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991.
丙烯酸接枝聚丙烯纤维的结构与性能   总被引:15,自引:2,他引:13  
肖为维  姚家华 《功能材料》1994,25(4):317-321
本文研究了用化学引发剂引发丙烯酸接枝聚丙烯纤维的某些影响因素。红外光谱分析表明,丙烯酸接枝在聚丙烯大分子链的叔碳原子上。X-射线衍射和DSC分析指出,纤维接枝后结晶度有所增加,接枝前纤维存在的β-变体转化成了α-变体,接枝纤维的吸湿性、离子交换容量和染色性随接枝率增加而增大。接枝纤维的力学性能有所下降。  相似文献   
992.
总结回顾了1994年中国化学工业的改革及发展现状,提出了1995年化工生产建设的目标及在化工行业改革方面的四项试点工作,强调了编制“九五”计划的重要性。  相似文献   
993.
采用自制的无膜电解槽,对同时电解氧化还原葡萄糖生成葡萄糖酸和山梨醇的工艺进行了研究。所得到的最佳工艺条件为:葡萄糖浓度0.4mol/L,pH值11,电流密度3A/dm ̄2。在此条件下电解12h,葡萄糖转化率可达96.4%,葡萄糖酸产率88%,山梨醇产率10%。同时,考察了和Zn ̄(2+)加入以及pH值对电流效率的影响。  相似文献   
994.
Surface free energies of polyurethanes made from toluene diisocyanate and 1, 4 butanediol-based hard segments and caprolactone polyol-based soft segments were calculated using additive functions. Good agreement was found between the calculated values based on additive functions and the calculated values based on contact angle measurements. The phase-separated polyurethanes were found to have a higher polar surface free energy component (γP). This was linked to the preferential segregation of butanediol/butanediol-derived moieties to the polyurethane surfaces due to phase separation. The adhesion values of these polyurethanes to soda-lime glass were correlated with their respective γP values and a linear relationship was found. It was also shown that the adhesion values of the low γP polyurethanes improved substantially when the glass surfaces were coated with a thin layer of butanediol prior to the bonding. The modulus of the interphase region rich in butanediol was evaluated. Although a modulus increase was found at the interface, this increase was found to play a secondary role in the adhesion. The chemical interactions at the polyurethane/glass interphase were investigated by pre-treating the glass surfaces with methyl-trimethoxysilane and trimethylchlorosilane prior to adhesion testing. The adhesion data showed no significant difference between the uncoated and the silane-treated glass substrates. Based on this experimental evidence, the possibility of any covalent or ionic bonding at the polyurethane/glass interphase was assumed negligible. It was determined that the mechanism of adhesion between the polyurethanes and the glass surface could be through the formation of an interphase region in which hydrogen bonding between the butanediol-rich interphase region and the hydroxylated glass surface plays a key role.  相似文献   
995.
从烧结矿冷却并回收其余热的角度出发,介绍了利用烧结机尾落矿空间,采用喷吹空气装置对烧结矿进行冷却的小型模拟试验,从测出的结果来看,有可能成为一种新的烧结矿冷却方式。  相似文献   
996.
997.
Intelligent processing of materials (IPM) deals with the integration of process models and in situ sensors into an intelligent process controller to achieve desired material properties. IPM-based control systems recently have been developed for both consolidation and solidification processes. This article explores the application of models based on the finite- element method (FEM) to develop process actuation systems, to design process schedules and component shape, and to develop a control model with which to control the process. The results in this article were presented at the AeroMat ’93 Advanced Aerospace Materials/Processes Conference and Exposition, Anaheim, CA, 7–10 June 1993  相似文献   
998.
某区在海上铺设管道,须通过厚沙波沙脊区,采用机械方法施工很困难,应用沉入混凝土管的爆破方法具有投资省,速度快,施工简单的特点。  相似文献   
999.
During the winter of 1988/1989, the relationships between the prevalence of work-related health and indoor climate complaints and a number of building, management, workplace and personal characteristics have been investigated in a study in more than 60 office buildings located throughout the Netherlands. To collect the information, a questionnaire was prepared on health and indoor climate complaints and personal and workplace characteristics. A checklist was used to obtain information on building characteristics More than 7000 questionnaires were completed by the regular users of the buildings investigated. The results showed that the prevalence of symptoms was higher in air-conditioned buildings than in naturally or mechanically ventilated buildings. some other variables were also related with most work-related complaints after adjustment for selected management, personal, workplace and job characteristics. These included gender, work satisfaction in general, presence of allergies and/or respiratory symptoms, and personal control over temperature at the workplace. No differences were found in symptom prevalences between buildings with spray and steam humidification. The combination of air-conditioning and humidification did not lead to further increases in the prevalence of complaints as compared to buildings with only airconditioning or only humidification.  相似文献   
1000.
本文研究了羊皮服装革的弯曲应力衰减性能。对应力衰减常数(αb)及其与羊皮服装革手感弹性的关系进行了讨论。结果表明:αb与革的手感弹性相关。αb值定量反映出革的手感弹性优劣。  相似文献   
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