Chemische Zusammensetzung und Mikrostruktur polymerabgeleiteter Gläser und Keramiken im System Si–C–O. Teil 2: Charakterisierung der Gefügeausbildung mittels hochauflösender Durchstrahlungselektronenmikroskopie und Feinbereichsbeugung

Chemical Composition and Microstructure of Polymer‐Derived Glasses and Ceramics in the Si–C–O System. Part 2: Characterization of microstructure formation by means of high‐resolution transmission electron microscopy and selected area diffraction Liquid or solid silicone resins represent the economically most interesting class of organic precursors for the pyrolytic production of glass and ceramics materials on silicon basis. As dense, dimensionally stable components can be cost‐effectively achieved by admixing reactive filler powders, chemical composition and microstructure development of the polymer‐derived residues must be exactly known during thermal decomposition. Thus, in the present work, glasses and ceramics produced by pyrolysis of the model precursor polymethylsiloxane at temperatures from 525 to 1550 °C are investigated. In part 1, by means of analytical electron microscopy, the bonding state of silicon was determined on a nanometre scale and the phase separation of the metastable Si–C–O matrix into SiO₂, C and SiC was proved. The in‐situ crystallization could be considerably accelerated by adding fine‐grained powder of inert fillers, such as Al₂O₃ or SiC, which permits effective process control. In part 2, the microstructure is characterized by high‐resolution transmission electron microscopy and selected area diffraction. Turbostratic carbon and cubic β‐SiC precipitate as crystallization products. Theses phases are embedded in an amorphous matrix. Inert fillers reduce the crystallization temperature by several hundred °C. In this case, the polymer‐derived Si–C–O material acts as a binding agent between the powder particles. Reaction layer formation does not occur. On the investigated pyrolysis conditions, no crystallization of SiO₂ was observed.     

宝钢研制的全氢罩式炉控制系统分析

对宝钢研制的全氢罩式炉计算机控制系统的逻辑结构、工作原理及硬件配置进行了分析.该系统与引进的系统相比,在通讯方式、程序结构、操作分析、报警和开放性等方面都有所改进.     

兰州重离子加速器大型真空室

已建成的兰州重离子加速器的真空室是一个大型整体结构的超高真空容器,直径约10m,高4.5m,重65000kg,内表面积211m~2,容积100m~3,工作真空度为5×10~(-5)Pa。采用有限单元法在计算机上用SAP-5C程序对真空室受力分析进行了计算。真空室结构材料选用瑞典Uddeholm钢厂生产的316 L 超低碳不锈钢。承制此大型容器的是航天工业部风华机器厂。由于结构庞大,首先将真空室分成八大块和几小块在工厂制造,然后运至现场焊制成一整体容器并进行机械加工。所有密封焊缝均用着色渗透液,X-射线探伤和氦质谱探漏仪进行检查和探漏。     

鞍钢现有人造富矿产能及1600万t/a生铁规模的合理炉料结构的探讨

简要介绍了鞍钢现有人造富矿生产能力，分析了鞍钢生产1600万t／a生铁所需要的炉料数量、品种和质量，并提出了解决炉料缺口的方法和措施。     

电子表格EXCEL5.0在选煤线性规划问题中的应用

采用电子表格软件ＥＸＣＥＬ５．０可以方便地解决许多选煤生产中的线性规划问题。本文通过选煤过程线性规划实例介绍ＥＸＣＥＬ５．０在此领域的应用方法。     

Subdivision of work on construction projects

In order to control a project, construction management requires project information. This is obtained through accounting, estimating, cost management and scheduling functions which produce project reports. These reports are best obtained by subdividing the project into small parts. The ways in which each of these functions subdivides a project in order to produce its reports is discussed, together with a means of interrelating this information with a technique known as the work breakdown structure.     

Robustness of VS-MRAC with respect to unmodelled dynamics and external disturbances

A variable structure model reference adaptive controller (VS-MRAC) using only input and output measurements was recently proposed and shown to be globally asymptotically stable with superior transient behaviour and disturbance rejection properties. In this paper a singular perturbation approach is used in order to establish the robustness of the controller in the presence of unmodelled dynamics (parasitics) and disturbances. We develop a new Lyapunov-based technique to analyse the overall system and show that for sufficiently small parasitics the system remains stable and the output error is small in some sense.     

The relationship among oxygen content, defect distribution and superconductivity in BiSrCaCuO systems

The effect of oxygen content on superconductivity of the 2212 and 2223 phase has been studied. By comparing the excess oxygen, the modulation vector, the XRD patterns, and the electric resistivity of 2212 and 2223 phase samples obtained with different post-annealing conditions, i.e., annealing at 600°C or quenching from 860°C, it was found that the super-conductivity is markedly influenced by both the defect distribution in non-Bi layers and the interstitial oxygens incorporated in the Bi-O layers. A tentative explanation for this is given.     

Symmetric Structures of Ultrahard Materials

Diamond and BN have common relatively soft precursor structures that are hexagonal. Electronic structure calculations have now revealed subtle energy differences between the two materials. Another hard material, stishovite, also has a relatively soft precursor phase, quartz, and here again electronic structure calculations have given insight into the nature of the phase transformation. On the other hand, with boron-related materials, the main focus is to connect basic icosahedra structures to produce a hard material. The structural aspects of these materials are examined and possible consequences for low- and high-coordination ultrahard nitrides considered.     

Deposition mechanisms in langmuir-blodgett films

As part of a study of the possible application of polymerisable Langmuir-Blodgett (LB) films as ultra-fine-line e-beam resists, an investigation of the variation of film structure of 22-tricosenoic acid with differing deposition conditions has been made. Unexpected effects with significant implications for deposition speed and resist sensitivity have been observed, and the new techniques for film characterisation developed during the investigation have resulted in a revised model of deposition explaining the observed independence of the disorder causing optical scattering and the macroscopic features observed by polarised microscopy.