for semiconductor encapsulation

Latent catalyst effects were investigated to improve the physical properties of halogen‐free epoxy molding compounds (EMCs) for semiconductor encapsulation. In this study, biphenyl‐type resins were used as the epoxy and hardener resin for halogen‐free EMCs to obtain high flame‐retardant properties and high filler contents. Latent catalyst effects were examined with two kinds of EMC compositions, halogen‐free EMCs and conventional EMC compositions. We used triphenylphosphine‐benzoquinone salt (TPP‐BQ) as a latent catalyst. Spiral flow and gel time were measured to investigate the change in moldability with the latent catalyst. We measured package fail, moisture absorption, and delamination for reliability evaluation and flexural strength, flexural modulus, and adhesion for mechanical properties to examine latent catalyst effects. An improvement in moldability, reliability, and the mechanical properties were observed in two types of halogen‐free EMCs with TPP‐BQ as a latent catalyst. These phenomena were seen in conventional EMCs, including o‐cresol novolac epoxy resin. The cure kinetics of these systems were investigated by differential scanning calorimetry with an isothermal approach to explain these phenomena. The results indicate that the improvement in moldability in halogen‐free EMCs with TPP‐BQ was due to the low conversion rate of this system, and the increase in mechanical properties was attributed to the high conversion of curing reaction. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 2287–2299, 2005