Production of hydrogen over bimetallic Pt–Ni/δ-Al2O3: I. Indirect partial oxidation of propane

Indirect partial oxidation (IPOX) of propane was studied over bimetallic 0.2 wt.% Pt–15 wt.% Ni/δ-Al₂O₃ catalyst in the 623–743 K temperature range. The unreduced and reduced forms of the catalyst were characterized by ESEM–EDAX and X-ray diffraction (XRD). In the IPOX tests, the effects of steam to carbon ratio (S/C), carbon to oxygen ratio (C/O₂) and residence time (W/F (g_cat h/mol HC)) on the hydrogen production activity, selectivity and product distribution were studied in detail. The effect of temperature program applied (increasing from 623 to 743 K, ITP; decreasing from 743 to 623 K, DTP) during reaction was also tested. The results showed that the Pt–Ni bimetallic system has superior performance characteristics compared to the monometallic catalysts reported in literature. The reason is thought to be the utilization of the catalyst particles as micro heat exchangers during IPOX; the heat generated by Pt sites during exothermic total oxidation (TOX) being readily transferred through the catalyst particles acting as micro heat exchangers to the Ni sites, which promote endothermic steam reforming (SR). The optimal conditions were found as S/C = 3, C/O₂ = 2.70 and W/F = 0.51 g_cat h/mol HC for IPOX of propane on the basis of high hydrogen productivity and selectivity between 623 and 748 K for the experimental conditions tested. The thermo-neutral points obtained showed the sustainability of reaction in terms of energy.     

一种新的含水率校正方法

从研究流体流动规律出发,结合模拟井实验结果,建立了多参数、非线性的半理论和半实验含水率校正模型,提出了反映两相滑脱效应的滑动比概念,其计算方法物理意义清晰并具有明确的收敛边界。与模拟井实验结果进行对比,使用平方法降低了含水率校正误差。     

模糊Petri网及知识表示

在建造专家系统中虽然有很多种知识表示方法，但都有不尽人意的地方，本文试图用一种新的方法－Ｐｅｔｒｉ网模型来表示知识。本文给出了Ｆｕｚｚｚｙ Ｐｅｔｒｉ网和广义Ｆｕｚｚｙ Ｐｅｔｒｉ网两种模型，并给出了相应的推理算法，一旦专家知识用Ｐｅｔｒｉ网表示后，根据Ｐｅｔｒｉ网固有的特性，我们就能处理专家系统中并行推理、无回溯推理，反向推理等问题。     

Estimation of bacterial production through the coupling of (methyl 3H) Thymidine incorporation and several parameters over a Microcystis aeruginosa bloom in a hypereutrophic reservoir

The coupling of the changes in bacterial quantitative and metabolic aspects during Microcystis aeruginosa bloom conditions together with several environmental parameters was studied in the hypereutrophic Villerest reservoir, France. Bacterial abundance varied from 5.20 to 21.28 × 10⁶ bacteria-mL^?1, while bacterial biomass ranged between 75 and 507 μg C mL^?1. These results confirmed the highly eutrophic status of the Villerest reservoir. The relative quantitative importance of attached bacteria increased as Microcystis proliferated. Methyl-³H incorporation and D-(U-¹⁴C) glucose uptake varied from 8.99 to 60.57 × 10⁶ cells-mL^?1, and 0.016 to 1.587 μg CL^?1 h^?1, respectively. Correlations between several abiotic and biotic parameters showed that phytoplankton regulated bacterial growth by releasing organic carbon which is directly uptaken by heterotrophic bacteria. In the hypolimnion, the sedimentation of decaying algae represented a substantial substrate for bacterial growth.     

米塔尔钢铁集团的全球并购发展战略

概述了米塔尔的并购经过和并购特点,着重探讨了米塔尔的管理模式、人员情况、钢铁厂布局、生产经营、主要战略伙伴、研发机构及其生产、采购与销售策略。系统地分析了米塔尔在中国的发展,指出米塔尔在全球钢铁业整合中处于领先地位,米塔尔来中国投资看中的是中国的原料和市场,且运作步伐明显加快,会对中国钢铁企业构成很大的威胁。     

不同灌溉条件下的水稻需水规律及水分生产率分析

稻田需水量包括植株蒸腾、棵间蒸发、田间渗漏3部分。研究表明，水稻在充分供水条件下所形成的蒸腾量中包含了一部分无效蒸腾，无效蒸腾量的减少不会影响作物的生长发育，反而会有不同程度的增产和优质效应。节水灌溉技术的推广产生了明显的经济与社会效益。结合当地实际情况采用3种常见的灌溉方式探讨了不同灌溉方式下水稻的需水规律、灌概定额和生产率的差异，为水稻节水高效栽培提供理论与技术依据。     

200 万t链箅机-回转窑球团生产线快速达产实践

介绍了邯钢200万t链箅机-回转窑酸性氧化球团生产线的工艺特点和主要设备,以及建成投产后试生产的有关情况。通过周密的部署和安排,该生产线实现了40天快速达产的目标。     

就拉杆固定支架谈锻件的缺陷分析

针对汽车锻件拉杆固定支架在生产过程中产生的裂纹、折叠、表面脱碳等多种形式缺陷,从锻件生产工艺过程的各工序来分析其可能产生的缺陷,并重点就裂纹、折叠、表面脱碳等缺陷产生的原因及其解决方法进行探讨,从而进一步完善生产工艺,改善锻件质量.     

Study of direct and indirect naphtha recycling to a resid FCC unit for maximum propylene production

To satisfy the increasing propylene demand, direct and indirect naphtha recycling schemes around an existing resid fluid catalytic cracking (FCC) unit were investigated. To this aim, light cracked naphtha (LCN), heavy cracked naphtha (HCN) and a PolyNaphtha (PN) oligomerisation product were cracked under a wide range of operating conditions over a commercial Y zeolite based equilibrium catalyst. Experimental data were acquired in three different units: a fixed bed bench scale unit, a fixed fluidised bed unit and an adiabatic circulating fluidised bed pilot plant. It was shown that FCC naphthas require high operating severities to crack, and that even then their conversion remains relatively moderate. Hence, direct recycling to the main riser does not seem a viable pathway to increase propylene product. Feeding FCC naphthas to a second reaction zone operating at high severity allows to increase the propylene yield in a significant manner. Increasing conversion, however, not only leads to higher LPG and propylene yields, but also results in very high dry gas yields. An alternative scheme was proposed, in which the olefinic C₄ and C₅ fractions are converted into a naphtha fraction through oligomerisation in a dedicated unit before being recracked in the secondary riser. As the highly olefinic oligomerised effluent mainly consist of dimerised and trimerised butenes and pentenes, this feed is more easily cracked and high conversions can be achieved. This indirect interconversion of butenes and pentenes into propylene therefore effectively allows to convert these butenes and pentenes into propylene, resulting in a significant increase in propylene yield. Each of the three main naphtha recycle options (directly to the main riser, directly to a secondary riser or indirectly via a light olefin oligomerisation unit) have been analysed and compared to a base case. In the evaluation of each of these schemes, all heat balance effects, both on the riser and the regenerator side, have been accounted for. The proposed process scheme with an indirect recycle via an oligomerisation unit enhances the already inherent flexibility of the FCC unit. The naphtha recycle can be turned on or off, the second reaction zone can be used to crack naphtha or to crack resid feed to maximise throughput, while the effluent of the oligomerisation unit can be recycled to the FCC unit for propylene production or hydrogenated and sent to gasoline and kerosene pool.     

Estimation of the Substrate Concentration Profiles in Petroleum Pipelines Containing Biofilms

In industrial systems, the formation of biofilms can cause many problems, such as an increase in the flow resistance of pipelines, energy losses in fluid transport and heat exchangers, product contamination, materials deterioration, and biocorrosion. As a result, biofilms contribute substantially to economic losses in the industry. Corrosion is particularly an issue in the petroleum industry and its implications range from down-hole completion through petroleum processing units. Much of this corrosion is attributed to microbial activities. This paper proposes a mathematical model for predicting substrate concentration for such microbial growth. Substrate concentrations in the system and near the biofilm surface are one of the parameters that has a great effect in determining the extent of the problems associated with biofilms. In this study, a convective-diffusion model under various flow conditions (stagnant, laminar, and turbulent) has been solved using the finite difference technique, employing the alternating direction implicit (ADI) method. The model assumes that a liquid containing substrate and bacteria is flowing in a pipeline with known concentrations at the inlet and then predicts the variation of the transient (as a function of time) substrate concentration along the pipeline and as a function of the pipe radius. The model is then used to predict and estimate the substrate concentration profiles on the biofilm surface under different environmental conditions. A parametric study was also conducted to study the effect of the different parameters influencing the substrate concentration profiles in the system and on the biofilm surface.