Preparation of High Strength and Toughness Aramid Fiber by Introducing Flexible Asymmetric Monomer to Construct Misplaced-Nunchaku Structure

High performance fibers with high strength and toughness have great potential in composites, but contradiction between tensile strength and elongation at break makes the preparation to become a current challenge. Herein, an asymmetric structure of more flexible diamine, 3,4′-diaminodiphenyl ether (3,4′-ODA), is introduced into heterocyclic aramid (PBIA) fibers to replace rigid symmetric p-phenylenediamine (PDA). By studying the properties of copolymer (mPEBA) fibers with different ratios of diamine, it is found that the mPEBA fiber reached the optimal mechanical properties with the 30% content of 3,4′-ODA. Compared with homopolymerized heterocyclic aramid fibers, the tensile strength and elongation at break of mPEBA fiber are improved by 26.2% and 38.7%, respectively. Results of X-ray diffraction show that the introduction of 3,4′-ODA structure can increase stretchability of mPEBA fibers, improving the orientation degree during hot-drawing. Molecular dynamics simulations confirm that 3,4′-ODA structure undergoes a conformation transformation to form a straightened chain during hot-drawing, while symmetrical 4,4′-diaminodiphenyl ether (4,4′-ODA) cannot form the same conformation. The misplaced-nunchaku structure is formed based on the special meta-para position of 3,4′-ODA, achieving the synergy of high strength and high toughness.     

A replacement of traditional insulation refractory brick by a waste-derived lightweight refractory castable

Lightweight insulation refractories are essential for high-temperature performance to reduce energy consumption. This study investigates a new insulation material, that is, solid waste rice husk ash (RHA) derived lightweight refractory castable, replacing traditional insulation refractory brick. The RHA is generated after the burning of rice husk as biomass fuel. The RHA is used as an aggregate and alkali-extracted silica sol from RHA as a binder to fabricate the insulation castable. The nanosilica containing (~30 wt%) sol is employed to synthesize the refractory castable by varying the sol amount (2.5-12.5 wt% silica from sol). The castable specimens are cast by a vibro-caster and fired at 900-1200°C in a muffle furnace. The physic-mechanical and thermal conductivity (κ) of the castable is investigated. At 1100°C with 10 wt% dry sol retaining sample shows an excellent apparent porosity (~65%), low bulk density (~ 0.8 g/cm³), and κ (0.136 W/m k) with sustainable compressive strength (6 MPa). The acquired results are a good match with the literature (other wastes-derived insulation materials) and industrial (silica insulation brick) obtained data. These promising outcomes may inspire the refractory industries for using RHA as an aggregate and RHA extracted sol as a binder for making insulation castable.     

煤粉炉粉煤灰提取氧化铝活化技术研究进展

介绍了近年来采用煤粉炉粉煤灰作为原料制备氧化铝的预处理活化工艺技术,指出了粉磨法、硫酸法、氯化钙法、铵盐法、碳酸盐法、氟化盐法、物理-化学联合活化法的优缺点及在工程转化过程中需重点关注的环节。虽然部分工艺技术实现了工业化,但因成本高等因素导致项目关停,建议粉煤灰综合利用研究方向应以工程转化难点问题为导向,理论研究与工程设计相结合,逐步探索出一条经济效益好、安全环保的粉煤灰制备氧化铝工业化路线。     

Pd／Ag纤维复合材料的制备工艺

用包套拉伸法和挤压法制备Ｐｄ／Ａｇ纤维复合材料，并通过金相和电子显微镜分别观察其微镜分别观察其微观结构，测试其性能，如电阻率，硬度，强度及接触电阻等。通过对比其工艺性及所得材料的微观结构和性能，认为挤压法优于包套拉伸法。此种Ｐｄ／Ａｇ纤维复合材料适合Ｐｄ／Ａｇ型复合铆钉和生产复铜铆钉。     

Fabrication of composite wire of lead coated on glass fiber by extrusion

1　INTRODUCTIONCoatingglassfiberwithleadproducesakindofnewcontinuouscomposite ,whichcanfindwideap plicationsinmanydifferentfields ,especiallyinthebatteryoftheEVsandHEVsthathasalreadybecomethemostimportantgoalinmostcountries[13] .Withakindofspecialtechnologythiskindofnewcompos itewirecanbeusedtoproducegridsofnewleadacidbatterythatisveryusefultotheEVsandHEVs .Thiskindofnewleadacidbatteryhasmanyadvan tages ,suchashigherspecificenergy ,lessinnerresis tance ,morequicklychargingcapabilityand…     

SiC FIBER／ALUMINIUM PREFORM WIRES FABRICATEDBY ULTRASONIC LIQUID INFILTRATION PROCESS

ＳｉＣＦＩＢＥＲ／ＡＬＵＭＩＮＩＵＭＰＲＥＦＯＲＭＷＩＲＥＳＦＡＢＲＩＣＡＴＥＤＢＹＵＬＴＲＡＳＯＮＩＣＬＩＱＵＩＤＩＮＦＩＬＴＲＡＴＩＯＮＰＲＯＣＥＳＳＺｈａｎｇＣｈｅｎｇｅ；ＷａｎｇＬｉｎｇｓｅｎ（ＣｅｎｔｒａｌＳｏｕｔｈＵｎｉｖｅｒｓｉｔｙｏｆ...     

磁性纤维随机混合媒质等效电磁参数的计算

为计及强散射偶极子间的相互作用,引入参量εh和μh,利用广义多重散射理论及MATLAB计算机软件对在2 GHz～18 GHz频率下的体积占空比为8%的铁纤维随机混合媒质等效磁导率的实验值进行曲线的拟合,导出了耦合系数εh和μh,并在此基础上,对体积占空比分别为30%和20%的铁纤维随机混合媒质等效磁导率进行了计算,计算结果与实验吻合良好.     

3D C/SiC复合材料在复杂环境试验中性能演变的两重性

用减压化学气相浸渗法(LPCVI)制备2组3D C/SiC复合材料,其中一组具有不同厚度的PyC界面层,另一组PyC界面层厚度一定,但经过热处理.对C/SiC复合材料在复杂环境中性能演变的两重性,即确定性和随机性进行了研究.结果表明,残余强度及其波动性对评价材料的环境适应性和可靠性是必需的.界面层和涂层是对氧化环境最敏感的微结构控制单元.以敏感度排序,3种环境参数依次是温度、气氛和应力.气氛参数的排序是氧气、水和盐,应力参数的排序是疲劳/蠕变,蠕变和疲劳.应力通过增加涂层裂纹及宽度从而加速复合材料的性能演变.氧化物薄膜有利于涂层裂纹封填,水能促进这种封填,然而疲劳/蠕变应力会使涂层裂纹封填失效.因此包括有氧气、水、疲劳和蠕变的环境是所有环境中最恶劣的.为了使复合材料具有自适应性,PyC的厚度应为最优,以提高热处理的效果;需保持适中的涂层氧化速率,以提高近表面抗氧化性.而适中的氧化速率是由温度和氧化气体分压来控制的.     

Thixoforging of continuous fiber-reinforced AlSi/AlMg-alloys

High strength in combination with low density is the key features for lightweight constructions in automotive and aerospace applications. Tailor-made fiber reinforcements in light-metal matrices could help to achieve this goal. However, the integration of fibers with conventional casting-route manufacturing techniques like squeeze casting or diffusion bonding restricts the component geometry and results in elevated process cost due to long cycle times and the need of additional fiber coatings. In the center of competence for casting and thixoforging Stuttgart (CCT), new processes for manufacturing metal matrix composites are developed. Long-fiber reinforced Al–Si alloys and components are produced by thixoforging of laminates made of alternating metal matrix layers and carbon fiber fabrics. This paper illustrates the manufacturing technology and first experimental results with special focus on fiber penetration and infiltration behavior and also on the formation of fiber-matrix interface to analyze fiber damage by mechanical or chemical attack.     

磷氮阻燃腈纶结构性能及阻燃机理研究

研究了含磷酸二氢铵和脲复合阻燃剂的共混阻燃腈纶的结构和性能。研究表明，在纤维成形加工过程中，部分阻燃剂聚合生成聚磷酸铵和聚脲，阻燃剂以微粒状均匀分散并包埋在纤维内部；阻燃剂的加入使纤维高序区大分子间等距离排列的规整性和片状结构单元等距离平行排列的程度降低，热稳定性亦略有下降；但纤维的宏形态结构及物理机械性能没有明显变化；磷氮阻燃腈纶具有良好的阻燃性和阻燃耐久性，经碱洗２０次、水洗３０次后，阻燃剂的磷和氮的保留率分别高达８２．９％和８９．５％，纤维的ＬＯＩ值仍在２６％以上。