Lipid hydrolysis and oxidation on the surface of milled rice

The changes in milled rice FFA content and composition and in conjugated diene (CD) content and bacterial, yeast, and mold counts were determined at 24, 37, and 50°C and 70% RH over 50 d. There was a rapid rate of FFA formation during the first few days of storage, which was optimal at 37°C, but that slowed after 2, 4, and 5 d at 37, 24, and 50°C, respectively. There was a second increase in FFA after about day 12 that increased with increasing temperature, indicating nonlipase hydrolysis. Linoleic and oleic acids were the main components of the total FFA produced on the surface of milled rice. The pattern of CD development followed that of FFA increase. Bacterial growth correlated with increased FFA levels after 12 d of storage, suggesting that bacterial lipase rather than bran lipase may be responsible for rice lipid hydrolysis     

Use of rice bran oil and epoxidized rice bran oil in carbon black–filled natural rubber–polychloroprene blends

In the present study we report the results obtained on the use of rice bran oil (RBO), a naturally occurring nontoxic oil, and its epoxidized variety (epoxidized RBO, or ERBO) in the compounding and vulcanization of different natural rubber–chloroprene rubber (NR–CR) blends. The processability, cure characteristics, and physical properties of the blends prepared with these oils were compared with those of control mixes prepared with aromatic oil. The optimum cure time and scorch time values of the different blends prepared with these oils were found to be lower than those of the respective control blends prepared with aromatic oil. Evaluation of physical properties of the different experimental blends showed that replacement of aromatic oil with these oils did not adversely affect their physical properties. Because RBO contains a good amount of free fatty acids it was tried as a coactivator in addition to its role as a processing aid. The level of these oils required for the blend preparation was optimized in a Brabender plasticorder. Physical properties such as tensile strength, elongation at break, tear strength, swelling index, and abrasion loss, for example, were evaluated for both experimental and control mixes. Comparison of cure characteristics and physical properties of the blends prepared with aromatic oil and with these oils showed that these oils could be used in place of aromatic oil in the above blends. It is also to be noted that aromatic oil is of petroleum origin and is reported to be carcinogenic. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 4084–4092, 2003     

Increasing the firmness of wax-based oleogels using ternary mixtures of sunflower wax with beeswax:candelilla wax combinations

Oleogels were prepared with 5% wax in soybean oil using mixtures of beeswax (BW) and candelilla wax (CLW) with ratios of 10:90, 30:70, 50:50, and 60:40 BW:CLW, and the same series where 10% of the total wax was substituted with sunflower wax (SFW). The hypothesis that SFW would increase the firmness of the oleogels without affecting the melting properties was tested. Firmness of one-wax oleogels decreased from SFW > CLW > BW. Oleogels with 50:50 BW:CLW and 60:40 BLW:CLW had equal firmness to pure 5% SFW oleogels. SFW significantly increased oleogel firmness and reduced the softening that occurred between 4°C and 22°C. Increased firmness was also found with rice bran wax and behenyl-behenate (C44) addition, but not with wax esters with chain lengths ranging from 30 to 40 carbons (C30 to C40). By differential scanning calorimetry, SFW significantly decreased the melting point of oleogels with 10:90 and 30:70 BW:CLW mixtures but significantly increased the melting point of those with 50:50 and 60:40 BW:CLW mixtures. However, the solid fat content melting curves were not significantly influenced by SFW addition. These results indicate that mixed wax oleogels had greater hardness and elasticity, and that the long chain wax esters contributed by SFW helped to improve the strength of oleogels without negatively affecting their melting properties.     

A New Model and Quality of Unfrozen and Frozen Cooked Rice Dried in a Microwave Vibro-Fluidized Bed Dryer

This study aimed to develop a suitable drying model for microwave vibro-fluidized bed drying in a single-mode applicator (MVFB-SMA drying) of cooked rice with and without prefreezing treatment and to investigate the effects of prefreezing treatment and drying temperature (110–185°C) on quality of dried cooked rice. During the process of drying cooked rice from 60 to 10% (wet basis), results indicated that drying rate increased, whereas drying time decreased with prefreezing treatment and increased drying temperature. The drying rate and drying time of unfrozen and frozen cooked rice ranged from 0.196 to 0.497 g water/g dry matter/min and 0.228 to 0.554 g water/g dry matter/min; and from 7 to 2.5 min and 5.5 to 2 min, respectively. A new model was proposed in this study (MR = exp(?k t ⁿ ) + bt + c) to compare with 11 commonly used drying models. The new model describes the MVFB-SMA drying data most satisfactorily. The values of effective diffusivity were between 1.70 × 10^?7 and 5.72 × 10^?7 m²/s for the unfrozen sample and between 1.99 × 10^?7 and 5.86 × 10^?7 m²/s for the frozen sample. Their activation energy values were 23.66 and 21.19 kJ/mol, respectively. Prefreezing treatment provided a whiter product with a less uniform porous structure and higher bulk density. Slower ability to rehydrate was also observed for the frozen cooked rice dried at 160 and 185°C. An increase in drying temperature resulted in changes in whiteness, microstructure, bulk density, and rehydration capability. No prefreezing treatment and drying at 160°C seemed to be the optimal process condition for cooked rice, ensuring whiteness, a porous structure, low bulk density, and high rehydration capability.     

Comparative Evaluation of Hot-Air and Superheated-Steam Impinging Stream Drying as Novel Alternatives for Paddy Drying

An investigation was conducted on impinging stream drying of moist paddy using hot air and superheated steam as the drying media. Drying experiments were divided into two parts: namely, one-pass and two-pass drying. The volumetric water evaporation rate, volumetric heat transfer coefficient, and specific energy consumption of the drying system at various conditions were assessed; in the case of superheated-steam drying, the effect of steam recycle was also assessed. The quality of dried paddy was evaluated in terms of color, head rice yield, and degree of starch gelatinization. In the case of one-pass drying, an increase in the drying temperature led to a significant increase in the volumetric water evaporation rate and volumetric heat transfer coefficient. On the other hand, in the case of two-pass drying, an increase in the drying temperature led to a significant decrease in the volumetric heat transfer coefficient; the volumetric water evaporation rate was not significantly affected, however. The specific energy consumption decreased with an increase in the drying temperature. At the same temperature, using superheated steam as the drying medium led to lower specific energy consumption; higher level of steam recycle also led to more energy conservation. The color of the dried paddy was not affected by the change in the drying temperature; superheated-steam-dried paddy was redder and more yellow than the hot-air-dried paddy. An increase in the drying temperature led to decreased percentage of head rice yield. Superheated-steam drying helped enhance the level of starch gelatinization in comparison with hot-air drying at the same temperature. Nevertheless, drying at the highest tested temperature led to a lower level of starch gelatinization.     

DEHUMIDIFICATION DRYING OF HIGH-MOISTURE ROUGH RICE IN A RADIAL-FLOW,CIRCULAR BIN

Abstract

An experimental radial-flow, circular bin dryer with a dehumidifier was fabricated and tested for rough rice drying. Results showed that high-moisture paddy could be dried to 14% moisture content (wet basis) over a 24 h drying span at an average drying rate of 0.5%/h. The open-cycle system's specific moisture extraction rate and the dehumidifier's coefficient of performance were within the usual range of values cited for similar conventional systems or equipment. The quality of the dehumidifier-dried and naturally dried paddy was similar with respect to minimum grain Assuring, The system was found to be a technically feasible, more energy-efficient and safer alternative to electrical resistance heating in the conditioning of ambient air for drying under humid tropical conditions.     

Effects of High-Temperature Drying on Physicochemical Properties of Various Cultivars of Rice

Abstract

Three varieties of paddy rice, namely Langi and Amaroo from Australia and Chainart I from Thailand, were dried from high initial moisture content of about 27% down to 13–14% wet basis using a two-stage drying system. A fluidized bed dryer reduced the moisture content down to 18%. Drying experiments were carried out at 100, 125, and 150°C. Further moisture content reduction down to 14% was achieved by shade drying. As a result of these treatments, head rice yield increased proportionally with the drying temperature. In contrast to that, the yellowness, measured by colorimeter in terms of b value, showed an opposite trend. Starch characteristics were studied by Rapid Visco Analyser (RVA), x-ray diffraction, and differential scanning calorimetry (DSC). Pasting properties were affected by the drying temperature. The peak viscosity and break down were decreasing with the increase of drying temperature in all varieties while the setback values were increasing in Langi and Amaroo only. All starch samples displayed the typical A type x-ray diffraction pattern. The apparent crystallinity determined by x-ray diffraction was reduced with increasing drying temperature. The gelatinization peak shifted to higher temperature while the endothermic enthalpy of gelatinization decreased with increasing drying temperature.     

Stationary versus Fluidized-Bed Drying of High-Moisture Paddy with Rest Period

Drying of high-moisture paddy was examined experimentally under stationary and fluidized bed with and without intervening rest periods. Introduction of a rest period between first and second stage of drying improved drying rate and lowered the energy requirement and increased head rice yield. Fluidization further improved the overall drying process. A single-term drying diffusion equation was suitably fitted to first, rest, and second stage drying data of fluidized and stationary bed by applying nonlinear regression method and effective diffusion coefficients were evaluated. During the period of rest stage, paddy grain released a considerable amount of moisture as an effect of residual grain temperature. An appropriate moisture ratio at which resting should start and the length of resting were evaluated by measuring changes in relative humidity in the headspace of mass of paddy and also from the diffusion coefficient values obtained from the experimental drying data. Resting duration between 75 and 90 min at moisture ratio around 0.715 was found suitable for overall good performance in both fluidized and stationary bed drying. A considerable amount of energy (21–44%) can be saved by providing a rest period from 30 to 120 min between the two stages of drying. Fluidization further reduces (≈ 50% against continuous drying under stationary bed) the energy requirement. No significant difference was found in head rice yield obtained from fluidized and stationary bed experiments, though discontinuing drying by providing intervening rest periods considerably improved the percentage head rice when compared with the results from continuous drying.     

连续法制备环氧米糠油

将双氧水、甲酸和专用催化剂滴加入米糠油中,在三个串联连接的反应釜中用连续法对米糠油进行氧化,产品精制后得到环氧米糠油。产品质量优于用传统方法生产的产品。