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51.
LIU JunFeng & FENG YuJie State Key Laboratory of Urban Water Resource Environment Harbin Institute of Technology Harbin China 《中国科学E辑(英文版)》2009,(6)
SnO2 electrodes have many advantages in the degradation of toxic or bio-refractory organic wastewater,and SnO2 is a kind of anode material which has the potential to be widely used.Electrocatalytic effi-ciency and service life of Ti\SnO2 electrodes are key factors that can influence its applications.In order to enhance the electrocatalytic characteristics of Ti\SnO2 electrodes,a type of electrocatalytic electrode with nanocoating was prepared by direct current(DC)electrodeposition method and thermal oxidati... 相似文献
52.
Metallo-Supramolecular Polymerization: A Route to Easy-To-Process Organic/Inorganic Hybrid Materials
Mark Burnworth Daniel Knapton Stuart J. Rowan Christoph Weder 《Journal of Inorganic and Organometallic Polymers and Materials》2007,17(1):91-103
The self-assembly polymerization of ditopic macromolecules via metal–ligand binding is a facile route for the preparation
of metallo-supramolecular polymers (MSPs). We herein review our recent work focused on the synthesis and investigation of
metallo-supramolecular polymers based on 2,6-bis(1′-methylbenzimidazolyl)pyridine endcapped poly(p-phenylene ethynylene) and poly(p-xylene) macromonomers. These materials are readily solution-processable and display appreciable mechanical properties as
well as other attractive properties such as specific opto/electrical functions or high thermal stability. Our work illustrates
that metallosupramolecular polymerization offers an attractive approach to assemble high-molecular-weight macromolecules from
well-defined, easy to process precursors. Variation of the ditopic ligands and metal ions allows one to easily tailor the
desired properties.
This paper is dedicated to Professor Ian Manners and his scientific accomplishments. 相似文献
53.
54.
钯-银合金膜分离氢气的研究 总被引:1,自引:0,他引:1
采用厚为50μm的Pd/Ag(23)合金膜进行了氢气渗透系数的测定和H_2/N_2混和气分离的研究,得出温度、压力、膜厚、进料气流量、膜的预处理和再活化及膜表面中毒等因素对氢气渗透的影响。分离H_2/N_2混和气可获得高纯氢气。 相似文献
55.
The kinetics of leaching arsenic from Ni-Mo ore roasting dust was investigated. The effects including leaching temperature, particle size of the smelter dust, stirring speed, the coefficient β(the molar ratio of sodium chlorate to arsenic in the smelter dust) and the initial H+ concentration on leaching arsenic were studied. The results indicate that the leaching of arsenic increases sharply with the decrease of particle size. The orders of reaction with respect to H+ concentration and particle size are determinted to be 1.136 and 1.806, respectively. The leaching of arsenic reaches 99% under experimental conditions, the apparent activation energy is determined to be 11.157 kJ/mol, which is consistent with the values of activation energy for diffusion model The kinetics equation of leaching arsenic from the roasting dust could be expressed by a semi-empirical equation as 1-2/3η (1 -η)^2/3 = k0(c[H+])^1.136ro^-1.806 exp[(-11157 /RT)t]. 相似文献
56.
选取炭黑、谷壳灰、绢云母、蒙脱土、凹凸棒石和硅灰石等6种不同形态的无机填料,采用液态成型工艺,制备了无机填料/丁腈橡胶硫化胶,研究了无机填料对丁腈橡胶的力学性能、交联密度、耐燃料B性、耐油性、耐热老化性和微观形貌等特性的影响。结果表明:加入炭黑后,硫化胶的综合性能最佳;加入蒙脱土后,硫化胶的交联密度增至2.49×10^-4mol/cm3,三维交联程度增幅最大;加入凹凸棒石后,硫化胶在燃料B中质量变化率、体积变化率降至同比最低,对耐燃料B性能改善幅度最大;加入硅灰石后,硫化胶在油性环境中的质量、体积变化率、硬度变化最小,对耐油性改善最多;加入绢云母后,硫化胶在热空气氛围下质量变化率、体积变化率和硬度变化同比最小,对耐热老化性能改善幅度最大。 相似文献
57.
This paper proposes a method of directly modifying the surface of cotton fiber to achieve super-hydrophobic properties. The process was directly utilized the long-chain alkyl siloxane and the nano-SiO2 modified cotton cloth, which was simple to operate, low in cost and environmentally friendly. This study discussed the influence of solvent ratio, reactant content and ammonia content on hydrophobicity. The solvent ratio had the greatest influence, and the maximum water contact angle (CA) changes were70° ± 1°. The maximum water CA of the superhydrophobic cotton fabric prepared after process selection was 162 ± 1.5°; it had good acid, alkali and salt resistance. After 24 h in a solution with a pH of 1–14, CA remained almost unchanged; After 144 h in a 3.5% salt solution, CA stabilized above 132°; it had self-cleaning properties; it had good selective adsorption performance, which can quickly separate oil and water; it had good mechanical stability. After 300 times abrasion of sandpaper, which still shows hydrophobic properties. 相似文献
58.
Jianping Shi Wei Zeng Zhiwang Yang Ju Li Pufang Zhao Hongtao Li Xingxing Yan Na Wen Ziqiang Lei Denglong Chen Jie Guan 《应用聚合物科学杂志》2021,138(21):50500
Organic–inorganic hybrid flame retardant was obtained by modifying aluminum hydroxide with different particle size with 1-hydroxyethylidene-1,1-diphosphonic acid. The structure of the organic–inorganic hybrid flame retardant is characterized by Fourier transform infrared spectroscopy, X-ray diffraction, and scanning electron microscopy, while 1H-NMR spectroscopy only characterizes specific samples. The thermal stability and flame retardancy of the samples were analyzed by thermogravimetric analysis, limiting oxygen index (LOI), vertical combustion of UL-94 and cone calorimeter. The results show that the modified 10 μm aluminum hydroxide has a better effect than the 25 μm aluminum hydroxide and 100 nm aluminum hydroxide. Compared with pure polyethylene terephthalate (PET), the LOI value of the best sample is increased by 24.4%, and UL-94 V reaches V-0 level. Heat release rate, total heat release rate, and carbon monoxide production rate decreased by 45.8%, 33.2%, and 41.5%, respectively, compared to pure PET. The results showed that the aluminum hydroxide with a particle size of 10 μm exhibited the best flame retardant effect, which could be attributed to the decomposition of organic phosphoric acid and the dehydration of aluminum hydroxide, yielding a higher amount of residual carbon. 相似文献
59.
论述了国内首创的ET-98无机磷酸盐富锌涂料,该涂料克服了无机磷酸富锌涂料、无机富锌涂料喷砂、抛丸的缺点,简易可行,除锈、除油后即可涂刷,并能达到较好的防腐效果。 相似文献
60.
ZHANG Yujuan YAN Pengxun WU Zhiguo ZHANG Pingyu 《稀有金属(英文版)》2005,24(4):370-375
Titanium nitride (TIN) films with nanostructure were prepared at ambient temperature on a (111) silicon substrate by the filtered cathodic arc plasma (FCAP) technology with an in-plane "S" filter. The effects of deposition parameters on the grain size, texture and nano-hardness of the films were systematically investigated. The grain size was obtained through calculation using the Scherrer formula and observed by TEM. The results of X-ray diffraction and electron diffraction indicated that increasing either negative substrate bias or argon flow promoted the formation of (111) preferred orientation. High argon flow leads to biaxial texture. The micro-hardness of the TIN films as a function of grain size showed a behavior according to the Hall-Petch relation under high argon flow. 相似文献