永平铜矿选矿厂减少硫精矿浓密池硫流失生产实践

针对近两年永平铜矿矿石性质发生变化后，造成硫精矿浓密池跑浑严重的问题所采取的一些技术措施和管理措施，在减少硫精矿浓密池硫流失方面取得了较好的成效，对同类型矿山有一定的借鉴作用。     

阳离子高分子絮凝剂F2合成及表征

以淀粉、丙烯酰胺、环氧丙基三甲基氯化铵为原料,合成了高密度阳离子有机高分子絮凝剂F2,并用红外光谱进行了表征。分子量为66万,F2对石油污水的澄清效果比常用的分子量为800万的聚丙烯酰胺絮凝剂效果好。投加量3 3mg/L时,废水色度的去除率在91%以上。F2与Q6a或Q6b配合絮凝时效果更好。     

改性淀粉絮凝剂的研究

改性淀粉絮凝剂具有无毒、原料来源广、价格低、易于生物降解等优点,近年来得到重视和发展应用。综述了接枝类改性淀粉絮凝剂、离子化改性淀粉絮凝剂如淀粉醚类化合物以及淀粉黄原酸脂类等天然改性淀粉絮凝剂的研究进展及在水处理中的应用。提出改性淀粉絮凝剂未来的发展前景和研究方向。利用我国极为丰富的淀粉资源,开发出更多高效、无毒、价廉的改性淀粉絮凝剂,以满足各种废水处理的不同需要;开发以淀粉为原料的改性天然高分子絮凝剂具有重要的现实意义。     

微生物絮凝剂的研究及应用

介绍微生物絮凝剂的发展历史、优点和作用机理，阐述其在给水和废水处理方面的应用情况。指出欲使微生物絮凝剂部分或全部取代现有的絮凝剂，还有许多问题需要研究。     

聚硅酸铝铁絮凝剂的研究进展

聚硅酸铝铁(PSAF)作为一种新型无机高分子絮凝剂,在除浊、脱色以及去除有机物方面具有优越的性能。文献报道的浊度、色度以及有机物的最高去除率可分别达97%、98%、87%。控制PSAF性能及稳定性的关键因素是Al/Fe/Si的摩尔比、硅酸浓度、碱化度、熟化时间等;同时,PSAF的絮凝效果还受水体参数的影响。介绍了PSAF的制备、絮凝效果及其影响因素,最后简要概括了当前研究存在的问题。     

分析无机絮凝剂混凝机理中的力化学因素

以混凝机理为基础,建立了无机絮凝剂的混凝物理模型。通过混凝物理模型与无机絮凝剂的双电层压缩机理相结合,研究无机絮凝剂和投加时的稀释比例不同产生的效果,指出无机絮凝剂的混凝机理中存在流体力化学效应。     

具有除Cd(Ⅱ)功能的新型高分子絮凝剂的制备

以胺甲基化聚丙烯酰胺(APAM)、二硫化碳、氢氧化钠为原料合成了二硫代羧基化胺甲基聚丙烯酰胺(DTAPAM)。考察了DTAPAM的制备条件。结果表明,在APAM质量分数3.0%,APAM、CS_2、NaOH物质量比1∶2∶2,预反应时间30 min,预反应温度25℃,主反应时间90 min,主反应温度40℃时,DTAPAM除镉性能最好,其最佳投药量随着Cd(Ⅱ)初始浓度的增加而增加。     

Preparation of chitosan-based flocculant for high density waste drilling mud solid–liquid separation

High performance flocculant was prepared by chitosan (CS), ethacryloyloxyethyl trimethyl ammonium chloride (DMC), and acrylamide (AM). The optimum preparation conditions were determined by orthogonal test of four factors and three levels. The different factors affecting the flocculating ability of the prepared flocculants for waste drilling mud were studied, and optimal synthesis conditions were established: polymerization temperature was 60, reaction time was 4 h, DMC was 3 mL, w(AM) : w(CS) was 4, and the initiator was 0.4% of AM (wt %). The prepared CS–AM–DMC copolymer was characterized by Fourier Transform Infrared Spectroscopy (FTIR), scanning electron microscopy (SEM), and gel permeation chromatography (GPC). The results showed that AM, DMC were grafted to CS successfully. The solid–liquid separation properties were also investigated, and the prepared flocculant showed great advantages than commercial products for high density waste drilling mud use. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

阳离子辣椒絮凝剂的制备与应用

以辣椒残渣，阳离子醚化剂，环氧丙基三甲基氯化胺为原料，通过干法合成了一种季胺型阳离子絮凝剂。采用正交实验方法，确定了制备的最佳工艺条件：辣椒与阳离子醚化剂物质的量比1：3，反应温度80℃，反应时间3h。实验用高岭土溶液模拟生活废水，加入自制絮凝剂检测凝剂性能，在此条件下合成的阳离子辣椒絮凝剂的除浊率是88％。     

Synthesis of lignosulfonate-acrylamide-dimethyldiallylammonium chloride copolymer and its flocculation performance

In this work, lignosulfonate-acrylamide-dimethyldiallylammonium chloride (LAD) terpolymer was designed and synthesized by microwave-assisted graft polymerization. The optimal synthetic process was obtained as follows: the monomer ratio was 1:4:4, the amount of initiator was 0.9% (w/w), the monomer solid content was 21 wt %, and the reaction time was 14 min with the microwave power of 280 W. Furthermore, the flocculation performance of LAD was verified by removing acid black-172 dye wastewater. At the LAD dosage of 350 mg L⁻¹, the maximum color removal ratio reached 99.8% in 100 mg L⁻¹ of dye wastewater. The dynamics of dye removal reached higher than 90% after 20 s. The flocculant can maintain color removal ratio more than 98% in a wide flocculant dosage and environmental pH. The flocculation mechanism was mainly electrical neutralization and bridging effect. In general, it is a promising candidate in wastewater treatment in terms of cost, synthetic method, and effectiveness. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48560.