超声CO激光的现状和展望(续)

介绍了200kWCW超声电子束连续CO激光器（SSCO－EIL）开环实物模型的能量和光谱特征的实验研究结果，以及增加SSCO－EIL的输出功率，谱线选择性，Q－开关激光作用的数字计算结果，同时讨论了SSCO－EIL的特性对几种激光技术效率的影响，由于激光能量利用率的增加和能量成本的降低，SSCO－EIL拥有的无与伦比的能量和特有的特征，将大大拓宽激光技术的应用领域。     

双酚单丙烯酸酯类抗氧剂GM的合成

以2,2′-甲撑双(4-甲基-6-特丁基苯酚)(简称2246)、丙烯酸、氯氧化磷等为反应原料,通过酯化反应合成了GM,考察了合成GM的适宜工艺条件。在n(2246)∶n(丙烯酸)∶n(氯氧化磷)=1∶1.25∶0.90、催化剂m(三乙胺)∶m(2246)=1∶1.0X、反应温度105℃、反应时间2.5 h的合成条件下,原料2246转化率大于96.0%;GM产品选择性大于91.0%;GM产品摩尔收率大于83.0%;GM产品的液相色谱纯度大于99.0%。采用该工艺合成抗氧剂GM的特点是将酰卤化过程和脱卤化氢过程合二为一,由2246和丙烯酸直接进行酯化反应合成GM。工艺流程短,产品收率高、质量稳定,有可能便于工业化生产。     

新型加成型硅橡胶灌封胶的研究

本文合成了两种新型加成型硅橡胶：ＴＡＳ硅橡胶和ＭＤＡＳ硅橡胶。与通常使用的乙烯基加成型硅橡胶相比，ＴＡＳ或ＭＤＡＳ硅橡胶的固化条件与之相似，但ＴＡＳ－ｐｔ和ＭＤＡＳ－ｐｔ固化体系对许多能阻滞乙烯基加成型硅橡胶固化的物质不敏感。另一方面，ＴＡＳ－ｐｔ和ＭＤＡＳ－ｐｔ固化体系对许多材料（尤其对金属）呈现良好的粘接性能，且当样品浸于水中１５天后，仍保持其粘性。上述性能，使之具有许多用途。本文还讨论了ＴＡＳ和ＭＤＡＳ生胶的合成方法，以及影响ＴＡＳ、ＭＤＡＳ固化的若干因素。     

A parametric frequency response method for non-linear time-varying systems

A new parametric frequency response algorithm is introduced to investigate linear and non-linear dynamic systems with time-varying parameters. In the new algorithm the time-varying parameters are regarded as additional inputs of the systems and the non-linear generalised frequency response functions for multi-input-single-output systems are then employed to obtain Zadeh's system functions from a differential equation representation. The parametric frequency response method reveals how the time-varying parameters affect the behaviour of the systems through a time-varying term. The new method can be applied to both linear and non-linear time-varying systems.     

颗粒多孔表面强化沸腾传热动力学研究

通过对颗粒多孔层几何结构、沸腾两相流及传热的理论分析，提出了微型通道薄膜环状蒸发物理模型和沸腾传热机理，建立了颗粒多孔表面强化沸腾传热动力学模型。该动力学模型与实验数据吻合良好，可用于工程设计。     

Adaptive tracking control of an autonomous underwater vehicle

This paper presents the trajectory tracking control of an autonomous underwater vehicle(AUV). To cope with parametric uncertainties owing to the hydrodynamic effect, an adaptive control law is developed for the AUV to track the desired trajectory. This desired state-dependent regressor matrix-based controller provides consistent results under hydrodynamic parametric uncertainties.Stability of the developed controller is verified using the Lyapunov s direct method. Numerical simulations are carried out to study the efficacy of the proposed adaptive controller.     

Decolourisation of aqueous dyes by sequential oxidation treatment with ozone and Fenton's reagent

Combined oxidation with ozone and Fenton's reagent (‘Fentozone’ process) for decolourisation of aqueous dyes was studied and compared with traditional Fenton's reagent. Although the ‘Fentozone’ process was found to be effective at a wide range of pH values, the maximum colour removal was achieved at pH 4. The effect of pre‐ozonation on colour removal efficiency of aqueous dyestuffs in the subsequent treatment with Fenton's reagent was investigated. The reaction kinetics using water‐soluble acid and reactive dyes were also studied. Our experimental results show that pre‐ozonation can considerably accelerate decomposition of dyestuffs in the subsequent treatment with Fenton's reagent. Different concentrations of ferrous sulfate were used to investigate their influences on the removal of colour. The rate of reaction increased with increasing doses of ferrous sulfate. © 2002 Society of Chemical Industry