24万t/a尿素装置技术改造总结

针对新化化肥有限公司尿素装置存在的问题进行了技术改造,从尿素合成塔、中压分解吸收、低压分解吸收、闪蒸等方面分析了产生问题的原因,提出了改进措施和实施方案。对改造前后工艺指标、产品质量和经济效益进行了对比和分析。改造结果表明.生产能力提高25％,5个月可收回全部投资。     

基站智能天线多波束合成技术

采用数字波束形成的技术，给出了基站智能天线多波束合成的有效算法。对圆环阵分布的基站天线多波束方向图进行了综合，得到了空间隔离度很好的多个波束，并将副瓣控制在30dB以下，结果令人满意。该方法可用于任意单元构成的不均匀阵列天线，还可用于波束展宽及扇形波束的合成。     

Gamma-irradiation-induced Ag/SiO2 composite films and their optical absorption properties

Small Ag particles or clusters dispersed mesoporous SiO₂ composite films were prepared by a new method: First the matrix SiO₂ films were prepared by sol-gel process combined with the dip-coating technique, then they were soaked in AgNO₃ solutions followed by irradiation of γ-ray at room temperature and in ambient pressure. The structures of these films were examined by X-ray diffraction (XRD), high-resolution transmission electron microscope (HRTEM), and optical absorption spectroscopy. It has been shown that the Ag particles grown within the porous SiO₂ films are very small, and they are isolated and dispersed from each other with very narrow size distributions. With increasing the soaking concentration and an additional annealing, an opposite peakshift effect of the surface plasmon resonance (SPR) was observed in the optical absorption measurements.     

天然气空气绝热转化制合成气催化剂研究

制备了天然气空气绝热转化催化剂,采用固定床反应器进行稳定性评价试验,对反应前后的催化剂进行了分析表征。结果说明,天然气和空气绝热转化反应放热形成的高温对催化剂有烧结作用,使催化剂晶体结构发生了变化,起活性作用的金属镍和氧化铝载体转化为镍铝尖晶石结构的物质。进一步的试验表明,在1050～1300℃的温度可以把催化剂的晶体结构改变。     

Electro-organic synthesis without supporting electrolyte: Possibilities of solid polymer electrolyte technology

The application of ion exchange membranes as solid polymer electrolytes (SPE) in fuel cells is state-of-the-art. This technology needs no supporting electrolyte; consequently it can be applied for electro-organic syntheses in order to save process steps. In this case the process is not predetermined to a maximized energy efficiency so that the selection of the cell design, of the electrode materials and of the operating conditions can be focused on a high selectivity of the electrode reactions. The electro-osmotic stream, which is caused by the solvation shells of the ions during their migration through the membrane, and hence is a typical property of SPE technology, has a significant effect on the electrode reactions. It generates enhanced mass transfer at the electrodes, which is beneficial for reaction selectivity. It can be influenced by the choice of, and possibly by the preparation of, the membrane. An additional remarkable advantage of SPE technology is the exceptional long durability of oxide coated electrodes. By combination of several process engineering methods stable operation of SPE cells has been realized, even for examples of non-aqueous reaction systems. Experiments up to 6000 h duration and in cells of up to 250 cm² membrane area show the potential for industrial application.     

甲基叔戊基醚合成反应的热力学分析

利用戊烯与甲醇合成甲基叔戊基醚(TAME)反应的热力学平衡实验数据, 选择不同的混合活度模型,分别计算得到了该反应体系的平衡常数,并与理论计算得到的平衡常数相比较,筛选出了适合该反应体系的活度计算模型.     

Synthesis and luminescence of Sr2CeO4 fine particles

Fine particles of a blue emission phosphor Sr₂CeO₄ have been synthesized using a chemical co-precipitation technique, and the textual and luminescent properties were compared with the one synthesized by the conventional solid-state reaction method. Particle size and distribution of the Sr₂CeO₄ fine powder prepared by the co-precipitation process were smaller and narrower than those obtained by the samples prepared from the conventional one. The emission intensity of the fine particles was equal to that of the larger particles prepared from the solid-state reaction, on the contrary to the general tendency that emission intensity decrease with particle size reduction. Although no Ce³⁺ peaks were observed in EPR measurements, X-ray photoelectron spectra of the samples clearly elucidated the existence of Ce³⁺ only on the surface of Sr₂CeO₄.