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排序方式: 共有10000条查询结果,搜索用时 312 毫秒
31.
Ricardo Cambraia Parreira Diana Paola Gmez‐Mendoza Itamar Couto Guedes de Jesus Rafael Pereira Lemos Anderson Kennedy Santos Cristiana Perdigo Rezende Henrique Csar Pereira Figueiredo Mauro Cunha Xavier Pinto Frank Kjeldsen Silvia Guatimosim Rodrigo Ribeiro Resende Thiago Verano‐Braga 《Proteomics. Clinical applications》2020,14(4)
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《矿业科学技术学报(英文版)》2020,30(2):265-269
The purpose of this study was to develop a physico-mathematical model and technique for estimation of chemical bond stability depending on electric field intensity of an external point charge. A hypothesis for a possible physico-chemical mechanism of the formation of additional harmful gases in the rock destruction by blasting was proposed. The theoretical basis of the hypothesis is the method of theretical evaluation of bond energy depending on the distance to a point charge, the third Coulomb centre. The quantum-mechanical model for calculating the electronic terms of molecules makes it possible to solve problems associated with the determination of parameters of molecules under the action of various physical fields on the system under consideration. The model was approved for some diatomic molecules. The discrepancy between the experimental data and calculated data did not exceed 14%, which proves accuracy of the obtained results. The model can be used in the field of research into the causes of gas-dynamic phenomena in underground coal mines, in studies of the degree of stability of nanostructured components of coal under physical influences, and in the theoretical design of new compounds and structures in the field of nanomaterial science and nanotechnology. 相似文献
34.
A heavy crude oil has been treated with deuterated alkylating reagents (CD3I and C2D5I) and directly analyzed without any prior fractionation and chromatographic separation by high-field Orbitrap Fourier Transform Mass Spectrometry (FTMS) and Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FT-ICR MS) using electrospray ionization (ESI). The reaction of a polycyclic aromatic sulfur heterocycles (PASHs) dibenzothiophene (DBT), in the presence of silver tetrafluoroborate (AgBF4) with ethyl iodide (C2H5I) in anhydrous dichloroethane (DCE) was optimized as a sample reaction to study heavy crude oil mixtures, and the reaction yield was monitored and determined by proton nuclear magnetic resonance spectroscopy (1H-NMR). The obtained conditions were then applied to a mixture of standard aromatic CH-, N-, O- and S-containing compounds and then a heavy crude oil, and only sulfur-containing compounds were selectively alkylated. The deuterium labeled alkylating reagents, iodomethane-d3 (CD3I) and iodoethane-d5 (C2D5I), were employed to the alkylation of heavy crude oil to selectively differentiate the tagged sulfur species from the original crude oil. 相似文献
35.
《Food Control》2015
Mycotoxins are secondary metabolites produced by filamentous fungi that usually contaminate food products. Coffee is a natural product susceptible to mycotoxin contamination. The present study evaluates the presence of nivalenol, deoxynivalenol, T-2 and HT-2 Toxin, diacetoxyscirpenol, aflatoxin B1, aflatoxin B2, aflatoxin G1, aflatoxin G2, fumonisin B1, fumonisin B2, ochratoxin A, zearalenone, enniatin A, enniatin A1, enniatin B, enniatin B1, and beauvericin in coffee samples, using liquid chromatography tandem mass spectrometry (LC-MS/MS). The results show that zearalenone was not present in any sample. In the positive samples the contents of fumonisins ranged from 58.62 to 537.45 μg/kg, emerging mycotoxins ranged from 0.10 to 3569.92 μg/kg, aflatoxins ranged from 0.25 to 13.12 μg/kg, and trichothecenes, excepting nivalenol, ranged from 5.70 to 325.68 μg/kg. Nivalenol presented the highest concentrations, from 0.40 to 25.86 mg/kg. Ochratoxin A ranged from 1.56 to 32.40 μg/kg, and five samples exceeded the maximum limit established by the European Commission. 相似文献
36.
《Calphad》2019
An overview of the research on silver-based (Ag-Sn, Ag-Cu, Ag-Ni) and nickel-based (Cu-Ni, Au-Ni, Ni-Pt) bimetallic nanoparticles is presented. The investigated nanoparticles in this review are formed by elements that represent an important group of metals revealing fcc lattice under macro-sized conditions (with the exception of Sn). The effects of surface stabilizing layer of the alloy nanoparticles are also described. Our experience with synthesis, characterization and stabilization of alloy nanoparticles is summarized. The development of the nanoparticle synthesis represents an important and mandatory part of the experimental nanoalloy research. Main synthetic routes under focus are the low temperature borohydride reduction method, the high temperature oleylamine synthesis, and the high pressure method in autoclave. The subsequent structural studies are focused on both nanoparticle core and outer stabilizing layer. The cores of the nanoparticles are studied mainly by electron microscopy techniques. The phase stability of the nanoparticle core is investigated by thermal analysis. The Knudsen effusion mass spectrometry was applied for studies of stabilizing organic molecules that can be found on the surface of the nanoparticles. The presented overview of the experimental results is complemented by thermodynamic calculations of phase diagrams by the CALPHAD method. 相似文献
37.
建立了一种快速、高效的QuEChERS-高效液相色谱-质谱联用法(QuEChERS-HPLC-MS/MS)测定谷类杂粮制品中脱氧雪腐镰刀菌烯醇(DON)、3-乙酰脱氧雪腐镰刀菌烯醇(3-ADON)、15-乙酰脱氧雪腐镰刀菌烯醇(15-ADON)和玉米赤霉烯酮(ZON)共4种真菌毒素。样品前处理采用乙腈-水溶剂提取,经Florisil+C18+无水硫酸镁净化后检测。以0.10%甲酸-乙腈作为流动相,在质谱检测器的多反应监测模式下进行分析。结果表明,4种真菌毒素在各自的线性范围内线性关系良好,相关系数R2均大于0.999,回收率在85.1%~102.0%,相对标准偏差(RSD)为2.11%~6.22%。该方法具有前处理简单、净化效果好、灵敏度高和检测速度快的优点,适用于谷类杂粮制品中DON、3-ADON、15-ADON 和ZON的分析和定量检测。 相似文献
38.
Wyatt L. Brown Douglas A. Day Harald Stark Demetrios Pagonis Jordan E. Krechmer Xiaoxi Liu Derek J. Price Erin F. Katz Peter F. DeCarlo Catherine G. Masoud Dongyu S. Wang Lea Hildebrandt Ruiz Caleb Arata David M. Lunderberg Allen H. Goldstein Delphine K. Farmer Marina E. Vance Jose L. Jimenez 《Indoor air》2021,31(1):141-155
Understanding the sources and composition of organic aerosol (OA) in indoor environments requires rapid measurements, since many emissions and processes have short timescales. However, real-time molecular-level OA measurements have not been reported indoors. Here, we present quantitative measurements, at a time resolution of five seconds, of molecular ions corresponding to diverse aerosol-phase species, by applying extractive electrospray ionization mass spectrometry (EESI-MS) to indoor air analysis for the first time, as part of the highly instrumented HOMEChem field study. We demonstrate how the complex spectra of EESI-MS are screened in order to extract chemical information and investigate the possibility of interference from gas-phase semivolatile species. During experiments that simulated the Thanksgiving US holiday meal preparation, EESI-MS quantified multiple species, including fatty acids, carbohydrates, siloxanes, and phthalates. Intercomparisons with Aerosol Mass Spectrometer (AMS) and Scanning Mobility Particle Sizer suggest that EESI-MS quantified a large fraction of OA. Comparisons with FIGAERO-CIMS shows similar signal levels and good correlation, with a range of 100 for the relative sensitivities. Comparisons with SV-TAG for phthalates and with SV-TAG and AMS for total siloxanes also show strong correlation. EESI-MS observations can be used with gas-phase measurements to identify co-emitted gas- and aerosol-phase species, and this is demonstrated using complementary gas-phase PTR-MS observations. 相似文献
39.
1,5-己二烯交联烯烃聚合物的合成及其抗剪切稳定性 总被引:1,自引:0,他引:1
以金属配合物为催化剂、1,5-己二烯为交联剂,采用本体聚合法合成了交联超高相对分子质量烯烃类聚合物(简称交联聚合物)。用傅里叶变换红外光谱、核磁共振、凝胶渗透色潜表征交联聚合物的结构和相对分子质量。用旋转黏度计和超声波仪研究了1,5-己二烯用量对交联聚合物溶液表观黏度的影响及交联聚合物的相对分子质量对交联聚合物溶液抗剪切稳定性的影响。实验结果表明,在最佳聚合条件(单体80mL、助催化剂0.4mL、CS-1催化剂0.090g、1,5-己二烯0.40mL、0℃、24 b)下所合成的交联聚合物的重均相对分子质量为7.7×106,数均相对分子质量3.6×106。加入少量1,5-己二烯能提高交联聚合物的抗剪切能力,同时也能提高交联聚合物的相对分子质量。交联聚合物的相对分子质量越大,抗剪切稳定性越好。1,5-己二烯用量约为0.1 mL时(单体40 mL),交联聚合物溶液的表观黏度达到最大值(16.8 mPa·s)。 相似文献
40.