提高16Mn连铸坯控轧合格率

１６Ｍｎ连涛坯进行控轧时，按铸坯碳当量的上限和下限，分别采用两种不同的控轧制度。在邯钢中板分厂试轧的结果，轧材合格率均达到９６％以上，投产后轧材合格率达到９８％以上。     

Electrochemical properties of ultra-long,aligned, carbon nanotube array electrode in organic electrolyte

The electrochemical properties of an electrochemical double-layer capacitor electrode based on an ultra-long (500 μm), aligned, carbon nanotube array (ACNTA) in Et₄NPF₆/propylene carbonate electrolyte are examined. The specific capacitance of the ACNTA electrode in an organic electrolyte is 24.5 F g⁻¹, which is larger than that obtained in an aqueous electrolyte. The results of ac impedance measurements show that the ACNTA electrode gives a high power density and an excellent rate capability in an organic electrolyte. It is shown that the ACNTA electrode has a lower equivalent series resistance and a better rate capability than activated carbon electrode. This is due to the fact that ACNTA possesses a larger pore size and a more a regular pore structure. Both these features are conformed by scanning electron microscopic and nitrogen gas adsorption studies.     

95W-Ni-Fe 合金工艺缺陷的 SAM 和 XPS 分析

藉助扫描俄歇探针、Ｘ射线光电子谱等分析了９５Ｗ－Ｎｉ－Ｆｅ合金碳污染和氧化的本质。发现，碳污染试样中碳的化学状态主要为石墨，少量为铁或镍的有机化合物，这些物质的界面富集使材料脆化。钨合金氧化后，氧大量富集于钨／粘结相界面，使沿着该界面的断裂更容易发生。     

利用分形几何确定多孔介质的孔尺寸分布

提出了利用分形几何确定多孔介质孔尺寸分布的方法。考虑多孔介质中孔间的屏蔽，采用此方法得到的孔尺寸分布范围比采用平行孔模型宽，分别采用本方法和平行孔模型测定γ－Al2O3催化剂的孔尺寸分布，构造简单立方体三维网络模型模拟压汞过程，并将模拟曲线与γ－Al2O3压汞实验曲线比较，结果表明，采用本方法所得孔尺雨分布优于平行孔模型所得孔尺寸分布。     

担载型含稀土三组份体系在二氧化碳甲烷化反应中的催化性能

用浸渍法制备了一系列氧化锆担载的含稀土Ⅷ族金属催化剂，对其在二氧化碳甲烷化过程中的催化活性作了研究，并用漫反射紫外可见光谱，ＦＴＩＲ等手段对催化剂作了表征。结果表明，含稀土新型催化剂具有催化活性高，目标产物选择性好等优点；稀土主要以氧化物形式存在于催化剂表面，参与对氢及表面含碳物种的吸附及活化；含稀土三组份催化剂的活性与所添加稀土三价离子的４ｆ电子数有关。     

Holmium-doped Porous Silicon Prepared by a New Electrochemical Approach and Its Photoluminescence

Ｐｏｒｏｕｓｓｉｌｉｃｏｎ（ＰＳ）ｗａｓｆｏｕｎｄｔｏｅｍｉｔｖｉｓｉｂｌｅｌｕｍｉｎｅｓｃｅｎｃｅａｔｒｏｏｍｔｅｍｐｅｒａｔｕｒｅｂｙＣａｎｈａｍｉｎ１９９０［１］．Ｔｈｉｓｐｈｅｎｏｍｅｎｏｎｉｍｐｌｉｅｄａｐｏｔｅｎｔｉａｌａｐｐｌｉｃａｔｉ...     

真空阴极弧离子镀类金刚石碳（DLC）膜的碳弧稳定性研究

选用氩气、氩气加氢气、氩气加乙炔等气体作为介质，石墨作为靶材进行真空阴极弧离子镀来制备类金刚石碳膜。石墨电弧有其独特的电弧特性曲线，不同气体介质对碳弧特性的影响不同，磁场的大小对电弧的稳定性有很大作用，碳弧下基片偏流随电弧电压的增加而减小，试验得到表面光滑的类金刚石碳（DLC）膜，对膜的表面进行了SEM分析。     

氯化氢浸渍活性炭净化汞蒸气的研究

用氯化氢对吸附汞热气用的活性炭进行浸渍处理是一种新的偿试。用氯化氢浸渍后的活性炭，对汞的吸附效率和吸附容量与没有浸渍的活性炭相比，均有很大的提高，同时，与其它吸附汞用的浸渍剂相比，具有价格低，来源广的优点，对汞的吸附效率平均在９５％以上。     

中国南海北部二氧化碳气成因

中国南海北部海域在油气勘探中发现了CO_2气,对油气有无影响?在借鉴世界、中国东部陆地CO_2气成因研究成果的基础上,从分析研究区CO_2,气的分布入手,采用多种方法,在综合分析基础上,对本区CO_2气藏进行分类.认为研究区CO_2;气藏为无机成因,其特征受各盆地或地区具体地质条件的控制.哈萨克斯坦引起了国际石油界的很大关注,但它并不是前苏联唯一的具吸引力之地.美国地质调查调查所(丹佛)和AAPG今年著名讲演者Gregory F Ulmishek说.前苏联有20多个沉积盆地生产油气或具有尚未开采的发现.Ulmishek 1980年到美国前,获得过莫斯科石油学院地质学硕士学位,作为一个地质学家在前苏联工作过23年.他的1993—1994年题为“前苏联主要油气地质学及勘探潜力”的著名演讲在1993年12月6日至17日和1994年3月28日至4月8日的巡回活动中推出.     

Influence of rainfall on the performance of bioretention systems modified with activated carbon and biochar

The use of bioretention areas is common in urban stormwater management, but their performance varies significantly depending on rainfall characteristics and design conditions. In this study, a pilot experiment using bioretention columns with different media (commercial activated carbon and river sediment-derived biochar) investigated the influence of rainfall on bioretention performance. The results indicated that the runoff volume retention ratio (R_v), which included the runoff purified and discharged at the bottom of the column, and the runoff retained in media during rainfall event, decreased significantly with increases in the rainfall event return period (p < 0.05). The R_v of the activated carbon and biochar columns decreased with a 2-yr return period and then fell further with a 50-yr return period. Porous material has been shown to improve the water-holding capacity of bioretention media, but it did not result in an improved R_v under heavy rain that exceeded the 2-yr return period. With the increase of the return period from two to 50 yr, the mass removal efficiency (R_L) of total phosphorus and phosphate illustrated a clear decreasing trend in all columns. The total nitrogen, ammonia and nitrate removal did not show a clear trend with return periods because of transformations among different forms of nitrogen and similar saturation periods during the different rainfall events. The influence of the return period on chemical oxygen demand (COD) removal was related to whether the inflow COD reached maximum COD removal capacity of the bioretention media. Under a rainfall event with a specific return period, there were no significant differences in the R_L of all nitrogen species and COD among the different columns (p > 0.05). The addition of adsorptive material, such as activated carbon and biochar, may not be the key factor for improving nitrogen and COD removal under heavy rain that exceeds the 2-yr return period. The bioretention performance of phosphorus removal from urban stormwater runoff could be improved by replacing or adding media with high adsorption capacity, but these improvements would not be significant under heavy rain that exceeds the 2-yr return period. The results provide some reference for evaluating bioretention performance and optimizing bioretention design in the future.