深穿透复合射孔技术在中原油田的应用

深穿透复合射孔是一项把射孔与高能气体压裂两种技术有机地结合在一起的综合改造油气层的新技术。重点对它的技术原理，包括设计原理、枪身内火药燃烧气体对射孔孔眼的冲刷作用原理、火药燃烧气体射流的高能气体压裂作用原理等进行了研究与探讨，同时对它的施工工艺、现场应用等方面进行了阐述，经中原油田189口井现场应用证明，其工艺简便，成本低廉，可实现多层跨隔层使用，处理后增产效果显著，投入产出比高，可代替传统的聚能射孔技术，具有广阔的推广和应用价值。     

葡萄栽培品种花芽高节位分化观察研究

在管理良好、植株健壮的条件下，葡萄花芽高节位分化是一个普遍的现象。一年生枝从低节位到高节位均可形成正常的花芽，并能正常开花结果，而且高节位分化花芽对当年的果实品质及次年的花芽分化无不良的影响。合理利用这一特性对促进葡萄幼树早丰产有重要的指导意义。     

从菜西瓜中提取果胶的最佳工艺研究

为确定从菜西瓜中提取果胶的最佳工艺条件,以山西省临汾市菜西瓜为材料,采用酸法进行了提取果胶的试验研究。正交试验结果表明:在萃取时间为45min的前提下,从瓜瓤中提取果胶的最佳工艺条件是加水量为原料重量的4倍,85℃下,添加原料重量0.3％的多聚磷酸钠,果胶得率可达2.03％;从外果皮中提取果胶,加水量为原料重量的4倍,75℃下,添加原料重量0.7％的多聚磷酸钠,果胶得率可达2.98％。     

Preparation, Characterisation and Catalytic Behaviour of a New TeVMoO Crystalline Phase

TeM_xMo_1.7O mixed oxides (M = V and/or Nb; x = 0-1.7) have been prepared by calcination of the corresponding salts at 600 °C in an atmosphere of N₂. A new crystalline phase, with a Te/V/Mo atomic ratio of 1/0.2-1.5/1.7, has been isolated and characterised by XRD and IR spectroscopy. This phase is observed in the TeVMo or TeVNbMo mixed oxide but not in the TeNbMo mixed oxide. The new crystalline phase shows an XRD pattern similar to Sb₄Mo₁₀O₃₁ and probably corresponds to the M1 phase recently proposed by Aouine et al. (Chem. Commun. 1180, 2001) to be present in the active and selective MoVTeNbO catalysts. Although these catalysts present a very low activity in the propane oxidation, they are active and selective in the oxidation of propene to acrolein and/or acrylic acid. However, the product distribution depends on the catalyst composition. Acrolein or acrylic acid can be selectively obtained from propene on Nb-free or Nb-containing TeVMo catalysts, respectively. The presence of both V and Nb, in addition to Mo and Te, appears to be important in the formation of acrylic acid from propene.     

双河油田特高含水后期开发阶段注采结构调整的实践与应用

针对双河油田的注采结构的现状及特征,通过近几年来在注采结构调整方面的实践与应用,总结出了油田在特高含水后期开发阶段,实现油田控水稳油目标的途径和方法,注水结构调整主要是结合地质特点,减少欠注层段,减少和控制不合理超注井层段和改善吸水剖面;在采液结构调整上,控制高含水层段的注入,加强中低渗透层段的注入,封堵高渗透、高水淹干扰层段,解放动用较差的中低渗透层段,改善平面上采出不平衡的状况。通过实施注采结构调整,双河油田在特高含水后期实现了高效开发。     

The effect of doubly tapered strut morphology on the plastic yield surface of cellular materials

Although the literature on the mechanics of cellular materials is vast, there is no theoretical model to account for the effects of axial yielding of struts aligned to the applied loading direction on the plastic yield surface under multiaxial loading conditions. An anisotropic hexagonal model having tapered strut morphology is developed to show these effects on the plastic yield surface under multiaxial tensile loading condition. This model covers several types of cellular structure such as two-dimensional (2D) hexagonal and square cellular materials, and three-dimensional (3D) hexagonal and rhombic cellular materials of rod-like columnar structure. A tetrahedral element with tapered strut morphology is also used for a foam model to illustrate these effects on the yield surface under axisymmetric loading condition. Plastic collapse due to bending moment in the inclined struts is a dominant mode. However, under multiaxial tensile loading, the collapse due to axial yielding of struts parallel to the loading direction is found to be an important mode. The shape of plastic yield surface was found to depend not only on relative density but also on the strut morphology.     

破乳-酸化法处理直馏柴油精制废碱液

采用破乳 -酸化法对直馏柴油精制废碱液进行处理 ,筛选出最佳的破乳条件和酸化终点。实验结果表明 ,采用破乳剂或热力破乳 -酸化法预处理直馏柴油精制废碱液是一种有效的预处理方法。经该方法处理后的废碱液化学需氧量 (COD)下降率可达 93 4 %,除油率为 87%,副产物硫酸钠能得到最大限度地回收利用。同时 ,该方法设备简单 ,处理费用低廉 ,易于实现工业化。     

熔融-固相缩聚法中固相聚合对聚乳酸合成的影响

以L 乳酸单体为原料 ,熔融 -固相缩聚法合成了聚乳酸 ,重点研究了固相聚合的工艺条件。结果表明 ,绝对压力 60Pa ,氯化亚锡为催化剂 ,分段控温 ,可使聚乳酸的粘均分子量提高到固相聚合反应前的 5 3倍。通过对固相聚合产物的结晶度和熔点的分析 ,探讨了固相聚合的机理。     

Facile modifications of polyimide via chloromethylation: II. Synthesis and characterization of thermocurable transparent polyimide having methylene acrylate side groups

From chloromethylated polyimide, a useful starting material for modification of aromatic polyimides, a thermocurable transparent polyimide having acrylate side groups was prepared. In the presence of 1,8‐diazabicyclo[5,4,0]undec‐7‐ene, chloromethylated polyimide was esterified with acrylic acid to synthesize poly(imide methylene acrylate). The polymer was soluble in organic solvent, which makes it possible to prepare a planar film by spin coating. The polymer film became insoluble after thermal treatment at 230 °C for 30 min. Optical transparency of the film at 400 nm (for 1 µm thickness) was higher than 98 % and not affected by further heating at 230 °C for 250 min. Adhesion properties measured by the ASTM D3359‐B method ranged from 4B to 5B. Preliminary results of planarization testing showed a high degree of planarization (DOP) value (>0.53). These properties demonstrate that poly(imide methylene acrylate) could be utilized as a thermocurable transparent material in fabricating display devices such as TFT‐LCD. Copyright © 2004 Society of Chemical Industry     

High char‐yielding poly[acrylonitrile‐co‐(itaconic acid)‐co‐(methyl acrylate)]: synthesis and properties

Polyacrylonitrile terpolymers of various compositions consisting of acrylonitrile (AN), itaconic acid (IA) and methyl acrylate (MA) were synthesized by solution polymerization in dimethylsulfoxide. Increase in concentration of either IA or MA retarded the overall polymerization rate and the polymer molecular weight. The system consisting of AN + MA and varying IA concentration was more prone to retardation in comparison with the system composed of AN + IA with variable MA concentration. The retardation factors were quantified. Minor quantities of MA boost the reactivity of IA in the terpolymer system. The terpolymer was richer in MA vis‐à‐vis the feed. The thermal characteristics of the terpolymer were examined as a function of its composition. In contrast to the copolymer of AN and IA requiring 1–1.5 mol% IA, the terpolymer required an IA content of approximately 2.5 mol% for optimum thermal stability. The polymer with 90 mol% AN, 2.5 mol% IA and 7.5 mol% MA exhibited reasonably good char‐forming characteristics and thermal stability. The overall crystallinity and crystallite size of the polymers were found to decrease on incorporation of the comonomers. The ‘aromatization index’ of the copolymer increased with the temperature of pyrolysis through re‐organization of the tetrahydropyridine ladder structure. Copyright © 2005 Society of Chemical Industry